8,095 research outputs found

    UMSL Bulletin 2023-2024

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    The 2023-2024 Bulletin and Course Catalog for the University of Missouri St. Louis.https://irl.umsl.edu/bulletin/1088/thumbnail.jp

    Graduate Catalog of Studies, 2023-2024

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    Proceedings of the 10th International congress on architectural technology (ICAT 2024): architectural technology transformation.

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    The profession of architectural technology is influential in the transformation of the built environment regionally, nationally, and internationally. The congress provides a platform for industry, educators, researchers, and the next generation of built environment students and professionals to showcase where their influence is transforming the built environment through novel ideas, businesses, leadership, innovation, digital transformation, research and development, and sustainable forward-thinking technological and construction assembly design

    Development of Flame Retardant and Antibacterial Dual Functionalised Flexible Polyurethane Foam

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    Flexible Polyurethane foam (PUF), with its unique properties, such as lightweight and softness, has been utilised extensively. Nevertheless, owing to the intrinsic high flammability and low ignition temperature, PUF-associated fire risks are always a concern. During PUF’s combustion, excessive heat and toxic gases can be generated, threatening the health and life of human beings and causing huge property loss. Consequently, improving the flame retardancy of the PUF is of importance. Later, the global COVID-19 pandemic broke out in 2019, leading to the public’s increased awareness of maintaining good hygiene conditions. Since PUF products are frequently in contact with humans daily, rendering the PUF with bacterial-killing properties should also be addressed. This dissertation delivers studies on introducing flame retardancy to the PUF via a surface engineering method named the layer-by-layer (LbL) assembly. Due to the consequent COVID-19 situation, this thesis expands the investigations to endow the PUF with antibacterial performances. Preliminary research on fabricating a newly emerged two-dimensional material called MXene (Ti3C2) and chitosan (CH) as flame retardants (FRs) to impart fire safety performances to the PUF was conducted. With only 6.9 wt.% mass added to the PUF, unprecedented fire resistance and smoke suppression properties were received. It was revealed that the FR mechanism was ascribed to the hybrid coating’s excellent barrier and carbonisation effects. Further investigations on improving the PUFs’ biodegradability identified synergistic effects between the MXene with the CH and phytic acid, demonstrating the great potential for reducing the toxicity and improving the eco-friendliness of the PUFs. Additionally, this thesis analysed the FR and antibacterial dual-functionalised PUFs. The synthesised MXene, CH, and silver ion hybridised coating endows the foam with exceptional bactericidal properties with decreases of 99.7 % in gram-negative bacteria and 88.9 % in gram-positive bacteria compared with the unmodified counterpart. Excellent flame retardancy possessed by the dual-functionalised PUFs was discovered. The compatibility of the two functional coatings was evaluated and confirmed. The results manifest the great potential for eradicating the fire risks of PUFs and providing traditional PUF products with antibacterial properties, further expanding PUF’s applications

    Mineral snowflakes on exoplanets and brown dwarfs

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    The diversity of exoplanets and brown dwarfs provides ideal atmospheric laboratories to investigate novel physico-chemical regimes. Furthermore, the atmospheres of exoplanets act as the history books of planetary system. However, as observational data improves, the contributions of cloud particles in exoplanet and brown dwarf atmospheres must be adequately accounted for. Microphysical modelling of cloud formation provides the best method to investigate the potentially observable properties of clouds in these atmospheres. Most observed gas-giant exoplanets have been suggested to host mineral clouds which could form `snowflake-like' structures through condensation and constructive collisions. Cloud particle porosity, size and number density are influenced by constructive and destructive collisions. In this thesis, we expand our kinetic non-equilibrium cloud formation model to explore the effects of non-compact, non-spherical cloud particles on cloud structure and their spectroscopic properties. Additionally, we investigate the effects on clouds of collisional growth and fragmentation. The impact of these affects is assessed on prescribed 1D (Tgas-Pgas) profiles in DRIFT-PHOENIX model atmospheres of brown dwarfs and exoplanets. We utilise Mie theory and effective medium theory to study cloud optical depths, where we additionally represent non-spherical cloud particles with a statistical distribution of hollow spheres. We find that micro-porosity can affect the distribution of cloud particles in an exoplanet atmosphere, and that irregular particle shape impacts the optical depth in the near- and mid-infrared. However, we also find that cloud particle collisions driven by turbulence result in fragmentation of cloud particles for exoplanet atmospheres, which also impacts optical depths in the optical and mid-infrared regions. The global distribution and properties of clouds is also important as observations begin to allow for treating exoplanets in their full 3D nature. We therefore apply a hierarchical approach to global cloud formation modelling. We also apply our 1D cloud formation model to profiles extracted from results of 3D General Circulation Models (GCM) for the gas-giant exoplanet WASP-43b and the ultra-hot Jupiter HAT-P-7b, revealing a dramatic difference in the distribution of clouds between these types of exoplanets as a result of stellar radiation heating the day-side of the ultra-hot planets. This results in an asymmetry in cloud structures for the terminators of WASP-43b and more significantly for HAT-P-7b, observable in the optical depth of the clouds at these points, further complicating retrieval of cloud properties from spectra."This work was supported by the Science and Technology Facilities Council (STFC), UK [grant number 2093954]; and the Ă–sterreichische Akademie der Wissenschaften."--Fundin

    Beam scanning by liquid-crystal biasing in a modified SIW structure

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    A fixed-frequency beam-scanning 1D antenna based on Liquid Crystals (LCs) is designed for application in 2D scanning with lateral alignment. The 2D array environment imposes full decoupling of adjacent 1D antennas, which often conflicts with the LC requirement of DC biasing: the proposed design accommodates both. The LC medium is placed inside a Substrate Integrated Waveguide (SIW) modified to work as a Groove Gap Waveguide, with radiating slots etched on the upper broad wall, that radiates as a Leaky-Wave Antenna (LWA). This allows effective application of the DC bias voltage needed for tuning the LCs. At the same time, the RF field remains laterally confined, enabling the possibility to lay several antennas in parallel and achieve 2D beam scanning. The design is validated by simulation employing the actual properties of a commercial LC medium

    Study of soft materials, flexible electronics, and machine learning for fully portable and wireless brain-machine interfaces

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    Over 300,000 individuals in the United States are afflicted with some form of limited motor function from brainstem or spinal-cord related injury resulting in quadriplegia or some form of locked-in syndrome. Conventional brain-machine interfaces used to allow for communication or movement require heavy, rigid components, uncomfortable headgear, excessive numbers of electrodes, and bulky electronics with long wires that result in greater data artifacts and generally inadequate performance. Wireless, wearable electroencephalograms, along with dry non-invasive electrodes can be utilized to allow recording of brain activity on a mobile subject to allow for unrestricted movement. Additionally, multilayer microfabricated flexible circuits, when combined with a soft materials platform allows for imperceptible wearable data acquisition electronics for long term recording. This dissertation aims to introduce new electronics and training paradigms for brain-machine interfaces to provide remedies in the form of communication and movement for these individuals. Here, training is optimized by generating a virtual environment from which a subject can achieve immersion using a VR headset in order to train and familiarize with the system. Advances in hardware and implementation of convolutional neural networks allow for rapid classification and low-latency target control. Integration of materials, mechanics, circuit and electrode design results in an optimized brain-machine interface allowing for rehabilitation and overall improved quality of life.Ph.D

    Investigations of phase transitions in magnetic materials by magnetic-field- and temperature-dependent x-ray diffraction

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    The subject of this doctoral work is the assembly of a laboratory-based x-ray diffractometer with magnet and non-ambient sample temperature environment for investigations of magnetic materials. A special focus is on the versatility and accessibility of the instrument. The x-ray diffractometer serves as important analysis tool for the determination of the crystallographic unit cell and derived parameters like strain or expansion as function of the temperature and magnetic field. Some materials undergo structural or magnetic phase transformations under specific conditions, which can be induced within the x-ray diffractometer. These phase transformations, and their effect on crystallographic parameters of the investigated materials can be followed in situ in the instrument. Several case studies of investigations of magnetoelastic and magnetostructural phase transitions at temperatures between 25 to 600 K under various magnetic fields highlight the performance and capabilities of the instrument. The final x-ray diffractometer setup is equipped with a 5.5 T magnet and cryofurnace for non-ambient measurements in the range between 11–700 K. Measurements in transmission geometry result in reliable reflection intensities that allow for the refinement of structural parameters, and even structure solution from the diffraction data. The fast position-sensitive Si strip detector has a large angular coverage, and allows for quick data collections. High resolution data can be collected with the use of a monochromator crystal at the expense of photon flux instead of the high flux x-ray mirror optics. Integration of all diffractometer components into the control software enables the use of macros for automated data collection for a series of different measurement conditions. The first set of case studies is related to materials with a magnetoelastic phase transition, MnB, FeB and LaFe11.4Si1.6, which exhibit no structural change over the course of the magnetic ordering, but a large elastic response. Synchrotron and neutron scattering studies complement the characterization with the lab-based diffractometer with magnet, and reveal the first-order character of the phase transition. Spin fluctuations are the connecting driving force behind the magnetovolume effects and anomalies over the course of the phase transition in MnB, FeB and LaFe11.4Si1.6. The term spin fluctuations, however, describes different phenomena in the investigated materials and is clarified accordingly. The second set of case studies is related to the (La,Ce)Fe12B6 class of materials. They undergo a magnetic-field-induced phase transition at low temperatures that is coupled with a huge magnetostriction. The origin behind this anisotropic expansion over the course of the phase transition is determined as magnetic-field-induced magnetostructural phase transition into a new ferromagnetic structure. The structure is determined from the x-ray diffraction data collected in magnetic fields. A model for the transformation mechanism in the form of a martensitic-like phase transition is proposed. The model also explains the burst-like growth of ferromagnetic phase in the matrix of surrounding grain boundaries. A kinetic arrest of the ferromagnetic structure occurs, and results in a delay and large hysteresis of the magnetostructural phase transition

    Neuromorphic-P2M: Processing-in-Pixel-in-Memory Paradigm for Neuromorphic Image Sensors

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    Edge devices equipped with computer vision must deal with vast amounts of sensory data with limited computing resources. Hence, researchers have been exploring different energy-efficient solutions such as near-sensor processing, in-sensor processing, and in-pixel processing, bringing the computation closer to the sensor. In particular, in-pixel processing embeds the computation capabilities inside the pixel array and achieves high energy efficiency by generating low-level features instead of the raw data stream from CMOS image sensors. Many different in-pixel processing techniques and approaches have been demonstrated on conventional frame-based CMOS imagers, however, the processing-in-pixel approach for neuromorphic vision sensors has not been explored so far. In this work, we for the first time, propose an asynchronous non-von-Neumann analog processing-in-pixel paradigm to perform convolution operations by integrating in-situ multi-bit multi-channel convolution inside the pixel array performing analog multiply and accumulate (MAC) operations that consume significantly less energy than their digital MAC alternative. To make this approach viable, we incorporate the circuit's non-ideality, leakage, and process variations into a novel hardware-algorithm co-design framework that leverages extensive HSpice simulations of our proposed circuit using the GF22nm FD-SOI technology node. We verified our framework on state-of-the-art neuromorphic vision sensor datasets and show that our solution consumes ~2x lower backend-processor energy while maintaining almost similar front-end (sensor) energy on the IBM DVS128-Gesture dataset than the state-of-the-art while maintaining a high test accuracy of 88.36%.Comment: 17 pages, 11 figures, 2 table

    Stabilization and Resuscitation of Newborns

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    The majority of newborns do not need medical interventions to manage the neonatal transition after birth. However, every year millions of newborns worldwide require respiratory support immediately after birth, and another considerable number of newborns additionally require extensive resuscitation including chest compressions and drug administration. Despite a significant increase in knowledge and development of enhanced therapy strategies over the past few years, morbidity and mortality caused by failures in neonatal transition remain an important health issue. The purpose of this reprint is to support or introduce novel concepts and add information in the area of the “Stabilization and Resuscitation of Newborns”, aiming to improve neonatal care and, as the major objective, to enhance neuro-developmental outcomes
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