Studies of the scattering/absorption of minerals

Reflectance spectra were computed for water ice and ammonia ice mixtures as functions of weight fraction, grain size, and viewing geometry to simulate possible outer solar system satellite surfaces. Reflectance spectra of planetary surfaces are most affected by the weight fraction and grain sizes of the minerals in the surface. The reflectance can range from 1.0 to about 0.01 by changing the grain size or weight fraction, a factor of 100. Viewing geometry changes the reflectance by about 25 percent or less

MODELING OF WAX DEPOSITION DURING OIL PRODUCTION USING A TWO-PHASE FLASH CALCULATION

Wax deposition is a serious problem in the Petroleum Industry that results in the plugging of flow strings, formation damage, loss of hydrocarbons, increased production cost. The existing models used jn the oil industry for predicting wax phase equilibrium parameters over-estimate the amount of wax that is formed in terms of the wax weight fraction and the number of moles of solid. The Coutinho correlation is the latest of these models and is used to calculate the melting temperature and the enthalpy of fusion of the crude oil components. It did not consider the effect of branching of carbon atoms in the hydrocarbon structure/compound. But branching of carbon atoms in the hydrocarbon compounds affects its melting point. In this work, the correlation for calculating the melting temperature in crude oil developed by Coutinho has been modified to take into account the effect of branching of carbon-carbon chains in isoparaffins and the model has been used to calculate a new set of equilibrium parameter. The modified regular solution theory was used to calculate the activity coefficient ratio that was used as an input to the new model. Wax phase equilibrium flash calculations were carried out with the new set of equilibrium parameters. The wax mixture was then characterized using the weight fraction of component in the solid phase and weight fraction of component in the solid phase in the mixture. In order to check the reliability of the model, the data presented by Hanquan was used as input into the models developed by Won, Chung, Countinho and the new one. The new model predicted a more conservative value for the number of moles of solid formed, weight fraction of component in the solid phase and weight fraction of component in the solid phase in the mixture for C1s-C4o.This is an improvement over the existing models which overestimate the values of the parameters

Segmented block copolymers based on dimerized fatty acids and poly(butylene terephthalate)

Segmented block copolymers based on dimerized fatty acids and poly(butylene terephthalate) (PBT) have been synthesized in the melt. Branched C36, C44 and C70 dimerized fatty acids with a low degree of unsaturation were used. The fraction of PBT was varied from 50 to 100wt%. The resulting polymers were analysed with d.s.c. and d.m.a. The glass transition temperature (Tg) increased with increasing weight fraction of PBT. Tg decreased with increasing molecular mass of the dimerized fatty acid. The melting temperature increased with increasing weight fraction of PBT and increasing molecular mass of the dimerized fatty acid. The range of service temperatures of the thermoplastic elastomers can therefore be enlarged by using dimerized fatty acid with a high molecular mass. With increasing molecular mass of the dimerized fatty acid the storage modulus and the melting and crystallization enthalpy did not change significantly. The storage modulus can be described as a function of the volume fraction of crystalline PBT, but is not a function of the type of dimerized fatty acid

A closed character formula for symmetric powers of irreducible representations

We prove a closed character formula for the symmetric powers $S^N V(\lambda)$ of a fixed irreducible representation $V(\lambda)$ of a complex semi-simple Lie algebra $\mathfrak{g}$ by means of partial fraction decomposition. The formula involves rational functions in rank of $\mathfrak{g}$ many variables which are easier to determine than the weight multiplicities of $S^N V(\lambda)$ themselves. We compute those rational functions in some interesting cases. Furthermore, we introduce a residue-type generating function for the weight multiplicities of $S^N V(\lambda)$ and explain the connections between our character formula, vector partition functions and iterated partial fraction decomposition.Comment: 14 pages, 1 figure, published versio

Chemical analysis of soluble fractions from normal and autolysed rabbit liver by column chromatography

Chromatography on Sephadex G-200 was performed with the soluble fraction of homogenated rabbit liver, which was extracted with 0.1 M phosphate buffer containing 0.1 M NaCl. and the influences of autolysis on the soluble fraction of liver were also examined. The soluble fraction of liver was different from serum in molecular weight, in electrophoretic character and in components with sedimentation coefficients. The soluble fraction of liver was stable under the influence of Mg and K ions, and rather unstable in the presence of Na ions. Serum was fractionated in three main peaks. The soluble fraction of liver was fractionated in a similar pattern as of serum, but the first peak contained nucleic acid and lipoprotein. The second contained albumin. 32p radioactivity peaks of the stored sample appeared with change in patterns by autolysis from the original, and were observed wide based and continuous figures in retarded peaks. The correlations with the first peak and retarded peaks were represented by the analysis of phosphorus compounds and electrophoresis. In lipid analysis, both diglyceride and monoglyceride gradually decreased, and phospholipid pattern was observed to increase in retarded peaks by autolysis. Lipoprotein or lipid-albumin complex was gradually converted to smaller molecular weight compounds, and appeared in retarded peaks.</p

Messenger RNA coding for only the alpha subunit of the rat brain Na channel is sufficient for expression of functional channels in Xenopus oocytes

Several cDNA clones coding for the high molecular weight (alpha) subunit of the voltage-sensitive Na channel have been selected by immunoscreening a rat brain cDNA library constructed in the expression vector lambda gt11. As will be reported elsewhere, the amino acid sequence translated from the DNA sequence shows considerable homology to that reported for the Electrophorus electricus electroplax Na channel. Several of the cDNA inserts hybridized with a low-abundance 9-kilobase RNA species from rat brain, muscle, and heart. Sucrose-gradient fractionation of rat brain poly(A) RNA yielded a high molecular weight fraction containing this mRNA, which resulted in functional Na channels when injected into oocytes. This fraction contained undetectable amounts of low molecular weight RNA. The high molecular weight Na channel RNA was selected from rat brain poly(A) RNA by hybridization to a single-strand antisense cDNA clone. Translation of this RNA in Xenopus oocytes resulted in the appearance of tetrodotoxin-sensitive voltage-sensitive Na channels in the oocyte membrane. These results demonstrate that mRNA encoding the alpha subunit of the rat brain Na channel, in the absence of any beta-subunit mRNA, is sufficient for translation to give functional channels in oocytes

Mechanical properties of plastics predetermined by empirical method

To predetermine the mechanical properties of rigid plastics as a function of plasticizer content and composition, a set of equations has been empirically derived. These relate strain rate, yield stress, temperature, and weight fraction of the plasticizer

The Effect of Molecular Weight on the Retrogradation of Amylose

The effect of molecular weight on the rate of retrogradation of amylose was studied by monitoring turbidity (corrected for molecular shape) with a light scattering photometer. The results obtained showed that by acid modification of the amylose fraction of starch, the chain length of amylose molecules were reduced. The rate of retrogradation increased with decreasing molecular weight until a maximum was reached at 1 1/2 hours of hydrolysis. The rate of retrogradation then decreased with further decreasing molecular weight until retrogradation began to lessen

Phase separation effects and the nematic-isotropic transition in polymer and low molecular weight liquid crystals doped with nanoparticles

Properties of the nematic–isotropic phase transition in polymer and low molecular weight liquid crystals doped with nanoparticles have been studied both experimentally and theoretically in terms of molecular mean-field theory. The variation of the transition temperature and the transition heat with the increasing volume fraction of CdSe quantum dot nanoparticles in copolymer and low molecular weight nematics has been investigated experimentally and the data are interpreted using the results of the molecular theory which accounts for a possibility of phase separation when the system undergoes the nematic–isotropic transition. The theory predicts that the nematic and isotropic phases with different concentrations of nanoparticles may coexist over a broad temperature range, but only if the nanoparticle volume fraction exceeds a certain threshold value which depends on the material parameters. Such unusual phase separation effects are determined by the strong interaction between nanoparticles and mesogenic groups and between nanoparticles themselves