Intrinsically stretchable and transparent thin-film transistors based on printable silver nanowires, carbon nanotubes and an elastomeric dielectric.

Thin-film field-effect transistor is a fundamental component behind various mordern electronics. The development of stretchable electronics poses fundamental challenges in developing new electronic materials for stretchable thin-film transistors that are mechanically compliant and solution processable. Here we report the fabrication of transparent thin-film transistors that behave like an elastomer film. The entire fabrication is carried out by solution-based techniques, and the resulting devices exhibit a mobility of ∼30 cm(2) V(-1) s(-1), on/off ratio of 10(3)-10(4), switching current >100 μA, transconductance >50 μS and relative low operating voltages. The devices can be stretched by up to 50% strain and subjected to 500 cycles of repeated stretching to 20% strain without significant loss in electrical property. The thin-film transistors are also used to drive organic light-emitting diodes. The approach and results represent an important progress toward the development of stretchable active-matrix displays

Stretchable Piezoelectric Power Generators Based on ZnO Thin Films on Elastic Substrates

The paper describes a stretchable, microfabricated power generator that will be attached on the skin and will produce energy based on the movements of the human body. The device was fabricated on a polymeric, elastomeric, poly(dimethylsiloxane) (PDMS) sheet. It consists of a piezoelectric thin film of ZnO sandwiched between two stretchable gold electrodes. An innovative technique was used for the deposition of ZnO thin film on the gold electrode-coated polymeric substrate at low temperatures below 150C. This is the first attempt to use a uniform film of ZnO, for energy harvesting. The ZnO film had the thickness at the submicron scale and the surface at the centimeter scale. We demonstrated that under a strain of 8% the voltage output from this power generator was equal to 2 V, the power output was equal to 160 W and the corresponding power density was 1.27 mW/cm2. This device has great potential for application in power sensors attached on the human body, such as temperature sensors or wearable electrocardiography systems

Materials, Mechanics, and Patterning Techniques for Elastomer-Based Stretchable Conductors

Stretchable electronics represent a new generation of electronics that utilize soft, deformable elastomers as the substrate or matrix instead of the traditional rigid printed circuit boards. As the most essential component of stretchable electronics, the conductors should meet the requirements for both high conductivity and the capability to maintain conductive under large deformations such as bending, twisting, stretching, and compressing. This review summarizes recent progresses in various aspects of this fascinating and challenging area, including materials for supporting elastomers and electrical conductors, unique designs and stretching mechanics, and the subtractive and additive patterning techniques. The applications are discussed along with functional devices based on these conductors. Finally, the review is concluded with the current limitations, challenges, and future directions of stretchable conductors

Exploration of Miniature Flexible Devices Empowered by Van Der Waals Material

This research mainly focuses on the fabrication of miniature flexible devices empowered by van der Waals materials. Through the extensive experiments contained in this thesis, by exploring the characteristics of van der Waals materials, optimizing the manufacturing process of lithography technology, and characterizing the photoelectric performance of micro devices, this thesis has promoted the development of micro flexible device manufacturing and expanded its applications in the fields of biological detection, medical treatment, and environmental monitoring. We introduced a miniature van der Waals semiconductor empowered vertical color sensor, which saves three times the volume space compared to the traditional planer color sensor and includes multiple optical aberration correction functions as well. Such a small red, green, and blue (RGB) color sensor can be applied in bionic eyes, breaking through the limitations of existing black and white recognition. On this basis, we further explored the stretchability of two-dimensional materials represented by MoS2. We proposed a chemical treatment method combined with gold nanoparticles and (3-mercaptopropyl)trimethoxysilane (MPTMS) to realize the relocation of flexible micro devices. This method improves the adhesion between the material layer and the flexible substrate (PDMS), which significantly increases the flexible device stretchability, and prolongs its service life. Through the above work, this thesis explores the van der Waals materials’ properties, and optimizes the manufacturing process of micro devices, further exerts the advantages of material flexibility, therefore provides more possibilities for the development of smart wearable devices, biomedical detection, and other fields

Dynamical magnetic anisotropy and quantum phase transitions in a vibrating spin-1 molecular junction

We study the electronic transport through a spin-1 molecule in which mechanical stretching produces a magnetic anisotropy. In this type of device, a vibron mode along the stretching axis will couple naturally to the molecular spin. We consider a single molecular vibrational mode and find that the electron-vibron interaction induces an effective correction to the magnetic anisotropy that shifts the ground state of the device toward a non-Fermi liquid phase. A transition into a Fermi liquid phase could then be achieved, by means of mechanical stretching, passing through an underscreened spin-1 Kondo regime. We present numerical renormalization group results for the differential conductance, the spectral density, and the magnetic susceptibility across the transition.Comment: 7 pages, 7 figure

Soft chromophore featured liquid porphyrins and their utilization toward liquid electret applications

Optoelectronically active viscous liquids are ideal for fabricating foldable/stretchable electronics owing to their excellent deformability and predictable π-unit-based optoelectronic functions, which are independent of the device shape and geometry. Here we show, unprecedented 'liquid electret' devices that exhibit mechanoelectrical and electroacoustic functions, as well as stretchability, have been prepared using solvent-free liquid porphyrins. The fluidic nature of the free-base alkylated-tetraphenylporphyrins was controlled by attaching flexible and bulky branched alkyl chains at different positions. Furthermore, a subtle porphyrin ring distortion that originated from the bulkiness of alkyl chains was observed. Its consequences on the electronic perturbation of the porphyrin-unit were precisely elucidated by spectroscopic techniques and theoretical modelling. This molecular design allows shielding of the porphyrin unit by insulating alkyl chains, which facilitates its corona-charged state for a long period under ambient conditions

Rubbery electronics and sensors from intrinsically stretchable elastomeric composites of semiconductors and conductors

A general strategy to impart mechanical stretchability to stretchable electronics involves engineering materials into special architectures to accommodate or eliminate the mechanical strain in nonstretchable electronic materials while stretched. We introduce an all solution-processed type of electronics and sensors that are rubbery and intrinsically stretchable as an outcome from all the elastomeric materials in percolated composite formats with P3HT-NFs [poly(3-hexylthiophene-2,5-diyl) nanofibrils] and AuNP-AgNW (Au nanoparticles with conformally coated silver nanowires) in PDMS (polydimethylsiloxane). The fabricated thin-film transistors retain their electrical performances by more than 55% upon 50% stretching and exhibit one of the highest P3HT-based field-effect mobilities of 1.4 cm2/V.s, owing to crystallinity improvement. Rubbery sensors, which include strain, pressure, and temperature sensors, show reliable sensing capabilities and are exploited as smart skins that enable gesture translation for sign language alphabet and haptic sensing for robotics to illustrate one of the applications of the sensors

Transparent and Flexible Radio Frequency (RF) Structures

With increasing demand for a wearable devices, medical devices, RFID, and small devices, there is a growing interest in the field of transparent and flexible electronics. In order to realize optically transparent and flexible microwave components, novel materials can be used. The combination of new materials and radio frequency (RF) structures can open interesting perspectives for the implementation of cost effective wireless communication system and wearable device design. The transparent and flexible RF structures can facilitate its application in the transparent and curved surfaces. In this dissertation, we present several demonstrations, all based on optically transparent and flexible materials and structures. We firstly demonstrate an optically transparent, flexible, polarization-independent, and broadband microwave absorber. The bow-tie shaped array which possesses double resonances is designed and measured. The combined resonances lead to more than 90% total absorption covering a wide frequency range from 5.8 to 12.2 GHz. Due to the use of thin metal and PDMS, the whole structure is optically transparent and flexible. Secondly, we demonstrate a new method for fabricating transparent and stretchable radiofrequency small antennas by using stretchable micromesh structures. Size reduction is achieved by using the zeroth-order resonant (ZOR) property. The antennas consist of a series of tortuous micromesh structures, which provides a high degree of freedom for stretching when encapsulated in elastomeric polymers and is optically transparent. Accordingly, these antennas can be stretched up to 40% in size without breaking. The resonant frequency of the antennas is linearly reconfigurable from 2.94 GHz to 2.46 GHz upon stretching. Next, we describe an ultra-low profile and flexible triple-polarization antenna. It is realized by using ZOR array antenna with high port-to-port isolation. This flexible antenna is fabricated with a flexible substrate and silver nanowire vias to be used in various wearable applications. Lastly, we demonstrate a dual-band tri-polarized antenna based on half-mode hexagonal (HMH) SIW structure. CRLH HMHSIW antenna and ZOR HMHSIW antenna are designed to have dual-band operating frequencies. This novel antenna can provide much improved wireless communication efficiency for the WBAN system under various incident field angles and polarizations.PHDElectrical EngineeringUniversity of Michigan, Horace H. Rackham School of Graduate Studieshttps://deepblue.lib.umich.edu/bitstream/2027.42/147562/1/tjang_1.pd

Facile fabrication of stretchable Ag nanowire/polyurethane electrodes using high intensity pulsed light

Silver nanowires (AgNWs) have emerged as a promising nanomaterial for next generation stretchable electronics. However, until now, the fabrication of AgNW-based components has been hampered by complex and time-consuming steps. Here, we introduce a facile, fast, and one-step methodology for the fabrication of highly conductive and stretchable AgNW/polyurethane (PU) composite electrodes based on a high-intensity pulsed light (HIPL) technique. HIPL simultaneously improved wire-wire junction conductivity and wire-substrate adhesion at room temperature and in air within 50 mu s, omitting the complex transfer-curing-implanting process. Owing to the localized deformation of PU at interfaces with AgNWs, embedding of the nanowires was rapidly carried out without substantial substrate damage. The resulting electrode retained a low sheet resistance (high electrical conductivity) of <10 Omega/sq even under 100% strain, or after 1,000 continuous stretching-relaxation cycles, with a peak strain of 60%. The fabricated electrode has found immediate application as a sensor for motion detection. Furthermore, based on our electrode, a light emitting diode (LED) driven by integrated stretchable AgNW conductors has been fabricated. In conclusion, our present fabrication approach is fast, simple, scalable, and cost-efficient, making it a good candidate for a future roll-to-roll process