Radioisotope thermal photovoltaic application of the GaSb solar cell

An examination of a RTVP (radioisotopic thermophotovoltaic) conceptual design has shown a high potential for power densities well above those achievable with radioisotopic thermoelectric generator (RTG) systems. An efficiency of 14.4 percent and system specific power of 9.25 watts/kg were predicted for a system with sixteen GPHS (general purpose heat source) sources operating at 1100 C. The models also showed a 500 watt system power by the strontium-90 isotope at 1200 C at an efficiency of 17.0 percent and a system specific power of 11.8 watts/kg. The key to this level of performance is a high-quality photovoltaic cell with narrow bandgap and a reflective rear contact. Recent work at Boeing on GaSb cells and transparent back GaAs cells indicate that such a cell is well within reach

Evaluation of PV technology implementation in the building sector

This paper presents a simulation case that shows the impact on energy consumption of a building applying photovoltaic shading systems. In order to make photovoltaic application more economical, the effect of a photovoltaic facade as a passive cooling system can result in a considerable energy cost reduction, with positive influence on the payback time of the photovoltaic installation. Photovoltaic shading systems can be applied to both refurbishment of old buildings and to new-build, offering attractive and environmentally integrated architectural solutions

DC-DC Boost Converter with Constant Output Voltage for Grid Connected Photovoltaic Application System

The main purpose of this paper is to introduce an approach to design a DC-DC boost converter with constant output voltage for grid connected photovoltaic application system. The boost converter is designed to step up a fluctuating solar panel voltage to a higher constant DC voltage. It uses voltage feedback to keep the output voltage constant. To do so, a microcontroller is used as the heart of the control system which it tracks and provides pulse-width-modulation signal to control power electronic device in boost converter. The boost converter will be able to direct couple with grid-tied inverter for grid connected photovoltaic system. Simulations were performed to describe the proposed design. Experimental works were carried out with the designed boost converter which has a power rating of 100 W and 24 V output voltage operated in continuous conduction mode at 20 kHz switching frequency. The test results show that the proposed design exhibits a good performance

Single Phase Voltage Source Inverter Photovoltaic Application

Photovoltaic applications have been developing and spreading rapidly in recent times. This paper describes the control strategy of the Voltage Source Inverter that is the important tail end of many photovoltaic applications.In order to supply the grid with a sinusoidal line current without harmonic distortion, the inverter is connected to the supply network via a L-C-L filter. The output current is controlled by the hysteresis controller. To improve the behaviors of the L-C-L filter, active damping of the filter is being used. This paper discusses controller design and simulation results

Review of stand-alone photovoltaic application projects sponsored by US DOE and US AID

Experience with dc photovoltaic systems (without backup power) and ranging in output from 23 to 3,500 peak watts, in a wide range of environmental conditions and with a wide range of insolation, is described. Cooperation of NASA with other government agencies resulted in the installation of an air pollution monitor in New Jersey, a seismic sensor in Hawaii, power for lookout towers in national forests in California, an electric power system for a Papago Indian village in Arizona, and a power system for a grain mill and water pump in Tangaye, Upper Volta. Significant operational results are discussed and system reliability is assessed for the 20 experimental systems installed since 1976. Additional systems to be installed overseas are highlighted, and economic factors are considered

Ideal Bandgap in a 2D Ruddlesden-Popper Perovskite Chalcogenide for Single-junction Solar Cells

Transition metal perovskite chalcogenides (TMPCs) are explored as stable, environmentally friendly semiconductors for solar energy conversion. They can be viewed as the inorganic alternatives to hybrid halide perovskites, and chalcogenide counterparts of perovskite oxides with desirable optoelectronic properties in the visible and infrared part of the electromagnetic spectrum. Past theoretical studies have predicted large absorption coefficient, desirable defect characteristics, and bulk photovoltaic effect in TMPCs. Despite recent progresses in polycrystalline synthesis and measurements of their optical properties, it is necessary to grow these materials in high crystalline quality to develop a fundamental understanding of their optical properties and evaluate their suitability for photovoltaic application. Here, we report the growth of single crystals of a two-dimensional (2D) perovskite chalcogenide, Ba3Zr2S7, with a natural superlattice-like structure of alternating double-layer perovskite blocks and single-layer rock salt structure. The material demonstrated a bright photoluminescence peak at 1.28 eV with a large external luminescence efficiency of up to 0.15%. We performed time-resolved photoluminescence spectroscopy on these crystals and obtained an effective recombination time of ~65 ns. These results clearly show that 2D Ruddlesden-Popper phases of perovskite chalcogenides are promising materials to achieve single-junction solar cells.Comment: 4 Figure

Ionization energies of amphoteric-doped Cu2ZnSnS4: Photovoltaic application

The substitution of Cu, Sn or Zn in the quaternary Cu2ZnSnS4 semiconductor by impurities that introduce intermediate states in the energy bandgap could have important implications either for photovoltaic or spintronic applications. This allows more generation–recombination channels than for the host semiconductor. We explore and discuss this possibility by obtaining the ionization energies from total energy first-principles calculations. The three substitutions of Cu, Sn and Zn by impurities are analyzed. From these results we have found that several impurities have an amphoteric behavior with the donor and acceptor energies in the energy bandgap. In order to analyze the role of the ionization energies in both the radiative and non-radiative processes, the host energy bandgap and the acceptor and the donor energies have been obtained as a function of the inward and outward impurity-S displacements. We carried out the analysis for both the natural and synthetic CZTS. The results show that the ionization energies are similar, whereas the energy band gaps are different