Current-voltage characteristics of asymmetric double-barrier Josephson junctions

We develop a theory for the current-voltage characteristics of diffusive superconductor-normal metal-superconductor Josephson junctions with resistive interfaces and the distance between the electrodes smaller than the superconducting coherence length. The theory allows for a quantitative analytical and numerical analysis in the whole range of the interface transparencies and asymmetry. We focus on the regime of large interface resistance compared to the resistance of the normal region, when the electron-hole dephasing in the normal region is significant and the finite length of the junction plays a role. In the limit of strong asymmetry we find pronounced current structures at the combination subharmonics of $\Delta+\Delta_g$, where $\Delta_g$ is the proximity minigap in the normal region, in addition to the subharmonics of the energy gap $2\Delta$ in the electrodes. In the limit of rather transparent interfaces, our theory recovers a known formula for the current in a short mesoscopic connector - a convolution of the current through a single-channel point contact with the transparency distribution for an asymmetric double-barrier potential.Comment: 10 pages, 3 figure

Proceedings of the International RILEM Conference Materials, Systems and Structures in Civil Engineering segment on Service Life of Cement-Based Materials and Structures

Vol. 1O volume II encontra-se disponível em: http://hdl.handle.net/1822/4390

International RILEM Conference on Materials, Systems and Structures in Civil Engineering Conference segment on Service Life of Cement-Based Materials and Structures

Vol. 2O volume I encontra-se disponível em: http://hdl.handle.net/1822/4341

Synthetic, spectroscopic, and electrochemical studies on complexes of ruthernium an osmium

CHAPTER 1 Reviews triply halide bridged binuclear ruthenium systems of the type [L₍₃₋ₓ₎ ClₓRuCl₃ RuClᵧL₍₃₋ᵧ₎] in oxidation states ranging from Ru₂(II/II) to Ru₂(III/III). In the present work, organo-soluble salts of [Ru₂X₉]³⁻ (X = CI,Br) are described and their electrochemical, magnetic and spectroscopic properties investigated. Electrosynthesis of the oxidised derivatives [Ru₂X₉]²⁻ and [Ru₂X₉]⁻, and their characterisation by electronic absorption spectroscopy and magnetic susceptibility measurements have helped to elucidate their electronic nature, leading to a greater understanding of the nature of ruthenium triple halide-bridged complexes in general. CHAPTER 2 Mixed-valence triple chloro bridged binuclear complexes of ruthenium bearing NH₃ or H₂0 terminal ligands such as [Ru₂Cl₃(NH₃)₆]²⁺ and [Ru₂Cl₃(H₂O)₆]²⁺ are discussed. A comprehensive examination of the redox properties of [Ru₂Cl₃(NH₃)₆]²⁺ achieved in non-aqueous media, and of optical spectra in differing oxidation states, are reported. The underlying metal metal interactions are discussed in relation to the influence of terminal ligand basicity. CHAPTER 3 A sequence of binuclear complexes of the type [Ru₂ Brₓ(AsR₃) (₉₋ₓ)] (x = 5,6)] have been synthesised and previous suggestions regarding their structure as indicated by esr studies and their electrochemical behaviour, have been enhanced and reinforced. CHAPTER 4 Electroreduction of mer [OsCl₃ (PMe₂Ph)₃ ] in a variety of coordinating media has produced a range of 6-coordinate Os(II) monomeric complexes in two separable isomeric forms. In non-coordinating solvents the Os(III) complex is found to expel chloride under most conditions, to give a detectable 5-coordinate intermediate, which can react under favourable conditions to produce doubly- and triply-bridged binuclear species. This series of electro-initiated reactions has so far yielded many separate complexes, identified by both spectroscopic methods and voltammetric data. APPENDIX 1 Voltammetric measurements establish a reversible one-electron oxidation for the complex [RuCl₅NO]²⁻. Bulk electrogeneration of the resulting oxidised species has allowed i.r, esr and magnetic susceptibility measurements to confirm its existance as the low-spin [RuCl₅NO]⁻ ion, in contrast to previous reports. APPENDIX 2 Electrochemical studies on [Os₂(OCOR)₄Cl₂] (R = Et, ⁿPr) and [Os₂(hp)₄ CI₂] (hp = hydroxypyridinate anion) establish a reversible one-electron reduction for these complexes, producing the first examples of species containing the Os₂⁵⁺ core. These derivatives have been characterised by voltammetry, electronic absorption spectroscopy, esr spectroscopy and magnetic susceptibility measurements

Miniaturized Electron Optics based on Self-Assembled Micro Coils

Zahlreiche Geräte, die in den Naturwissenschaen, in der Industrie und im Gesundheitswesen unverzichtbar sind, basieren auf Strahlen schneller geladener Teilchen. Dazu zählen unter anderem Elektronen- und Ionenmikroskope, entsprechende Lithographiestrahlanlagen und Röntgenstrahlungsquellen. Magnetische Optiken, die Strahlen geladener Teilchen ablenken, formen und fokussieren, sind das Rückgrat aller Geräte die mit hochenergetischen Teilchen arbeiten, da sie im Vergleich zu Optiken, die auf elektrischen Feldern basieren, bei hohen Teilchengeschwindigkeiten eine überlegene optische Leistung aufweisen. Konventionelle makroskopische magnetische Optiken sind jedoch groß, teuer und platzraubend, nicht hochfrequenzfähig und erfordern aktive (Wasser-)Kühlung zur Wärmeabfuhr. Sie sind daher für Mehrstrahlinstrumente, miniaturisierte Anwendungen und schnelle Strahlmanipulation ungeeignet, die für zukünftige Fortschritte in der Nanofabrikation und -analyse gebraucht werden. Im Rahmen dieser Arbeit wurden die ersten magnetischen selbst-assemblierenden Mikro-Origami-Elektronenoptiken entwickelt, hergestellt und charakterisiert. Mit dem verwendeten Miniaturisierungsansatz können, bei ähnlicher optischer Leistung, alle oben genannten Nachteile von konventionellen magnetischen Optiken überwunden werden. Die außergewöhnlichen Eigenschaften dieser optischen Elemente werden durch die einzigartigen Merkmale der Mikrospulen ermöglicht: geringe Größe, geringe Induktivität und geringer Widerstand. Im Rahmen dieser Arbeit wurden unter anderem adaptive Phasenplaen hergestellt, die Elektronenvortexstrahlen mit einem bislang unerreichten Bahndrehimpuls von bis zu mehreren 1000 ̄h erzeugen. Des Weiteren wurden schnelle Elektronenstrahldeflektoren zur Strahlablenkung, zum zweidimensionalen Rastern und für stroboskopische Experimente gefertigt. Sie besitzen eine Ablenkleistung im mrad-Bereich für 300 kV Elektronen und einen Frequenzdurchgang bis zu 100 MHz. Darüber hinaus wurden miniaturisierte adrupollinsen mit Brennweiten kleiner als 46 mm für 300 kV Elektronen entwickelt. Diese drei Arten elektronenoptischer Elemente sind von großem Interesse für verschiedenste Anwendungen in der Nanofabrikation und -analyse, da sie unter anderem als integrale Bestandteile von zu entwickelnden Mehrstrahlinstrumenten, miniaturisierten Geräten und stroboskopischen Messaufbauten dienen können.:1 Introduction 1.1 Charged Particle Optics 1.2 Miniaturized Charged Particle Optics 1.3 Phase Plates for Transmission Electron Microscopy 2 Charged Particle Optics 2.1 Hamiltonian Formalism 2.2 Gaussian Matrix Optics 2.3 Transfer Matrices of Magnetic Elements 2.3.1 Single Quadrupole 2.3.2 Quadrupole Multiplets 2.3.2.1 Quadrupole Doublet 2.3.2.2 Quadrupole Triplet 2.3.2.3 Higher Order Quadrupole Multiplets 2.4 Scaling Laws for Charged Particle Optics 2.4.1 Thin Film 2.4.2 Electrostatic Scaling Laws 2.4.3 Magnetic Scaling Laws 3 Design and Fabrication of Miniaturized Electron Optics 3.1 Basics of Polymer-Based Self-Assembly Technology 3.2 Basic Coil Design and Magnetic Field Simulations 3.3 CoFeSiB-Pyrex Core-Shell Micro Wires 3.4 Fabrication of Self-Assembled Micro Coil Devices 4 Optical Properties of Self-Assembled Miniaturized Electron Optics 4.1 Electron Vortex Phase Plate 4.1.1 Projected Magnetic Fields 4.1.2 Vortex Beam Characteristics 4.2 Miniaturized Deflector 4.3 Quadrupole Focusing Optic 4.4 High Frequency Characteristics of Self-Assembled Electron Optics 5 Summary and Outlook 5.1 Applications of Electron Vortex Beams with Large OAM 5.2 Optics of Large Optical Power for Pulsed Instruments 5.3 Stroboscopic TEM Measurements 5.4 Miniaturized Wigglers, Undulators and Free Electron Lasers 5.5 Towards Integrated Electron Optical SystemsBeams of highly accelerated charged particles are essential for numerous indispensable devices used throughout natural sciences, industry and the healthcare sector, e.g., electron and ion microscopes, charged particle lithography machines and X-ray radiation sources. Magnetic charged particle optics that deflect, shape and focus high-energy charged particles are the backbone of all such devices, because of their superior optical power compared to electric field optics at large particle velocities. Conventional macroscopic magnetic optics, however, are large, costly and bulky, not high frequency capable and require active cooling for heat dissipation. They are therefore unsuitable for fast beam manipulation, multibeam instrumentation, and miniaturized applications, much desired for future advances in nanofabrication and analysis. The first on-chip micro-sized magnetic charged particle optics realized via a self-assembling micro-origami process were designed, fabricated and characterized within the frame of this work. The utilized micro-miniaturization approach overcomes all the aforementioned obstacles for conventional magnetic optics, while maintaining similar optical power. The exceptional properties of these optical elements are rendered possible by the unique features of strain-engineered micro-coils: small size, small inductance and small resistivity. Within the frame of this work, adaptive phase plates were fabricated, which generate electron vortex beams with an unprecedented orbital angular momentum of up to several 1000 ̄h. Furthermore, fast electron beam deflectors for beam blanking, two-dimensional scanning and stroboscopic experiments were manufactured. They possess a deflection power in the mrad regime for 300 kV electrons and a high frequency passband up to 100 MHz. Additionally, miniaturized strong quadrupole lenses with focal lengths down to 46 mm for 300 kV electrons have been developed. These three types of electron optical elements are of great interest for a wide range of applications in nanofabrication and analysis, as they serve as integral components of future multibeam instruments, miniaturized devices, and stroboscopic measurement setups to be developed.:1 Introduction 1.1 Charged Particle Optics 1.2 Miniaturized Charged Particle Optics 1.3 Phase Plates for Transmission Electron Microscopy 2 Charged Particle Optics 2.1 Hamiltonian Formalism 2.2 Gaussian Matrix Optics 2.3 Transfer Matrices of Magnetic Elements 2.3.1 Single Quadrupole 2.3.2 Quadrupole Multiplets 2.3.2.1 Quadrupole Doublet 2.3.2.2 Quadrupole Triplet 2.3.2.3 Higher Order Quadrupole Multiplets 2.4 Scaling Laws for Charged Particle Optics 2.4.1 Thin Film 2.4.2 Electrostatic Scaling Laws 2.4.3 Magnetic Scaling Laws 3 Design and Fabrication of Miniaturized Electron Optics 3.1 Basics of Polymer-Based Self-Assembly Technology 3.2 Basic Coil Design and Magnetic Field Simulations 3.3 CoFeSiB-Pyrex Core-Shell Micro Wires 3.4 Fabrication of Self-Assembled Micro Coil Devices 4 Optical Properties of Self-Assembled Miniaturized Electron Optics 4.1 Electron Vortex Phase Plate 4.1.1 Projected Magnetic Fields 4.1.2 Vortex Beam Characteristics 4.2 Miniaturized Deflector 4.3 Quadrupole Focusing Optic 4.4 High Frequency Characteristics of Self-Assembled Electron Optics 5 Summary and Outlook 5.1 Applications of Electron Vortex Beams with Large OAM 5.2 Optics of Large Optical Power for Pulsed Instruments 5.3 Stroboscopic TEM Measurements 5.4 Miniaturized Wigglers, Undulators and Free Electron Lasers 5.5 Towards Integrated Electron Optical System

Development and modelling of a versatile active micro-electrode array for high density in-vivo and in-vitro neural signal investigation

The electrophysiological observation of neurological cells has allowed much knowledge to be gathered regarding how living organisms are believed to acquire and process sensation. Although much has been learned about neurons in isolation, there is much more to be discovered in how these neurons communicate within large networks. The challenges of measuring neurological networks at the scale, density and chronic level of non invasiveness required to observe neurological processing and decision making are manifold, however methods have been suggested that have allowed small scale networks to be observed using arrays of micro-fabricated electrodes. These arrays transduce ionic perturbations local to the cell membrane in the extracellular fluid into small electrical signals within the metal that may be measured. A device was designed for optimal electrical matching to the electrode interface and maximal signal preservation of the received extracellular neural signals. Design parameters were developed from electrophysiological computer simulations and experimentally obtained empirical models of the electrode-electrolyte interface. From this information, a novel interface based signal filtering method was developed that enabled high density amplifier interface circuitry to be realised. A novel prototype monolithic active electrode was developed using CMOS microfabrication technology. The device uses the top metallization of a selected process to form the electrode substrate and compact amplification circuitry fabricated directly beneath the electrode to amplify and separate the neural signal from the baseline offsets and noise of the electrode interface. The signal is then buffered for high speed sampling and switched signal routing. Prototype 16 and 256 active electrode array with custom support circuitry is presented at the layout stage for a 20 μm diameter 100 μm pitch electrode array. Each device consumes 26.4 μW of power and contributes 4.509 μV (rms) of noise to the received signal over a controlled bandwidth of 10 Hz - 5 kHz. The research has provided a fundamental insight into the challenges of high density neural network observation, both in the passive and the active manner. The thesis concludes that power consumption is the fundamental limiting factor of high density integrated MEA circuitry; low power dissipation being crucial for the existence of the surface adhered cells under measurement. With transistor sizing, noise and signal slewing each being inversely proportional to the dc supply current and the large power requirements of desirable ancillary circuitry such as analogue-to-digital converters, a situation of compromise is approached that must be carefully considered for specific application design

MODELLING AND SIMULATION OF HIGH VOLTAGE DIRECT CURRENT TRANSMISSION SYSTEM

High voltage direct current (HVDC) is one of the technologies in electrical transmission system. It is established as an alternative to AC transmission system. The main purpose ofthis project is to model and simulate the HVDC system by using software. The scope of this project is to cover the concepts about transmission system, specifically HVDC.In fact, familiarization with softwaresuch as ATPwill be covered too as it will assist in the modeling and simulation stage. The systematic approaches such as research, modeling, simulation, validation and troubleshooting in accomplishing this project are discussed in the chapter of methodology. Assessments on several softwares were conducted in order to identify the best software in studying the behavior of HVDC system. Besides that, data taken from real HVDC project, which is EGAT/TNB HVDC Interconnection Project, will be discussed too. Comparison between the simulated results and the real data were carried out in order to validate the findings from the simulation. Based on the evaluation made on the relevant software, it is found that ATP is the best software to be utilized in this project. Subsequently, simulations were conducted by using ATP and desired waveforms were obtained since they managed to resemble the real data and consistent with the theoretical concept

金属有機構造体からの機能性多孔性炭素材料の合成

早大学位記番号:新7976早稲田大