Growth mechanism of nanocrystals in solution: ZnO, a case study

We investigate the mechanism of growth of nanocrystals from solution using the case of ZnO. Spanning a wide range of values of the parameters, such as the temperature and the reactant concentration, that control the growth, our results establish a qualitative departure from the widely accepted diffusion controlled coarsening (Ostwald ripening) process quantified in terms of the Lifshitz-Slyozov-Wagner theory. Further, we show that these experimental observations can be qualitatively and quantitatively understood within a growth mechanism that is intermediate between the two well-defined limits of diffusion control and kinetic control.Comment: 10 pages, 4 figure

Growth mechanism of nanostructured superparamagnetic rods obtained by electrostatic co-assembly

We report on the growth of nanostructured rods fabricated by electrostatic co-assembly between iron oxide nanoparticles and polymers. The nanoparticles put under scrutiny, {\gamma}-Fe2O3 or maghemite, have diameter of 6.7 nm and 8.3 nm and narrow polydispersity. The co-assembly is driven by i) the electrostatic interactions between the polymers and the particles, and by ii) the presence of an externally applied magnetic field. The rods are characterized by large anisotropy factors, with diameter 200 nm and length comprised between 1 and 100 {\mu}m. In the present work, we provide for the first time the morphology diagram for the rods as a function of ionic strength and concentration. We show the existence of a critical nanoparticle concentration and of a critical ionic strength beyond which the rods do not form. In the intermediate regimes, only tortuous and branched aggregates are detected. At higher concentrations and lower ionic strengths, linear and stiff rods with superparamagnetic properties are produced. Based on these data, a mechanism for the rod formation is proposed. The mechanism proceeds in two steps : the formation and growth of spherical clusters of particles, and the alignment of the clusters induced by the magnetic dipolar interactions. As far as the kinetics of these processes is concerned, the clusters growth and their alignment occur concomitantly, leading to a continuous accretion of particles or small clusters, and a welding of the rodlike structure.Comment: 15 pages, 10 figures, one tabl

The stability of a rising droplet: an inertialess nonmodal growth mechanism

Prior modal stability analysis (Kojima et al., Phys. Fluids, vol. 27, 1984) predicted that a rising or sedimenting droplet in a viscous fluid is stable in the presence of surface tension no matter how small, in contrast to experimental and numerical results. By performing a non-modal stability analysis, we demonstrate the potential for transient growth of the interfacial energy of a rising droplet in the limit of inertialess Stokes equations. The predicted critical capillary numbers for transient growth agree well with those for unstable shape evolution of droplets found in the direct numerical simulations of Koh & Leal (Phys. Fluids, vol. 1, 1989). Boundary integral simulations are used to delineate the critical amplitude of the most destabilizing perturbations. The critical amplitude is negatively correlated with the linear optimal energy growth, implying that the transient growth is responsible for reducing the necessary perturbation amplitude required to escape the basin of attraction of the spherical solution.Comment: 11pages, 7 figure

On the linear growth mechanism driving the stationary accretion shock instability

During stellar core collapse, which eventually leads to a supernovae explosion, the stalled shock is unstable due to the standing accretion shock instability (SASI). This instability induces large-scale non spherical oscillations of the shock, which have crucial consequences on the dynamics and the geometry of the explosion. While the existence of this instability has been firmly established, its physical origin remains somewhat uncertain. Two mechanisms have indeed been proposed to explain its linear growth. The first is an advective-acoustic cycle, where the instability results from the interplay between advected perturbations (entropy and vorticity) and an acoustic wave. The second mechanism is purely acoustic and assumes that the shock is able to amplify trapped acoustic waves. Several arguments favouring the advective-acoustic cycle have already been proposed, however none was entirely conclusive for realistic flow parameters. In this article we give two new arguments which unambiguously show that the instability is not purely acoustic, and should be attributed to the advective-acoustic cycle. First, we extract a radial propagation timescale by comparing the frequencies of several unstable harmonics that differ only by their radial structure. The extracted time matches the advective-acoustic time but strongly disagrees with a purely acoustic interpretation. Second, we present a method to compute purely acoustic modes, by artificially removing advected perturbations below the shock. All these purely acoustic modes are found to be stable, showing that the advected wave is essential to the instability mechanism.Comment: 17 pages, 10 figures, accepted for publication in MNRA

Rapid formation of black holes in galaxies: a self-limiting growth mechanism

We present high-quality fluid dynamical simulations of isothermal gas flows in a rotating barred potential. We show that a large quantity of gas is driven right into the nucleus of a model galaxy when the potential lacks a central mass concentration, but the inflow stalls at a nuclear ring in comparison simulations that include a central massive object. The radius of the nuclear gas ring increases linearly with the mass of the central object. We argue that bars drive gas right into the nucleus in the early stages of disk galaxy formation, where a nuclear star cluster and perhaps a massive black hole could be created. The process is self-limiting, however, because inflow stalls at a nuclear ring once the mass of gas and stars in the nucleus exceeds ~1% of the disk mass, which shuts off rapid growth of the black hole. We briefly discuss the relevance of these results to the seeding of massive black holes in galaxies, the merger model for quasar evolution, and the existence of massive black holes in disk galaxies that lack a significant classical bulge.Comment: 11 pages, 6 figures, accepted to appear in Ap

In situ observation of mono-molecular growth steps on aqueous solution grown crystals and the transport of molecules to the crystals

Direct in situ observation of mono-molecular growth steps on a crystal growing in an aqueous solution became possible. The combination of this method with high resolution Schlieren methods or interferometry, permits the growth mechanism of crystals to be investigated directly. Since the observation of growth steps on crystals is the most direct and sensitive way for investigating a crystal growth mechanism, it would contribute to revealing fundamental differences between the growth in space and on Earth. The method was recently extended to in situ observation of the growth processes at high temperatures (1800K)