SERS Detection of Graphene Oxide in Acid Catalyzed Sol-Gels

Silica sol-gel and aerogel substrates were synthesized using a modified acid catalyzed hydrolysis of tetramethyl orthosilicate method that incorporated graphene oxide and silver nanoparticles into the matrix. The effectiveness of loading of graphene oxide was monitored by UV-vis and surface enhanced Raman spectroscopy (SERS). Characterization data suggests that graphene oxide is detectable through SERS while integrated into a sol-gel and that size of silver nanoparticles has an impact on the SERS spectrum of graphene oxide

Stability of Graphene Oxide encapsulated Gold Nanorods for optical sensing purposes

This paper presents the synthesis and characterization of a graphene oxide encapsulated gold nanorod (GNR) complex, where its stability was investigated over time by recording the absorption spectra obtained using a UV/Visible spectrometer over the wavelength region of 200 nm to 1000 nm. Poly Ethylene Glycol (PEG) stablized GNRs were found to be more stable in the presence of graphene oxide dispersions compared to Cetyl Timethyl Ammonium Bromide (CTAB) stabilized GNRs. These GNR complexes, prepared with an active graphene oxide coating on the surface, are presented as a well-suited platform for the development of localized plasmon resonance-based fibre optic biosensors due to the surface functional groups of graphene oxide that can form bio-composites with other biological nanomaterials

Ultra-fast self-assembly and stabilization of reactive nanoparticles in reduced graphene oxide films.

Nanoparticles hosted in conductive matrices are ubiquitous in electrochemical energy storage, catalysis and energetic devices. However, agglomeration and surface oxidation remain as two major challenges towards their ultimate utility, especially for highly reactive materials. Here we report uniformly distributed nanoparticles with diameters around 10 nm can be self-assembled within a reduced graphene oxide matrix in 10 ms. Microsized particles in reduced graphene oxide are Joule heated to high temperature (∼1,700 K) and rapidly quenched to preserve the resultant nano-architecture. A possible formation mechanism is that microsized particles melt under high temperature, are separated by defects in reduced graphene oxide and self-assemble into nanoparticles on cooling. The ultra-fast manufacturing approach can be applied to a wide range of materials, including aluminium, silicon, tin and so on. One unique application of this technique is the stabilization of aluminium nanoparticles in reduced graphene oxide film, which we demonstrate to have excellent performance as a switchable energetic material

Hydrophobicity properties of graphite and reduced graphene oxide of the polysulfone (PSf) mixed matrix membrane

Hydrophobicity properties of graphite and reduced graphene oxide (rGO) (from exfoliated graphite/rGO) towards PSf polymer membrane characteristic and properties at different additives weight concentrations (1, 2, 3, 4 and 5 wt. %) were investigated. Both PSF/graphite and PSf/rGO membranes were characterized in term of hydrophobicity, surface bonding, surface roughness and porosity. FTIR peaks revealed that membrane with graphite and reduced graphene oxide nearly diminished their O-H bonding which was opposite to the graphene oxide peak that shows a strong O-H bonding as increased exfoliated times. These results were in line with the contact angle results that showed strong hydrophobicity of graphite and reduced graphene oxide membranes as increased these additives concentration. The effect of strong hydrophobicity in these membranes also has resulted in smoother surface roughness compared to pristine PSf membrane. Further investigation of the performance of water flux also proved that both above membranes have strong hydrophobic effect, with the lowest pure water flux rate (L/m2h) was given by PSf/rGO 3% membrane at 19.2437 L/m2h