A reconnaissance geochemical drainage survey of the Criffel-Dalbeattie granodiorite complex and its environs

Regional geochemical reconnaissance by stream sediments and panned concentrates was undertaken over an area of 850 km 2 of south-west Scotland. Rocks of Ordovician to Permian age are exposed within the area but the major part is occupied by the Criffel-Dalbeattie granodiorite complex. Multi-element analysis of the samples collected demonstrates patterns of trace element distribution related to the geology and Broad-scale patterns in the distribution of some elements reflect compositional anumber of mineralisation. variations in both the Lower Palaeozoic turbidite sequence and the Criffel- Dalbeattie granodiorite complex, both of which may be sub-divided into specific units on the basis of the geochemical data. The follow-up of copper anomalies in drainage samples from the Black Stockarton Moor area led to the discovery of porphyry-style copper mineralisation within an arcuate belt at least 5 km by 1 km within the Black Stockarton Moor subvolcanic complex and of related disseminated copper mineralisation at Screel Burn. The area to the west of the Criffel-Dalbeattie plutonic complex is also characterised by relatively high boron levels in stream sediments reflecting the widespread occurrence of tourmaline both in association with and peripheral to the copper mineralisation. Vein mineralisation, usually containing baryte in addition to base.metals, is also identifiable from the drainage survey at the eastern margin of the Criffel-Dalbeattie granodiorite; in association with the Lower Carboniferous rocks along the Solway coast; and within the Lower Palaeozoic turbidites in the west of the area

Constraining the long-term evolution of the slip rate for a major extensional fault system in the central Aegean, Greece, using thermochronology

The brittle/ductile transition is a major rheologic boundary in the crust yet little is known about how or if rates of tectonic processes are influenced by this boundary. In this study we examine the slip history of the large-scale Naxos/Paros extensional fault system (NPEFS), Cyclades, Greece, by comparing published slip rates for the ductile crust with new thermochronological constraints on slip rates in the brittle regime. Based on apatite and zircon fission-track (AFT and ZFT) and (U–Th)/He dating we observe variable slip rates across the brittle/ductile transition on Naxos. ZFT and AFT ages range from 11.8 ± 0.8 to 9.7 ± 0.8 Ma and 11.2 ± 1.6 to 8.2 ± 1.2 Ma and (U–Th)/He zircon and apatite ages are between 10.4 ± 0.4 to 9.2 ± 0.3 Ma and 10.7 ± 1.0 to 8.9 ± 0.6 Ma, respectively. On Paros, ZFT and AFT ages range from 13.1 ± 1.4 Ma to 11.1 ± 1.0 Ma and 12.7 ± 2.8 Ma to 10.5 ± 2.0 Ma while the (U–Th)/He zircon ages are slightly younger between 8.3 ± 0.4 Ma and 9.8 ± 0.3 Ma. All ages consistently decrease northwards in the direction of hanging wall transport. Most of our new thermochronological results and associated thermal modeling more strongly support the scenario of an identical fault dip and a constant or slightly accelerating slip rate of 6–8 km Myr− 1 on the NPEFS across the brittle/ductile transition. Even the intrusion of a large granodiorite body into the narrowing fault zone at 12 Ma on Naxos does not seem to have affected the thermal structure of the area in a way that would significantly disturb the slip rate. The data also show that the NPEFS accomplished a minimum total offset of 50 km between 16 and 8 Ma

Gamma-ray spectrometry in the field: Radioactive heat production in the Central Slovakian Volcanic Zone

We report 62 sets of measurements from central-southern Slovakia, obtained using a modern portable gamma-ray spectrometer, which reveal the radioactive heat production in intrusive and extrusive igneous rocks of the Late Cenozoic Central Slovakian Volcanic Zone. Sites in granodiorite of the Štiavnica pluton are thus shown to have heat production in the range ~ 2.2–4.9 μW m− 3, this variability being primarily a reflection of variations in content of the trace element uranium. Sites in dioritic parts of this pluton have a lower, but overlapping, range of values, ~ 2.1–4.4 μW m− 3. Sites that have been interpreted in adjoining minor dioritic intrusions of similar age have heat production in the range ~ 1.4–3.3 μW m− 3. The main Štiavnica pluton has zoned composition, with potassium and uranium content and radioactive heat production typically increasing inward from its margins, reflecting variations observed in other granodioritic plutons elsewhere. It is indeed possible that the adjoining dioritic rocks, hitherto assigned to other minor intrusions of similar age, located around the periphery of the Štiavnica pluton, in reality provide further evidence for zonation of the same pluton. The vicinity of this pluton is associated with surface heat flow ~ 40 mW m− 2 above the regional background. On the basis of our heat production measurements, we thus infer that the pluton has a substantial vertical extent, our preferred estimate for the scale depth for its downward decrease in radioactive heat production being ~ 8 km. Nonetheless, this pluton lacks any significant negative Bouguer gravity anomaly. We attribute this to the effect of the surrounding volcanic caldera, filled with relatively low-density lavas, ‘masking’ the pluton's own gravity anomaly. We envisage that emplacement occurred when the pluton was much hotter, and thus of lower density, than at present, its continued uplift, evident from the local geomorphology, being the isostatic consequence of localized erosion. The heat production in this intrusion evidently plays a significant role, hitherto unrecognized, in the regional geothermics

Pseudo-two-girdles c-axis fabric patterns in a quartz-feldspar mylonite (Costabona granodiorite, Canigo massif)

An example of the relationship that exist between the preferred crystaliografic orientation of quartz grains and the attitude of the mylonite foliation of quartz-feldspar mylonites is described. These rocks are the result of the inhomogeneous deformation under low-grade metamorphic conditions of a late Hercynian granodiorite, intruded into the gneisses of the slopes of the Canig massif (Eastern Pyrenees). The Costabona mylonites have a quartz c-axis fabric in pseudo-twogirdles symmetrical with respect to the mylonite foliation and perpendicular to the shearband systems which produce an extensional crenulation of the mylonite foliation

Dielectric properties of Granodiorite partially saturated with water and its correlation to the detection of seismic electric signals

Transient electric signals emitted prior to earthquake occurrence are recorded at certain sites in the Earth's crust termed sensitive. These field observations enforce the laboratory investigation of the dielectric response of rocks forming these localities. The dielectric relaxation of granodiorite rock coming from such a sensitive locality (Keratea, Greece) reveals, through complex impedance spectroscopy, that the activation volume for relaxation of this rock is negative which so far has been reported only rarely. This result, however, supports a theoretical model on the pre-seismic electric signals and is likely to be correlated with the sensitivity of the site and hence with the selectivity

X-ray diffraction studies of shocked lunar analogs

The X-ray diffraction experiments on shocked rock and mineral analogs of particular significance to lunar geology are described. Materials naturally shocked by meteorite impact, nuclear-shocked, or artificially shocked in a flat plate accelerator were utilized. Four areas were outlined for investigation: powder diffractometer studies of shocked single crystal silicate minerals (quartz, orthoclase, oligoclase, pyroxene), powder diffractometer studies of shocked polycrystalline monomineralic samples (dunite), Debye-Scherrer studies of single grains of shocked granodiorite, and powder diffractometer studies of shocked whole rock samples. Quantitative interpretation of peak shock pressures experienced by materials found in lunar or terrestrial impact structures is presented

Zircon U-Pb dating of Mesozoic volcanic and tectonic events in northwest Palmer Land and southwest Graham Land, Antarctica

New whole rock Rb-Sr and zircon U-Pb geochronological data and Sm-Nd isotopic data are presented from the central magmatic arc domain of the Antarctic Peninsula in the area of northwest Palmer Land and southwest Graham Land, Rb-Sr isochrons indicate an age of 169±6 Ma for basement orthogneisses and 132±9 to 71±9 Ma for plutons. A U-Pb age of 183 ± 2.1 Ma, with no detectable inheritance, on zircons from an orthogneiss from Cape Berteaux provides the first reliable age for the orthogneisses, which are interpreted as metamorphosed silicic volcanic rocks, and Sm-Nd data indicate derivation in a mature volcanic arc. The age indicates they may be correlatives of the Jurassic ‘Chon Aike’ volcanism of the eastern Antarctic Peninsula. A U-Pb zircon age of 107 ± 1.7 Ma on a terrestrial volcanic sequence overlying an uncomformity strongly suggests a mid-Cretaceous age for the extensive volcanic cover of northwest Palmer Land that was previously thought to be Jurassic. The unconformity is interpreted to have been a result of compressional uplift related to the Palmer Land event. This is the first date for the event in the western part of the central magmatic arc terrane of the Antarctic Peninsula

Shock effects in plagioclase feldspar from the Mistastin Lake impact structure, Canada

Shock metamorphism, caused by hypervelocity impact, is a poorly understood process in feldspar due to the complexity of the crystal structure, the relative ease of weathering, and chemical variations, making optical studies of shocked feldspars challenging. Understanding shock metamorphism in feldspars, and plagioclase in particular, is vital for understanding the history of Earth's moon, Mars, and many other planetary bodies. We present here a comprehensive study of shock effects in andesine and labradorite from the Mistastin Lake impact structure, Labrador, Canada. Samples from a range of different settings were studied, from in situ central uplift materials to clasts from various breccias and impact melt rocks. Evidence of shock metamorphism includes undulose extinction, offset twins, kinked twins, alternate twin deformation, and partial to complete transformation to diaplectic plagioclase glass. In some cases, isotropization of alternating twin lamellae was observed. Planar deformation features (PDFs) are notably absent in the plagioclase, even when present in neighboring quartz grains. It is notable that various microlites, twin planes, and compositionally different lamellae could easily be mistaken for PDFs and so care must be taken. A pseudomorphous zeolite phase (levyne-Ca) was identified as a replacement mineral of diaplectic feldspar glass in some samples, which could, in some instances, also be potentially mistaken for PDFs. We suggest that the lack of PDFs in plagioclase could be due to a combination of structural controls relating to the crystal structure of different feldspars and/or the presence of existing planes of weakness in the form of twin and cleavage planes

A more informative way to name plutonic rocks — comment by Frost et al.

Published versio

Global hydrogen reservoirs in basement and basins

The authors are grateful to the Science and Technology Facilities Council (STFC) for funding, through Grant NE/G00322X/1. Samples were kindly contributed by K. Condie, M.J. Hole, and D. Muirhead. We are grateful to reviewers for their criticism.Peer reviewedPublisher PD