Fe-Containing Zeolites for NH3-SCR of NOx: Effect of Structure, Synthesis Procedure, and Chemical Composition on Catalytic Performance and Stability

[EN] The direct preparation of different iron-containing Beta and CHA zeolites has been attempted under diverse synthesis conditions, including in alkaline and fluoride media, to evaluate the influence of their physicochemical properties on the selective catalytic reduction (SCR) of NOx using NH3 as reductant. Of the different Fe-Beta zeolites, the sample prepared in the absence of alkali cations with a Si/Al ratio of around 13 showed high NO conversion values (>90%). However, this catalyst suffered from severe deactivation when aged at high temperatures in the presence of steam. The preparation of more hydrophobic Fe-Beta zeolites did not improve the resistance of the catalyst against steam. In contrast, Fe-CHA zeolites prepared by a one-pot method under alkaline conditions with a Si/Al ratio of around 13 by using N,N,N-trimethyladamantylammonium as template not only showed excellent catalytic activity but also high hydrothermal stability, especially when sodium cations were selectively removed. Moreover, the Fe-CHA material synthesized by using the less expensive tetraethylammonium template also resulted in an active and hydrothermally stable catalyst.This work has been supported by Haldor Topsoe A/S, by the Spanish Government MINECO ("Severo Ochoa", SEV-2016-0683, and MAT2015-71261-R), by the European Union (ERC-AdG-2014-671093, SynCatMatch), and by the Fundacion Ramon Areces through a research contract from the "Life and Materials Science" program. N.M. thanks MINECO for economic support through a pre-doctoral fellowship (BES-2013-064347). The authors thank Isabel Millet for technical support.Martín-García, N.; Vennestrom; Peter Nicolai Ravnborg; Thogersen, JR.; Moliner Marin, M.; Corma Canós, A. (2017). Fe-Containing Zeolites for NH3-SCR of NOx: Effect of Structure, Synthesis Procedure, and Chemical Composition on Catalytic Performance and Stability. Chemistry - A European Journal. 23(54):13404-13414. https://doi.org/10.1002/chem.201701742S1340413414235