Supramolecular architectures from bent-core dendritic molecules

Control of the self-assembly of small molecules to generate architectures with diverse shapes and dimensions is a challenging research field. We report unprecedented results on the ability of ionic, bent dendritic molecules to aggregate in water. A range of analytical techniques (TEM, SEM, SAED, and XRD) provide evidence of the formation of rods, spheres, fibers, helical ribbons, or tubules from achiral molecules. The compact packing of the bent-core structures, which promotes the bent-core mesophases, also occurs in the presence of a poor solvent to provide products ranging from single objects to supramolecular gels. The subtle balance of molecule/solvent interactions and appropriate molecular designs also allows the transfer of molecular conformational chirality to morphological chirality in the overall superstructure. Functional motifs and controlled morphologies can be combined, thereby opening up new prospects for the generation of nanostructured materials through a bottom-up strategy.We greatly appreciate financial support from the Spanish Government (MICINN-FEDER projects MAT2012-38538-C03-01 and CTQ2012-35692) and Aragon’s Government (GA) (project E04). We are also grateful to Juan de la Cierva-MICINN, JAEDOC-CSIC (N.G.), and to GA (M.C.) fellowship programs for support.Peer Reviewe