Bulky-yet-flexible carbene ligands and their use in palladium cross-coupling

In recent years, several classes of new N-heterocyclic carbene (NHC) ligands were developed around the concept of flexible steric bulk. The steric hindrance of these ligands brings stability to the active species, while ligand flexibility still allows for the approach of the substrate. In this review, the synthesis of several types of new classes, such as IBiox, cyclic alkyl amino carbenes (CAAC), ITent, and IPr* are discussed, as well as how they move the state-of-the-art in palladium catalyzed cross-coupling forward

Combining human and computer interpretation capabilities to analyze ERTS imagery

The human photointerpreter and the computer have complementary capabilities that are exploited in a computer-based data analysis system developed at the Forestry Remote Sensing Laboratory, University of California. This system is designed to optimize the process of extracting resource information from ERTS images. The human has the ability to quickly delineate gross differences in land classes, such as wildland, urban, and agriculture on appropriate ERTS images, and to further break these gross classes into meaningful subclasses. The computer, however, can more efficiently analyze point-by-point spectral information and localized textural information which can result in a much more detailed agricultural or wildland classification based on species composition and/or plant association. These human and computer capabilities have been integrated through the use of an inexpensive small scale computer dedicated to the interactive preprocessing of the human inputs and the display of raw ERTS images and computer classified images. The small computer is linked to a large scale computer system wherein the bulk of the statistical work and the automatic point-by-point classification is done

Open two-species exclusion processes with integrable boundaries

We give a complete classification of integrable Markovian boundary conditions for the asymmetric simple exclusion process with two species (or classes) of particles. Some of these boundary conditions lead to non-vanishing particle currents for each species. We explain how the stationary state of all these models can be expressed in a matrix product form, starting from two key components, the Zamolodchikov-Faddeev and Ghoshal-Zamolodchikov relations. This statement is illustrated by studying in detail a specific example, for which the matrix Ansatz (involving 9 generators) is explicitly constructed and physical observables (such as currents, densities) calculated.Comment: 19 pages; typos corrected, more details on the Matrix Ansatz algebr

Impact of mechanized harvesting on compaction of sandy and clayey forest soils : results of a meta-analysis

Nowadays, harvest operations are predominantly performed fully mechanized using heavy tractors or forestry machines. The resulting soil compaction may negatively affect the soil ecosystem. We wanted to draw general conclusions concerning the impact of mechanized harvesting on forest soil bulk density and the influencing factors. Therefore, we combined the data of several studies using a meta-analysis approach. The impact decreased from the surface towards deeper soil layers. At 0-10 cm depth, the impact on clayey soils was highest although not significantly different from the impact on sandy soils. Higher initial bulk densities, i.e., on already compacted forest soils, generally led to smaller extra increases of bulk density after machine traffic. For sandy soils, the impact was also significantly smaller when machines were lighter. No significant relationship was observed between the compaction degree and traffic intensity. We observed clear compaction on both clayey and sandy soils, especially in case of low initial soil compaction degrees and heavy machines. The compacted initial state of many forest soils, the long recovery period, and the generally high impact of the first passes that is frequently mentioned in literature all count in favour of designated skid trails and an adjustment of the machine type to the job

Integrable boundary conditions for multi-species ASEP

The first result of the present paper is to provide classes of explicit solutions for integrable boundary matrices for the multi-species ASEP with an arbitrary number of species. All the solutions we have obtained can be seen as representations of a new algebra that contains the boundary Hecke algebra. The boundary Hecke algebra is not sufficient to build these solutions. This is the second result of our paper.Comment: 20 page

Digital simulation of chronopotentiometric and steady-state voltammetric curves at microelectrodes in the presence of a low concentration of supporting electrolyte

A simulation scheme for the calculation of theoretical chronopotentiograms at microelectrodes in solutions containing low amounts of supporting electrolyte is presented. The scheme allows computation of the changes in the concentration profiles of the substrates, products and the supporting electrolyte ions with time. The electrode potentials that are established after reaching the steady-state, together with the appropriate current intensities, can be used for constructing the steady-state voltammograms. The simulation of the mixed diffusional and migrational transport is based on the Crank-Nicolson method with an exponentially expanding time and space grids. The scheme does not impose any limitations on diffusion coefficients and it can be applied both to simple electrode reactions (one reactant-one product) and more complicated reactions under the assumption that the double-layer thickness is small in comparison to the diffusion layer. Five simple types of electrode reactions and an example of a more complicated scheme were considered. The results obtained demonstrate that the dependence of the steady-state limiting current on the support ratio (csupp.el./csubst) depends not only on the charge of the reactant and the product, but also on the diffusion coefficient ratio of the substrate and product. If the difference between diffusion coefficients is large, the predictions based on simpler theories available in literature can become invalid

Investigating the radial flow like effects using identified triggered correlation in pp collisions at s\sqrt{s} = 7 TeV

An inclusive baryon to meson enhancement with increase in multiplicity has been observed in pp collisions at $\sqrt{s}$= 7 TeV. Such a striking feature of the data can be explained by approaches based on hydrodynamics and multi-parton interactions (MPI) coupled with color reconnection (CR) mechanism. In this paper, we investigate the multiplicity evolution of the charged particle yields associated with pions and protons selected from the intermediate $p_{T}$ region where the inclusive baryon to meson enhancement has been observed. The study has been peformed using EPOS 3 (hydrodynamics) and PYTHIA 8 (MPI with CR) event generators in pp collisions at 7 TeV. We find that the response of the individual pion and proton triggered correlation towards these two mechanisms is different and can be used to disentangle the effect of one from the other. The current study can, therefore, provide important insights on the origin of radial flow like effects in high multiplicity pp collisions at the LHC energies.Comment: 5 pages, 6 figure