Examining the Hydration and Mechanical Properties of Cement Paste Containing Cellulose Nanocrystals

Cellulose nanocrystals (CNCs) are a nano-scaled particulae material that has been shown to improve strength in cementitious pastes. One advantage of CNCs compared to other nano-materials is that CNCs are renewable and sustainable. The objective of this investigation is to investigate the influence of additional alkali content on the behavior of CNCs in cement paste. This work evaluates flexural and compressive strength as a function of heat of hydration—which measures the extent of reaction. Previous mechanical tests on cement paste containing cellulose nanocrystals (CNCs) have shown CNCs to improve the flexural strength of cement paste by approximately 30%. Isothermal calorimetry testing showed that degree of hydration of the cement paste containing CNCs increases compared to the plain system. Since properties of cement composites are time dependent, specimens were tested at degree of hydration. The hypothesis of this work is that CNC will improve the strength gain as a function of hydration. In addition, CNC will improve in the degree of hydration. To evaluate this hypothesis, cement paste samples were prepared using CNC of 0%, 0.2%, and 1.0% by volume and alkali content of 0.19%, 0.61%, and 1.01% by weight. Heat of hydration quantities was related to specimen ages and mechanical properties at given ages. Results showed that specimens containing CNCs with additional alkali content greatly increased strength at the same degree of hydration. Results indicate that CNCs are improving the strength of the cement paste by mobility of the microstructure

Environmentally Tuning Asphalt Pavements Using Phase Change Materials

Environmental conditions are considered an important factor influencing asphalt pavement performance. The addition of modifiers, both to the asphalt binder and the asphalt mixture, has attracted considerable attention in potentially alleviating environmentally induced pavement performance issues. Although many solutions have been developed, and some deployed, many asphalt pavements continue to prematurely fail due to environmental loading. The research reported herein investigates the synthetization and characterization of biobased Phase Change Materials (PCMs) and inclusion of Microencapsulated PCM (μPCM) in asphalt binders and mixtures to help reduce environmental damage to asphalt pavements. In general, PCM substances are formulated to absorb and release thermal energy as the material liquify and solidify, depending on pavement temperature. As a result, PCMs can provide asphalt pavements with thermal energy storage capacities to reduce the impacts of drastic ambient temperature scenarios and minimize the appearance of critical temperatures within the pavement structure. By modifying asphalt pavement materials with PCMs, it may be possible to tune the pavement to the environment

Contaminant Release from Storm Water Culvert Rehabilitation Technologies: Understanding Implications to the Environment and Long-Term Material Integrity

Millions of miles of existing U.S. storm water culverts are critical for roadway safety but much of this infrastructure requires repair. State departments of transportation (DOT) are increasingly choosing to rehabilitate culverts with spray-on and cured-in-place pipe (CIPP) lining processes. These culvert lining practices involve the manufacture of a new plastic liner inside a damaged culvert. DOTs are selecting these outdoor plastic manufacturing methods partly to avoid open-trench excavation, which can cause traffic disruption and work zone traffic safety issues. This study was conducted to better understand current knowledge about culvert lining caused environmental contamination, final product quality, and recommend improved construction specifications, project oversight, and testing requirements to limit undesirable consequences. Literature reviews, a survey of construction specifications and special provisions for 32 transportation agencies, as well as field- and bench-scale testing for CIPP projects in California, New York, and Virginia, were completed. During this project, the safety of workers, transportation agency employees, and the general public at lining installation sites, was raised as a concern by state and federal agencies. Due to previously unreported hazards which were encountered at multiple CIPP field sites, the provision of worksite safety recommendations for DOTs was added to this study. Recommendations are provided for spray-on lining and CIPP lining culvert repair projects that can (1) limit environmental contamination, (2) improve worksite safety, and (3) aid DOTs in better understanding the quality of their new liners

The MUSCLES Treasury Survey. II. Intrinsic Lyα and extreme ultraviolet spectra of K and M dwarfs with exoplanets

This work was supported by NASA grants HST-GO-12464.01 and HST-GO-13650.01 to the University of Colorado at Boulder. Sarah Rugheimer would like to acknowledge support from the Simons Foundation (339489, Rugheimer).The ultraviolet (UV) spectral energy distributions (SEDs) of low-mass (K- and M-type) stars play a critical role in the heating and chemistry of exoplanet atmospheres, but are not observationally well-constrained. Direct observations of the intrinsic flux of the Lyα line (the dominant source of UV photons from low-mass stars) are challenging, as interstellar H i absorbs the entire line core for even the closest stars. To address the existing gap in empirical constraints on the UV flux of K and M dwarfs, the MUSCLES Hubble Space Telescope Treasury Survey has obtained UV observations of 11 nearby M and K dwarfs hosting exoplanets. This paper presents the Lyα and extreme-UV spectral reconstructions for the MUSCLES targets. Most targets are optically inactive, but all exhibit significant UV activity. We use a Markov Chain Monte Carlo technique to correct the observed Lyα profiles for interstellar absorption, and we employ empirical relations to compute the extreme-UV SED from the intrinsic Lyα flux in ∼100 bins from 100-1170. The reconstructed Lyα profiles have 300 km s-1 broad cores, while >1% of the total intrinsic Lyα flux is measured in extended wings between 300 and 1200 km s-1. The Lyα surface flux positively correlates with the Mg ii surface flux and negatively correlates with the stellar rotation period. Stars with larger Lyα surface flux also tend to have larger surface flux in ions formed at higher temperatures, but these correlations remain statistically insignificant in our sample of 11 stars. We also present H i column density measurements for 10 new sightlines through the local interstellar medium.Publisher PDFPeer reviewe

Prikazan’je historije svetoga Panuncija; Utiha nesriće

We present a catalog of panchromatic spectral energy distributions (SEDs) for 7 M and 4 K dwarf stars that span X-ray to infrared wavelengths (5 {\AA} - 5.5 {\mu}m). These SEDs are composites of Chandra or XMM-Newton data from 5 - ~50 {\AA}, a plasma emission model from ~50 - 100 {\AA}, broadband empirical estimates from 100 - 1170 {\AA}, HST data from 1170 - 5700 {\AA}, including a reconstruction of stellar Ly{\alpha} emission at 1215.67 {\AA}, and a PHOENIX model spectrum from 5700 - 55000 {\AA}. Using these SEDs, we computed the photodissociation rates of several molecules prevalent in planetary atmospheres when exposed to each star's unattenuated flux ("unshielded" photodissociation rates) and found that rates differ among stars by over an order of magnitude for most molecules. In general, the same spectral regions drive unshielded photodissociations both for the minimally and maximally FUV active stars. However, for ozone visible flux drives dissociation for the M stars whereas NUV flux drives dissociation for the K stars. We also searched for an FUV continuum in the assembled SEDs and detected it in 5/11 stars, where it contributes around 10% of the flux in the range spanned by the continuum bands. An ultraviolet continuum shape is resolved for the star {\epsilon} Eri that shows an edge likely attributable to Si II recombination. The 11 SEDs presented in this paper, available online through the Mikulski Archive for Space Telescopes, will be valuable for vetting stellar upper-atmosphere emission models and simulating photochemistry in exoplanet atmospheres.Comment: 20 pages, 12 figures, 4 tables. Accepted to the ApJ. Spectra in FITS format available for download at https://archive.stsci.edu/prepds/muscle

The MUSCLES Treasury Survey. IV. : Scaling relations for ultraviolet, Ca II K, and energetic particle fluxes from M dwarfs

Characterizing the UV spectral energy distribution (SED) of an exoplanet host star is critically important for assessing its planet's potential habitability, particularly for M dwarfs, as they are prime targets for current and near-term exoplanet characterization efforts and atmospheric models predict that their UV radiation can produce photochemistry on habitable zone planets different from that on Earth. To derive ground-based proxies for UV emission for use when Hubble Space Telescope (HST) observations are unavailable, we have assembled a sample of 15 early to mid-M dwarfs observed by HST and compared their nonsimultaneous UV and optical spectra. We find that the equivalent width of the chromospheric Ca ii K line at 3933 Å, when corrected for spectral type, can be used to estimate the stellar surface flux in ultraviolet emission lines, including H i Lyα. In addition, we address another potential driver of habitability: energetic particle fluxes associated with flares. We present a new technique for estimating soft X-ray and >10 MeV proton flux during far-UV emission line flares (Si iv and He ii) by assuming solar-like energy partitions. We analyze several flares from the M4 dwarf GJ 876 observed with HST and Chandra as part of the MUSCLES Treasury Survey and find that habitable zone planets orbiting GJ 876 are impacted by large Carrington-like flares with peak soft X-ray fluxes ≥10−3 W m−2 and possible proton fluxes ~102–103 pfu, approximately four orders of magnitude more frequently than modern-day Earth.Publisher PDFPeer reviewe

The MUSCLES Treasury Survey. I. Motivation and overview

Ground- and space-based planet searches employing radial velocity techniques and transit photometry have detected thousands of planet-hosting stars in the Milky Way. With so many planets discovered, the next step toward identifying potentially habitable planets is atmospheric characterization. While the Sun–Earth system provides a good framework for understanding the atmospheric chemistry of Earth-like planets around solar-type stars, the observational and theoretical constraints on the atmospheres of rocky planets in the habitable zones (HZs) around low-mass stars (K and M dwarfs) are relatively few. The chemistry of these atmospheres is controlled by the shape and absolute flux of the stellar spectral energy distribution (SED), however, flux distributions of relatively inactive low-mass stars are poorly understood at present. To address this issue, we have executed a panchromatic (X-ray to mid-IR) study of the SEDs of 11 nearby planet-hosting stars, the Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems (MUSCLES) Treasury Survey. The MUSCLES program consists visible observations from Hubble and ground-based observatories. Infrared and astrophysically inaccessible wavelengths (EUV and Lyα ) are reconstructed using stellar model spectra to fill in gaps in the observational data. In this overview and the companion papers describing the MUSCLES survey, we show that energetic radiation (X-ray and ultraviolet) is present from magnetically active stellar atmospheres at all times for stars as late as M6. The emission line luminosities of C iv and Mg ii are strongly correlated with band-integrated luminosities and we present empirical relations that can be used to estimate broadband FUV and XUV (≡X-ray + EUV) fluxes from individual stellar emission line measurements. We find that while the slope of the SED, FUV/NUV, increases by approximately two orders of magnitude form early K to late M dwarfs (≈0.01–1), the absolute FUV and XUV flux levels at their corresponding HZ distances are constant to within factors of a few, spanning the range 10–70 erg cm−2 s−1 in the HZ. Despite the lack of strong stellar activity indicators in their optical spectra, several of the M dwarfs in our sample show spectacular UV flare emission in their light curves. We present an example with flare/quiescent ultraviolet flux ratios of the order of 100:1 where the transition region energy output during the flare is comparable to the total quiescent luminosity of the star Eflare(UV) ∼ 0.3 L*Δt (Δt = 1 s). Finally, we interpret enhanced L(line)/LBol ratios for C iv and N v as tentative observational evidence for the interaction of planets with large planetary mass-to-orbital distance ratios (Mplan/aplan) with the transition regions of their host stars.Publisher PDFPeer reviewe

The High-Energy Radiation Environment Around a 10 Gyr M Dwarf: Habitable at Last?

High levels of X-ray and UV activity on young M dwarfs may drive rapid atmospheric escape on temperate, terrestrial planets orbiting within the liquid water habitable zone. However, secondary atmospheres on planets orbiting older, less active M dwarfs may be stable and present more promising candidates for biomarker searches. We present new HST and Chandra observations of Barnard's Star (GJ 699), a 10 Gyr old M3.5 dwarf, acquired as part of the Mega-MUSCLES program. Despite the old age and long rotation period of Barnard's star, we observe two FUV ($\delta_{130}$ $\approx$ 5000s; $E_{130}$ $\approx$ 10$^{29.5}$ erg each) and one X-ray ($E_{X}$ $\approx$ 10$^{29.2}$ erg) flares, and estimate a high-energy flare duty cycle (defined here as the fraction of the time the star is in a flare state) of $\sim$ 25\%. A 5 A - 10 $\mu$m SED of GJ 699 is created and used to evaluate the atmospheric stability of a hypothetical, unmagnetized terrestrial planet in the habitable zone ($r_{HZ}$ $\sim$ 0.1 AU). Both thermal and non-thermal escape modeling indicate (1) the $quiescent$ stellar XUV flux does not lead to strong atmospheric escape: atmospheric heating rates are comparable to periods of high solar activity on modern Earth, and (2) the $flare$ environment could drive the atmosphere into a hydrodynamic loss regime at the observed flare duty cycle: sustained exposure to the flare environment of GJ 699 results in the loss of $\approx$ 87 Earth atmospheres Gyr$^{-1}$ through thermal processes and $\approx$ 3 Earth atmospheres Gyr$^{-1}$ through ion loss processes, respectively. These results suggest that if rocky planet atmospheres can survive the initial $\sim$ 5 Gyr of high stellar activity, or if a second generation atmosphere can be formed or acquired, the flare duty cycle may be the controlling stellar parameter for the stability of Earth-like atmospheres around old M stars.Comment: Accepted to A

The Muscles Treasure Survey. I. Motivation and Overview

Ground- and space-based planet searches employing radial velocity techniques and transit photometry have detected thousands of planet-hosting stars in the Milky Way. With so many planets discovered, the next step toward identifying potentially habitable planets is atmospheric characterization. While the Sun–Earth system provides a good framework for understanding the atmospheric chemistry of Earth-like planets around solar-type stars, the observational and theoretical constraints on the atmospheres of rocky planets in the habitable zones (HZs) around low-mass stars (K and M dwarfs) are relatively few. The chemistry of these atmospheres is controlled by the shape and absolute flux of the stellar spectral energy distribution (SED), however, flux distributions of relatively inactive low-mass stars are poorly understood at present. To address this issue, we have executed a panchromatic (X-ray to mid-IR) study of the SEDs of 11 nearby planet-hosting stars, the Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems (MUSCLES) Treasury Survey. The MUSCLES program consists visible observations from Hubble and ground-based observatories. Infrared and astrophysically inaccessible wavelengths (EUV and Lyα) are reconstructed using stellar model spectra to fill in gaps in the observational data. In this overview and the companion papers describing the MUSCLES survey, we show that energetic radiation (X-ray and ultraviolet) is present from magnetically active stellar atmospheres at all times for stars as late as M6. The emission line luminosities of C iv and Mg ii are strongly correlated with band-integrated luminosities and we present empirical relations that can be used to estimate broadband FUV and XUV (≡X-ray + EUV) fluxes from individual stellar emission line measurements. We find that while the slope of the SED, FUV/NUV, increases by approximately two orders of magnitude form early K to late M dwarfs (≈0.01–1), the absolute FUV and XUV flux levels at their corresponding HZ distances are constant to within factors of a few, spanning the range 10–70 erg cm−2 s−1in the HZ. Despite the lack of strong stellar activity indicators in their optical spectra, several of the M dwarfs in our sample show spectacular UV flare emission in their light curves. We present an example with flare/quiescent ultraviolet flux ratios of the order of 100:1 where the transition region energy output during the flare is comparable to the total quiescent luminosity of the star Eflare(UV) ~ 0.3 L*Δt (Δt = 1 s). Finally, we interpret enhanced L(line)/LBol ratios for C iv and N v as tentative observational evidence for the interaction of planets with large planetary mass-to-orbital distance ratios (Mplan/aplan) with the transition regions of their host stars