5,205 research outputs found

    Casimir Energy and Entropy between perfect metal Spheres

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    We calculate the Casimir energy and entropy for two perfect metal spheres in the large and short separation limit. We obtain nonmonotonic behavior of the Helmholtz free energy with separation and temperature, leading to parameter ranges with negative entropy, and also nonmonotonic behavior of the entropy with temperature and with the separation between the spheres. The appearance of this anomalous behavior of the entropy is discussed as well as its thermodynamic consequences.Comment: 10 pages and 8 figures. Accepted for publication in the Proceedings of the tenth conference on Quantum Field Theory under the influence of external conditions - QFEXT'1

    Numerische Simulation von Temperaturgradienten und thermisch induzierten Eigenspannungen in Natursteinplatten infolge von Sonneneinstrahlung

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    The interaction between micro-organisms and natural stone surfaces has been studied in great detail in the past. The destructive mechanisms of micro-organisms can be roughly subdivided into (a) chemical attack and (b) physical attack. Microorganisms may physically destroy the structure of stones by creating an inter-granular swelling pressure. Recently, it has been shown experimentally that black spots formed by yeast-like fungi lead to a local temperature increase by selective absorption of solar radiation. The maximum temperature observed for clean marble surfaces remained below the maximum temperature observed on inoculated surfaces. As a consequence, thermal dilatation of inoculated marble was shown to be more important. Destruction of the heated stone occurs predominantly if there exists a thermal gradient. In this paper, temperature distribution in clean and stained marble plates have been simulated numerically. Thermal eigenstresses have been determined. It is shown that tensile stresses of up to 5 N/mm2 can be expected. This may cause damage in weak zones of the surface. A sudden driving rain leads to much higher stresses. Cyclic thermal loading may eventually destroy the surface by fatigu

    Untersuchung von Feuchtetransport mittels numerischer Modellierung und Neutronentransmissionsanalyse

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    Moisture transport in porous building materials is described by a transport model that expresses the action of the several transport mechanisms of liquid water and water vapor in the porous system by a single material specific transfer coefficient. This parameter has to be determined by experimental measurement of moisture distributions inside samples exposed to known initial and boundary conditions. Neutron radiography is employed as experimental method because of its high sensitivity and good spatial resolution. The moisture distribution is determined from the raw data obtained in the measurement by a calculation procedure based on a signal transfer model of the neutron transmission. This approach is illustrated by two examples: the drying of a plain brick sample and the drying of a composite sample consisting of two brick elements separated by a layer of morta

    Control of tunneling in an atomtronic switching device

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    The precise control of quantum systems will play a major role in the realization of atomtronic devices. As in the case of electronic systems, a desirable property is the ability to implement switching. Here we show how to implement switching in a model of dipolar bosons confined to three coupled wells. The model describes interactions between bosons, tunneling of bosons between adjacent wells, and the effect of an external field. We conduct a study of the quantum dynamics of the system to probe the conditions under which switching behavior can occur. The analysis considers both integrable and non-integrable regimes within the model. Through variation of the external field, we demonstrate how the system can be controlled between various switched-on and switched-off configurations.Comment: Revised Communications Physics (open access) version; Major revision: 8 pages, 6 figures; Supplementary material: 2 pages, 5 figure

    Near-Field Spherical Scanning Antenna Measurements: Probe Deconvolution and Sensitivity

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    We define and calculate sensitivity for several actual and simulated probes. Probe sensitivity can have a significant impact on the measurement uncertainty associated with probe deconvolution in near-field spherical-scanning, antenna measurements

    Rechnerische Bestimmung der lonenbeweglichkeit in Ziegelstein unter Zuhilfenahme von Ergebnissen aus nichtstationären Diffusionsversuchen

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    Ion concentration profiles in sandwich-brick specimens have been determined experimentally at different degrees of water saturation. Based on the experimental data, ion diffusion coefficients were determined by inverse analysis. The diffusion equation served as a basis for an optimization technique. It has been shown that the ion diffusivity in bricks decreases markedly as the moisture content decreases. The interface between two adjacent bricks slows down the ion migration at low water content in particular. It is planed to investigate the interface between mortar and bricks in further experimental and numerical studie

    Machine Learning-Assisted Directed Evolution Navigates a Combinatorial Epistatic Fitness Landscape with Minimal Screening Burden

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    Due to screening limitations, in directed evolution (DE) of proteins it is rarely feasible to fully evaluate combinatorial mutant libraries made by mutagenesis at multiple sites. Instead, DE often involves a single-step greedy optimization in which the mutation in the highest-fitness variant identified in each round of single-site mutagenesis is fixed. However, because the effects of a mutation can depend on the presence or absence of other mutations, the efficiency and effectiveness of a single-step greedy walk is influenced by both the starting variant and the order in which beneficial mutations are identified—the process is path-dependent. We recently demonstrated a path-independent machine learning-assisted approach to directed evolution (MLDE) that allows in silico screening of full combinatorial libraries made by simultaneous saturation mutagenesis, thus explicitly capturing the effects of cooperative mutations and bypassing the path-dependence that can limit greedy optimization. Here, we thoroughly investigate and optimize an MLDE workflow by testing a number of design considerations of the MLDE pipeline. Specifically, we (1) test the effects of different encoding strategies on MLDE efficiency, (2) integrate new models and a training procedure more amenable to protein engineering tasks, and (3) incorporate training set design strategies to avoid information-poor low-fitness protein variants (“holes”) in the training data. When applied to an epistatic, hole-filled, four-site combinatorial fitness landscape of protein G domain B1 (GB1), the resulting focused training MLDE (ftMLDE) protocol achieved the global fitness maximum up to 92% of the time at a total screening burden of 470 variants. In contrast, minimal-screening-burden single-step greedy optimization over the GB1 fitness landscape reached the global maximum just 1.2% of the time; ftMLDE matching this minimal screening burden (80 total variants) achieved the global optimum up to 9.6% of the time with a 49% higher expected maximum fitness achieved. To facilitate further development of MLDE, we present the MLDE software package (https://github.com/fhalab/MLDE), which is designed for use by protein engineers without computational or machine learning expertise

    Energy levels and decoherence properties of single electron and nuclear spins in a defect center in diamond

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    The coherent behavior of the single electron and single nuclear spins of a defect center in diamond and a 13C nucleus in its vicinity, respectively, are investigated. The energy levels associated with the hyperfine coupling of the electron spin of the defect center to the 13C nuclear spin are analyzed. Methods of magnetic resonance together with optical readout of single defect centers have been applied in order to observe the coherent dynamics of the electron and nuclear spins. Long coherence times, in the order of microseconds for electron spins and tens of microseconds for nuclear spins, recommend the studied system as a good experimental approach for implementing a 2-qubit gate.Comment: 4 pages, 4 figure
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