Electronic and total energy properties of ternary and quaternary semiconductor compounds, alloys, and superlattices: Theoretical study of Cu/graphite bonding

The goals of the research were to provide a fundamental science basis for why the bonding of Cu to graphite is weak, to critically evaluate the previous analysis of the wetting studies with particular regard to the values used for the surface energies of Cu and graphite, and to make recommendations for future experiments or other studies which could advance the understanding and solution of this technological problem. First principles electronic structure calculations were used to study the problem. These are based on density functional theory in the local density approximation and the use of the linear muffin-tin orbital band structure method. Calculations were performed for graphite monolayers, single crystal graphite with the hexagonal AB stacking, bulk Cu, Cu(111) surface, and Cu/graphite superlattices. The study is limited to the basal plane of graphite because this is the graphite plane exposed to Cu and graphite surface energies and combined with the measured contact angles to evaluate the experimental adhesion energy

Solar Irradiance Observed from PVO and Inferred Solar Rotation

Solar irradiance in the extreme ultraviolet flux (EUV) has been monitored for 11 years by the Pioneer Venus Orbiter (PVO). Since the experiment moves around the Sun with the orbital rate of Venus rather than that of Earth, the measurement gives us a second viewing location from which to begin unravelling which irradiance variations are intrinsic to the Sun, and which are merely rotational modulations whose periods depend on the motion of the observer. Researchers confirm an earlier detection, made with only 8.6 years of data, that the EUV irradiance is modulated by rotation rates of two families of global oscillation modes. One family is assumed to be r-modes occupying the convective envelope and sharing its rotation, while the other family (g-modes) lies in the radiative interior which as a slower rotation. Measured power in r-modes of low angular harmonic number indicates that the Sun's envelope rotated about 0.7 percent faster near the last solar maximum (1979 thru 1982) than it did during the next rise to maximum (1986 to 1989). No change was seen in the g-mode family of lines, as would be expected from the much greater rotational inertia of the radiative interior

Fifth district banks' return on assets: highest in decade

Reduced provisions for loan losses in 1988 boosted bank profits in the Fifth District and nationwide. Profit ratios also may have been influenced somewhat by subsidiary banks’ payment of management fees to their holding companies.Federal Reserve District, 5th ; Bank profits

Results of TC-1 boost pump icing tests in the space power facility

A series of tests were conducted in the space power facility to investigate the failure of the Centaur oxidizer boost pump during the Titan/Centaur proof flight February 11, 1974. The three basic objectives of the tests were: (1) demonstrate if an evaporative freezing type failure mechanism could have prevented the pump from operating, (2) determine if steam from the exhaust of one of the attitude control engine could have entered a pump seal cavity and caused the failure, and (3) obtain data on the heating effects of the exhaust plume from a hydrogen peroxide attitude control engine

Seasonal and inter-annual patterns of sediment-water nutrient and oxygen fluxes in Mobile Bay, Alabama (USA): Regulating factors and ecological significance.

Sediment oxygen and nutrient fluxes were measured monthly for 2 yr in Mobile Bay, Alabama, USA. Rates of sediment oxygen consumption (0.1 to 1.25 gO2 m-2 d-1), ammonium flux (-22 to 181 µmol m-2 h-1), nitrate flux (-14 to 67 µmol m-2 h-1), phosphate flux (-2 to 20.4 µmol m-2 h-1), and dissolved silicate flux (-15 to 342 µmol m-2 h-1) were moderate to high compared to values for other estuaries. A step-wise regression analysis revealed that dissolved oxygen concentration and temperature in bottom-waters explained much of the variance in fluxes. This is presumably because of their influence on rates of microbial and physico-chemical processes. Organic matter availability was not found to be an important factor in regulating temporal (month to month) variability of fluxes, possibly because frequent resuspension of the sediments in this shallow system rendered indices of sediment organic matter nearly constant with time. However, warm season-averaged sediment nutrient releases were correlated with sediment chlorophyll a. This relationship in Mobile Bay is in strong agreement with similar relationships found in other estuarine systems, and suggests that the availability of labile organic matter ultimately regulates the maximum rate of nutrient release by the sediments. Annually averaged sediment fluxes supplied 36% of the nitrogen (N) and 25% of the phosphorus (P) required by phytoplankton in Mobile Bay. While this is not particularly high compared to other estuaries, monthly estimates show that the sediments can supply from 0 to 94% of the N, and 0 to 83% of the P required by phytoplankton. In addition, flux ratios show that N and P are released from sediments at N:P ratios that rapidly switch from above (maximum 98) to below (minimum 1.2) that required for phytoplankton growth. This pattern is different from cooler temperate systems, where such switching is seasonally base