Thermodynamic Properties of Block Copolymer Electrolytes Containing Imidazolium and Lithium Salts

We report on the thermal properties, phase behavior, and thermodynamics of a series of polystyrene-block-poly(ethylene oxide) copolymers (SEO) mixed with the ionic species Li[N(SO_(2)CF_3)_2] (LiTFSI), imidazolium TFSI (ImTFSI), and an equimolar mixture of LiTFSI and ImTFSI (Mix). Differential scanning calorimetric scans reveal similar thermal behavior of SEO/LiTFSI and SEO/ImTFSI at the same salt concentrations. Phase behavior and thermodynamics were determined using a combination of small-angle X-ray scattering and birefringence. The thermodynamics of our mixtures can be mapped on to the theory of neat block copolymer phase behavior provided the Flory−Huggins interaction parameter, χ, between the blocks is replaced by an effective χ (χ_(eff)) that increases linearly with salt concentration. The phase behavior and the value of m, the slope of the χ_(eff) versus salt concentration data, were similar for SEO/LiTFSI, SEO/ImTFSI, and SEO/Mix blends. The theory developed by Wang [ J. Phys. Chem. B. 2008, 41, 16205] provides a basis for understanding the fundamental underpinnings of the measured value of m. We compare our experimental results with the predictions of this theory with no adjustable parameters

allergic contact dermatitis caused by metals in blackboard chalk a case report

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Nota previa sobre el Pérmico de la Cordillera Ibérica y bordes del Sistema Central

The principal stratigraphic characteristics from severa1 per- mian oatcrops from the Bordes del Macizo Central and Cor- dillera Ibérica are described here. The comparative study of these series, as well as the data apported by previous works allow certain conclusions about development of the sedimen- tation during the Permian and the limit between that system and the Trias

Nota previa sobre el Pérmico de la Cordillera Ibérica y bordes del Sistema Central

[ES] Se describen las principales características estratigráficas de varios afloramientos pérmicos de los bordes del Macizo Central y Cordillera Ibérica. El estudio comparativo de las series, así como los datos aportados por trabajos anteriores, permiten algunas conclusiones sobre el desarrollo de la sedimentación durante el Pérmico y el límite de éste con el Trías.[EN] The principal stratigraphic characteristics from severa1 permian oatcrops from the Bordes del Macizo Central and Cordillera Ibérica are described here. The comparative study of these series, as well as the data apported by previous works allow certain conclusions about development of the sedimentation during the Permian and the limit between that system and the Trias.Peer reviewe

low dose acitretin in treatment of plaque type psoriasis descriptive study of efficacy and safety

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contact vulvitis due to pseudowintera colorata in a topical herbal medicament

Sir, Besides traditional topical and systemic pharmacological treatments for the therapy of vulvovaginal yeast and bacterial infections, numerous over-the-counter medicaments containing natural substances (e.g. tea tree oil, echinacea, sodium caprylate, propolis) are marketed. Patients often prefer alternative medicine and selfprescribe herbal-based products. We report here an unusual case of acute vulvitis that occurred in a young patient after prolonged topical use of an antifungal herbal preparation

Vulvar lichen sclerosus: 11 women treated with tacrolimus 0.1% ointment.

Lichen sclerosus is a chronic relapsing disease, usually treated with ultra-potent corticosteroids. As immunological alterations are considered important aetiopathogenetic factors in lichen sclerosus, the new immunomodulating topical agents, such as tacrolimus and pimecrolimus, have been employed sporadically as alternative therapies. The aim of this study was to evaluate the therapeutic effects of tacrolimus 0.1% ointment in lichen sclerosus in 11 patients unresponsive or poorly responsive to previous treatments. Tacrolimus 0.1% ointment was applied twice daily for 6 weeks, then tapered over a further 6 weeks. Symptoms and objective parameters were evaluated and quantified at the start, after 6 weeks, at the end of the topical treatment, and at follow-up visits. Improvement or remission of symptoms was observed in the patients who completed the study, while objective parameters were poorly influenced and often were not related to symptom behaviour. Topical tacrolimus can be considered an alternative treatment for lichen sclerosus

Length–weight relationships of bivalve species in Italian razor clam Ensis minor (Chenu, 1843) (Mollusca: Bivalvia) fishery

Length–weight relationships of bivalve species collected during razor clam (Ensis minor) surveys along Italian coastal waters (Northern Adriatic and Tyrrhenian Sea) in the 3-year period 2016–2018 are reported. A total of 13,588 individuals, belonging to 12 bivalve species and 20 populations between the Adriatic and Tyrrhenian Seas, were sampled for this study. Analyzing growth parameters for each population, we found 11 allometries and nine isometries. About half of the species investigated showed different growth characteristics between the two areas

Pots vs trammel nets: A catch comparison study in a Mediterranean small-scale fishery

Passive bottom-set nets are the most widely used fishing gears in Mediterranean small-scale fisheries (SSFs). Trammel nets, in particular, have key advantages such as their ease of use and handling and high capture efficiency for numerous commercial species. However, they entail high discard rates (5\u201344% of the total catch) connected to high mortality, thus exerting an adverse impact on benthic communities, besides catching individuals of commercial species under the minimum conservation reference size (MCRS) and specimens of protected species. Fish pots are seen as alternative and a more sustainable gear type that allow reducing discards in SSFs. In this study, a collapsible pot was tested at three coastal sites in the north-western Adriatic Sea (GFCM GSA 17) to compare its catch efficiency with that of the local traditional trammel nets. Data analysis demonstrated a similar catch efficiency for the commercial species, both among sites and as a whole. Moreover, the trammel net caught a larger amount of discards, both in terms of species number and of CPUEW. The catch comparison study involved the two most abundant landed species, common cuttlefish Sepia officinalis and annular sea bream Diplodus annularis. The pots were more effective for S. officinalis, whereas the trammel net was more effective for the shorter length classes for D. annularis, which were mostly under the MCRS (12 cm). The innovative pots could provide a valuable alternative to the trammel nets traditionally used in the Adriatic Sea, at least in certain areas and periods. Their main advantages include that they do not require a different rigging and they can be used without bait, while their foldable design allows large numbers to be easily loaded on board SSF vessels. The results of this pilot study indicate that pots can achieve the objectives of reducing discards and bycatch in SSFs without penalizing the catch of commercial species

Simulation of the response of a silicon pixel detector

A model to simulate the response of a silicon pixel detector is described. The effects of geometrical charge sharing, electronic noise threshold dispersion, capacitive coupling between pixel channels and d -rays production have been taken into account. The model has been tested on the Omega3chip, which is the direct predecessor of the ALICE pixel detector, to be used in the inner tracking system of the ALICE experiment. The model is able to reproduce the experimental data and the resulting parameters are consistent with the measurements made on the Omega3chip. Key words:silicon pixel, simulation PACS:07.05.T,29.40.