51 research outputs found
Electrospray Ionization Based Methods for the Generation of Polynuclear Oxo- and Hydroxo Group 6 Anions in the Gas-Phase
Electrospray ionization (ESI) of the Lindqvist (n-Bu4N)2[M6O19] (M = Mo, W) polioxometalates provides a straightforward entry for the generation of an assortment of oxo- and hydroxo anions in the gas-phase. In particular, the series of oxo dianions of general formula [(MO3)nO]2- (n = 2-6; M = Mo, W), monoanions, namely [(MO3)nO]- (n = 1, 2) and [(MO3)n]- (n = 1, 2), and the hydroxo [(MO3)n(OH)]- (n = 1-6) species can be readily generated in the gas-phase upon varying the solvent composition as well as the ionisation conditions (typically the Uc cone voltage). Complementary tandem mass experiments (collision induced dissociation and ion-molecule reactions) are also used aimed to investigate the consecutive dissociation of these species and their intrinsic gas-phase reactivity towards methanol. Special emphasis is paid to some of the key factors of these group 6 anions related to the gas-phase activation of methanol, such as molecular composition, open vs closed shell electronic nature and cluster siz
A three-dimensional adamantane-like nanoscopic cage built from four iodide-bridged triangular Mo3S7 cluster units
Chemical oxidation of a Mo3S7 cluster featuring catecholate
ligands, namely [Mo3S7(Cl4cat)3]2 (Cl4cat = tetrachlorocatecholate),
allows the isolation of a unique nanoscopic
molecular cage made of four iodide-bridged Mo3S7 clusters as
the kinetically favoured produc
Ruthenium molecular complexes immobilized on graphene as active catalysts for the synthesis of carboxylic acids from alcohol dehydrogenation
Ruthenium complexes containing N-heterocyclic carbene ligands functionalized
with different polyaromatic groups (pentafluorophenyl, anthracene, and pyrene) are
immobilized onto the surface of reduced graphene oxide. The hybrid materials composed of
organometallic complexes and graphene are obtained in a single-step process. The hybrid
materials are efficient catalysts for the synthesis of carboxylic acids from the dehydrogenation
of alcohols in aqueous media. The catalytic materials can be recycled up to ten times without
significant loss of activity. The catalytic activity of the pyrene derivative, Pyr-Ru (3) is enhanced
when the ruthenium complex is anchored onto the surface of graphene. The carbonaceous
material limits the degradation of the ruthenium complex resulting in increased activity and
requiring lower catalyst loadings. The catalytic process of the pyrene hybrid material is
heterogeneous in nature due to the strong interaction between the pyrene and graphene. The
catalytic process of the anthracene and pentafluorophenyl hybrid materials is governed by the
so-called âboomerang effectâ. The ruthenium molecular complex is released from and returned
to the graphene surface during the catalytic reaction. Mechanistic insight has been obtained
experimentally and theoretically. The energy profile suggests that the rate-determining step is the water nucleophilic attack to a coordinated aldehyde complex to form a gem-diolate
complex.The authors thank the financial support from MINECO (CTQ2015-69153-C2-2-R and CTQ2015-
67461-P), Generalitat Valenciana (AICO/2015/039), Universitat Jaume I (P1.1B2015-09) and
Universidad de Zaragoza (UZ2014-CIE-01)
A Tetraferrocenyl-Resorcinarene Cavitand as a Redox-Switchable Host of Ammonium Salts
Tetraannulation of a resorcinarene-octaamino cavitand with ferrocenecarboxaldehyde allows the preparation of a tetrabenzimidazole-resorcinarene cavitand with four ferrocenyl moieties directly linked to the C2 atom of the imidazole units. Oxidation of the four ferrocenyl moieties produces important structural modifications of the molecule, as indicated by DFT calculations performed for the neutral and tetraoxidized forms of the cavitand. By means of 1Hâ
NMR spectroscopic analysis, the encapsulating properties of the new tetraferrocenyl-resorcinarene cavitand toward a series of ammonium salts were evaluated, and a clear cutoff point in binding affinity with respect to size was observed. Cyclic voltammetric studies allowed us to estimate the relative association constants for the neutral and oxidized forms of the cavitand, thus indicating that the guest was bound to the neutral (reduced) state of the cavitand and was released from the oxidized form. These redox-addressable conformational and binding properties of the resorcinarene-tetraferrocenyl cavitand constitute all the necessary features of a redox-switchable molecular gripper. By means of mass-spectrometric analysis, we could unambiguously confirm the molar stoichiometry of the hostâguest complex (1:1) and assess the strong guest encapsulation, as indicated by triggering the covalent coupling between host and guest in the gas phase.MEC of Spain (CTQ2011-24055/BQU and CTQ2014-54071-P) and the Universitat Jaume I (P11B2014-02
New insights on organosilane oligomerization mechanisms using ESI-MS and 29Si NMR
The use of electrospray ionization mass spectrometry (ESI-MS) in parallel with
29Si and 1H NMR to elucidate the aqueous speciation and temporal evolution of the
organosilane methyldiethoxysilane (MDES) through hydrolysis and condensation processes is
reported here. A suitable methodological approach for the monitoring of the oligomerization of
MDES under different pH conditions has been developed revealing details on the particular
oligomerization mechanism of this organosilan
Dramatic effect of the gas atmosphere on the deprotection of (Z)-Îł -hydroxy- α , ÎČ-unsaturated esters
The deprotection of O-protected (Z)-α-methyl-Îł-hydroxy-α,ÎČ-unsaturated ester 1 furnishes dimer 2 when the reaction is performed under a nitrogen atmosphere, while compound 3 forms when the reaction is performed under an oxygen atmospher
Ion Mobility Mass Spectrometry Uncovers Guest-Induced Distortions in a Supramolecular Organometallic Metallosquare
The encapsulation of the tetracationic palladiummetallosquare with four pyrene-bis-imidazolylidene ligands[1]4+with aseries of organic molecules was studied byElectrosprayionization Travelling Wave Ion-Mobility MassSpectrometry (ESI TWIM-MS). The method allowed todetermine the Collision Cross Sections (CCSs), whichwereused to assess the sizechanges experienced by the host uponencapsulation of the guest molecules.When fullerenes wereused as guests,the host is expanded DCCS 13 2and 23 2,forC60or C70,respectively.The metallorectangle [1]4+was alsoused for the encapsulation of aseries of polycyclic aromatichydrocarbons (PAHs) and naphthalenetetracarboxylic diimide(NTCDI), to form complexes of formula [(NTCDI)2-(PAH)@1]4+.For these host:guest adducts,the ESI IM-MSstudies revealed that [1]4+is expanded by 47â49 2.. Theenergy-minimized structures of [1]4+,[C60@1]4+,[C70@1]4+,[(NTCDI)2(corannulene)@1]4+in the gas phase were obtainedby DFT calculations.IntroductionFunding for open access charge: CRUE-Universitat Jaume
[Cr(dmbipy)(ox)2]â: a new bis-oxalato building block for metal assembling. Crystal structures and magnetic properties of XPh4[Cr(dmbipy)(ox)2]·5H2O (X = P and As), {Ba(H2O)2[Cr(dmbipy)(ox)2]2}n·17/2nH2O and {Ag(H2O)[Cr(dmbipy)(ox)2]}n·3nH2O
The synthesis, X-ray structure and variable-temperature magnetic study of new compounds of formula
PPh4
[Cr(dmbipy)(ox)2
]5H2O (2),
{Ba(H2O)2[Cr(dmbipy)(ox)2]2}n3nH2O (4) (PPh4
+
Œ tetraphenylphosphonium cation; AsPh4
+
Œ tetraphenylarsonium cation; dmbipy Œ 4,4
0
-dimethyl-
2,2
0
-bipyridine; ox
2
Œ oxalate dianion) are reported herein. The isomorphous compounds 1 and 2 are
made up of discrete [Cr(dmbipy)(ox)2]
anions, XPh4
+
cations [X Œ P (1) and As (2)] and uncoordinated
water molecules. The chromium environment in 1 and 2 is distorted octahedral with CrâO and CrâN
bond distances varying in the ranges 1.950(2)â1.9782(12) and 2.047(3)â2.0567(14) AË
, respectively. The
angles subtended at the chromium atom by the two bidentate oxalate ligands cover the range 82.58(10)â
83.11(5)
, and they are somewhat greater than those concerning the chelating dmbipy [79.04(10) (1) and
79.24(5)
(2)]. The [Cr(dmbipy)(ox)2]
unit of 1 and 2 also occurs in 3 and 4 but it adopts different
coordination modes. It acts as a chelating ligand through its two oxalate groups towards the divalent
barium cations in 3 affording neutral chains with diamond-shaped units sharing the barium atoms,
while the two other corners are occupied by two crystallographically independent chromium atoms.
The barium atom in 3 is coordinated by eight oxygen atoms from four oxalate groups and two aqua
ligands. The structure of 4 consists of neutral bimetallic layers where the [Cr(dmbipy)(ox)2]
unit acts as
a ligand towards the univalent silver(I) cation through its two oxalate groups, one of them being
bidentate and the other bidentate/monodentate (outer). Each silver atom is six-coordinated with
a water molecule and ïŹve oxygen atoms from three oxalate groups building a highly distorted
octahedral environment. Magnetic susceptibility measurements for 1â4 in the temperature range 1.9â
300 K show the occurrence of weak ferro- (1 and 2) and antiferromagnetic (3 and 4) interactions which
are mediated by pâp stacking between dmbipy ligands through the spin polarization mechanism. A
comparative study of the potentiality of the [Cr(AA)(ox)2]
unit (AA Œ bidentate nitrogen donor) as
a building bl
Identification and characterization of a novel cathinone derivative 1-(2,3dihydro-1H-inden-5-yl)-2-phenyl-2-(pyrrolidin-1-yl)-ethanone seized by customs in Jersey
A suspicious white powder labeled âidanyl-biphenyl-amninone,â which was seized by customs officials at the "channel island" of Jersey, UK, was brought to our laboratory for identification and characterization of its structure. The elucidation process required the use of several complementary analytical techniques, including gas chromatographyâmass spectrometry, liquid chromatography coupled with high-resolution mass spectrometry, nuclear magnetic resonance spectroscopy, and X-ray crystallography. The unknown compound was ultimately identified as 1-(2,3-dihydro-1H-inden-5-yl)-2-phenyl-2-(pyrrolidin-1-yl)-ethanone, a novel cathinone derivative. To the best of our knowledge, this compound has not been registered in the CAS or IUPAC databases. However, it has recently been marketed on the Internet as âindapyrophenidone,â and we therefore propose this as the common name of the compound. The results of this study may serve forensic and clinical laboratories in the identification of its related compounds with similar backbone structure using the information reported in this article obtained by the application of advanced analytical techniques. It may also lead to timely and effective response on the part of legislators and law enforcement
Radical Mechanism in the Elimination of 2-Arylsulfinyl Esters
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction
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