2,964 research outputs found
Measurement of Activity of Peroxidase Isoenzymes in Flax (\u3cem\u3eLinum usitatissimum\u3c/em\u3e)
Peroxidase isoenzynles may be separated on acrylamide gels and then detected by supplying the substrate in an appropriate reaction system. One such system frequently used contains guaiacol as the hydrogen donor, although this compound has certain drawbacks. Ways of circumventing these drawbacks are suggested, so that quantitative estimates of the activity of individual peroxidase isoenzymes may be obtained
Guiding chemical pulses through geometry: Y-junctions
We study computationally and experimentally the propagation of chemical
pulses in complex geometries.The reaction of interest, CO oxidation, takes
place on single crystal Pt(110) surfaces that are microlithographically
patterned; they are also addressable through a focused laser beam, manipulated
through galvanometer mirrors, capable of locally altering the crystal
temperature and thus affecting pulse propagation. We focus on sudden changes in
the domain shape (corners in a Y-junction geometry) that can affect the pulse
dynamics; we also show how brief, localized temperature perturbations can be
used to control reactive pulse propagation.The computational results are
corroborated through experimental studies in which the pulses are visualized
using Reflection Anisotropy Microscopy.Comment: submitted to Phys. Rev.
Spin-Coupled Local Distortions in Multiferroic Hexagonal HoMnO3
Local structural measurements have been performed on hexagonal HoMnO3 in
order to ascertain the specific changes in bond distances which accompany
magnetic ordering transitions. The transition from paramagnetic to the
antiferromagetic (noncollinear) phase near ~70 K is dominated by changes in the
a-b plane Mn-Mn bond distances. The spin rotation transition near ~40 K
involves both Mn-Mn and nearest neighbor Ho-Mn interactions while the low
temperature transition below 10 K involves all interactions, Mn-Mn, Ho-Mn
(nearest and next nearest) and Ho-Ho correlations. These changes in bond
distances reveal strong spin-lattice coupling. The similarity in magnitude of
the change in J(Mn-Mn) and J(Ho-Mn) enhances the system frustration. The
structural changes are interpreted in terms of a model of competing spin order
and local structural distortions. Density functional calculations are used to
estimate the energies associated with ionic displacements. The calculations
also reveal asymmetric polarization of the charge density of Ho, O3 and O4
sites along the z-axis in the ferroelectric phase. This polarization
facilitates coupling between Ho atoms on neighboring planes normal to the
z-axis.Comment: 8 figure
Pressure effects on charge, spin, and metal-insulator transitions in narrow bandwidth manganite PrCaMnO
Pressure effects on the charge and spin states and the relation between the
ferromagnetic and metallic states were explored on the small bandwidth
manganite PrCaMnO (x = 0.25, 0.3, 0.35). Under pressure,
the charge ordering state is suppressed and a ferromagnetic metallic state is
induced in all three samples. The metal-insulator transition temperature
(T) increases with pressure below a critical point P*, above which
T decreases and the material becomes insulating as at the ambient
pressure. The e electron bandwidth and/or band-filling mediate the
pressure effects on the metal-insulator transition and the magnetic transition.
In the small bandwidth and low doping concentration compound (x = 0.25), the
T and Curie temperature (T) change with pressure in a reverse way
and do not couple under pressure. In the x = 0.3 compound, the relation of
T and T shows a critical behavior: They are coupled in the range
of 0.8-5 GPa and decoupled outside of this range. In the x = 0.35
compound, T and T are coupled in the measured pressure range where
a ferromagnetic state is present
Influence of propulsion system size, shape, and location on supersonic aircraft design
The effects of various propulsion system parameters on the characteristics of a supersonic transport were investigated. The effects of arbitrarily scaling engine size on wave drag, friction drag, drag-due-to-lift, wing sizing, airplane balance, and airplane weight were studied. These evaluations were made for two families of nacelle shapes, resulting from typical turbojet and turbofan installations. Also examined were effects of nacelle location, and the wing camber plane deformations required to cancel the nacelle interference pressure field at cruise Mach number (2.7 M) were determined. The most drag-sensitive parameter is found to be nacelle shape. Similarly, wing deformation requirements are found to be primarily affected by nacelle shape. Effects of engine size variations are noted primarily in airplane gross weight
Searching For Integrated Sachs-Wolfe Effect Beyond Temperature Anisotropies: CMB E-mode Polarization-Galaxy Cross Correlation
The cross-correlation between cosmic microwave background (CMB) temperature
anisotropies and the large scale structure (LSS) traced by the galaxy
distribution, or sources at different wavelengths, is now well known. This
correlation results from the integrated Sachs-Wolfe (ISW) effect in CMB
anisotropies generated at late times due to the dark energy component of the
Universe. In a reionized universe, the ISW quadrupole rescatters and
contributes to the large-scale polarization signal. Thus, in principle, the
large-scale polarization bump in the E-mode should also be correlated with the
galaxy distribution. Unlike CMB temperature-LSS correlation that peaks for
tracers at low redshifts this correlation peaks mostly at redshifts between 1
and 3. Under certain conditions, mostly involving a low optical depth to
reionization, if the Universe reionized at a redshift around 6, the cross
polarization-source signal is marginally detectable, though challenging as it
requires all-sky maps of the large scale structure at redshifts between 1 and
3. If the Universe reionized at a redshift higher than 10, it is unlikely that
this correlation will be detectable even with no instrumental noise all-sky
maps. While our estimates do not guarantee a detection unknown physics related
to the dark energy as well as still uncertain issues related to the large
angular scale CMB and polarization anisotropies may motivate attempts to
measure this correlation using upcoming CMB polarization E-mode maps.Comment: 13 pages; 3 figure panels, JCAP submitte
Localized Gradual Photomediated Brightness and Lifetime Increase of Superacid Treated Monolayer MoS
Monolayer semiconducting transition metal dichalcogenides (S-TMDs) have been
extensively studied as materials for next-generation optoelectronic devices due
to their direct band gap and high exciton binding energy at room temperature.
Under a superacid treatment of bis(trifluoromethane)sulfonimide (TFSI),
sulfur-based TMDs such as MoS can emit strong photoluminescence (PL) with
photoluminescence quantum yield (PLQY) approaching unity. However, the
magnitude of PL enhancement varies by more than two orders of magnitude in
published reports. A major culprit behind the discrepancy is sulfur-based TMD's
sensitivity to above band-gap photostimulation. Here, we present a detailed
study of how TFSI-treated MoS reacts to photostimulation with increasing PL
occurring hours after constant or pulsed laser exposure. The PL of TFSI-treated
MoS is enhanced up to 74 times its initial intensity after 5 hours of
continuous exposure to 532nm laser light. Photostimulation also enhances the PL
of untreated MoS but with a much smaller enhancement. Caution should be
taken when probing MoS PL spectra as above-bandgap light can alter the
resulting intensity and peak wavelength of the emission over time. The presence
of air is verified to play a key role in the photostimulated enhancement
effect. Additionally, the rise of PL intensity is mirrored by an increase in
measured carrier lifetime of up to ~400ps consistent with the suppression of
non-radiative pathways. This work demonstrates why variations in PL intensity
are observed across samples and provides an understanding of the changes in
carrier lifetimes to better engineer next-generation optoelectronic devices.Comment: Main document: 15 pages, 4 figures. Supplemental document: 12 pages,
7 figure
Towards Precision LSST Weak-Lensing Measurement - I: Impacts of Atmospheric Turbulence and Optical Aberration
The weak-lensing science of the LSST project drives the need to carefully
model and separate the instrumental artifacts from the intrinsic lensing
signal. The dominant source of the systematics for all ground based telescopes
is the spatial correlation of the PSF modulated by both atmospheric turbulence
and optical aberrations. In this paper, we present a full FOV simulation of the
LSST images by modeling both the atmosphere and the telescope optics with the
most current data for the telescope specifications and the environment. To
simulate the effects of atmospheric turbulence, we generated six-layer phase
screens with the parameters estimated from the on-site measurements. For the
optics, we combined the ray-tracing tool ZEMAX and our simulated focal plane
data to introduce realistic aberrations and focal plane height fluctuations.
Although this expected flatness deviation for LSST is small compared with that
of other existing cameras, the fast f-ratio of the LSST optics makes this focal
plane flatness variation and the resulting PSF discontinuities across the CCD
boundaries significant challenges in our removal of the systematics. We resolve
this complication by performing PCA CCD-by-CCD, and interpolating the basis
functions using conventional polynomials. We demonstrate that this PSF
correction scheme reduces the residual PSF ellipticity correlation below 10^-7
over the cosmologically interesting scale. From a null test using HST/UDF
galaxy images without input shear, we verify that the amplitude of the galaxy
ellipticity correlation function, after the PSF correction, is consistent with
the shot noise set by the finite number of objects. Therefore, we conclude that
the current optical design and specification for the accuracy in the focal
plane assembly are sufficient to enable the control of the PSF systematics
required for weak-lensing science with the LSST.Comment: Accepted to PASP. High-resolution version is available at
http://dls.physics.ucdavis.edu/~mkjee/LSST_weak_lensing_simulation.pd
Temporal variability and statistics of the Strehl ratio in adaptive-optics images
We have investigated the temporal variability and statistics of the
"instantaneous" Strehl ratio. The observations were carried out with the 3.63-m
AEOS telescope equipped with a high-order adaptive optics system. In this paper
Strehl ratio is defined as the peak intensity of a single short exposure. We
have also studied the behaviour of the phase variance computed on the
reconstructed wavefronts. We tested the Marechal approximation and used it to
explain the observed negative skewness of the Strehl ratio distribution. The
estimate of the phase variance is shown to fit a three-parameter Gamma
distribution model. We show that simple scaling of the reconstructed wavefronts
has a large impact on the shape of the Strehl ratio distribution.Comment: submitted to PAS
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