Treatment of end-of-life concrete in an innovative heating-air classification system for circular cement-based products

A stronger commitment towards Green Building and circular economy, in response to environmental concerns and economic trends, is evident in modern industrial cement and concrete production processes. The critical demand for an overall reduction in the environmental impact of the construction sector can be met through the consumption of high-grade supplementary raw materials. Advanced solutions are under development in current research activities that will be capable of up-cycling larger quantities of valuable raw materials from the fine fractions of End-of-Life (EoL) concrete waste. New technology, in particular the Heating-Air classification System (HAS), simultaneously applies a combination of heating and separation processes within a fluidized bed-like chamber under controlled temperatures (±600 °C) and treatment times (25–40 s). In that process, moisture and contaminants are removed from the EoL fine concrete aggregates (0–4 mm), yielding improved fine fractions, and ultrafine recycled concrete particles (<0.125 mm), consisting mainly of hydrated cement, thereby adding value to finer EoL concrete fractions. In this study, two types of ultrafine recycled concrete (either siliceous or limestone EoL concrete waste) are treated in a pilot HAS technology for their conversion into Supplementary Cementitious Material (SCM). The physico-chemical effect of the ultrafine recycled concrete particles and their potential use as SCM in new cement-based products is assessed by employing substitutions of up to 10% of the conventional binder. The environmental viability of their use as SCM is then evaluated in a Life Cycle Assessment (LCA). The results demonstrated accelerated hydration kinetics of the mortars that incorporated these SCMs at early ages and higher mechanical strengths at all curing ages. Optimal substitutions were established at 5%. The results suggested that the overall environmental impact could be reduced by up to 5% when employing the ultrafine recycled concrete particles as SCM in circular cement-based products, reducing greenhouse gas emissions by as much as 41 kg CO2 eq./ton of cement (i.e. 80 million tons CO2 eq./year). Finally, the environmental impacts were reduced even further by running the HAS on biofuel rather than fossil fuel.The authors of the present paper, prepared in the framework ofthe Project VEEP "Cost-Effective Recycling of C&DW in High AddedValue Energy Efficient Prefabricated Concrete Components forMassive Retrofitting of our Built Environment", wish to acknowl-edge the European Commission for its support. This project hasreceived funding from the European Union’s Horizon 2020 researchand innovation programme under grant agreement No 723582.This paper reflects only the author’s view and the European Com-mission is not responsible for any use that may be made of theinformation it contains.The authors are also grateful to the Spanish Ministry of Science,Innovation and Universities (MICIU) and the European RegionalDevelopment Fund (FEDER) for funding this line of research(RTI2018-097074-B-C21)

Data Adequacy by an Extended Analytic Hierarchy Process for Inverse Uncertainty Quantification in Nuclear Safety Analysis

Data Adequacy (DA) assessment of experimental databases must be performed to control the impact of user effects on the results provided by the Thermal-Hydraulic (T-H) codes employed for the safety assessment of Nuclear Power Plants (NPPs). The activity is typically based on expert judgement, which, however, lacks a rigorous treatment of the uncertainties. With the objective to overcome this limitation, we propose a Multi-Criteria Decision Making (MCDM) approach to consider the Representativeness (R) and Completeness (C) of the databases by an Analytic Hierarchy Process (AHP) combined with Interval Analysis (IA) and Monte Carlo Simulation (MCS) to quantify the uncertainty. The approach for DA is exemplified on the databases made available to the participants of the ATRIUM (Application Tests for Realization of Inverse Uncertainty quantification and validation Methodologies in thermal hydraulics) project promoted by the WGAMA of the OECD-NEA, whose ultimate objective is the systematic application of Inverse Uncertainty Quantification (IUQ) methodologies to assess the uncertainties affecting the T-H model of an Intermediate Break Loss Of Coolant Accident (IBLOCA) of a Light Water Reactor (LWR). The outcomes of the application show that the proposed approach allows overcoming some of the limitations of expert-based approaches, reducing the reliance on subjective evaluations through the incorporation of quantitative metrics in the analysis and via the proper quantification of the uncertainty

Complexity reduction of astrochemical networks

We present a new computational scheme aimed at reducing the complexity of the chemical networks in astrophysical models, one which is shown to markedly improve their computational efficiency. It contains a flux-reduction scheme that permits to deal with both large and small systems. This procedure is shown to yield a large speed-up of the corresponding numerical codes and provides good accord with the full network results. We analyse and discuss two examples involving chemistry networks of the interstellar medium and show that the results from the present reduction technique reproduce very well the results from fuller calculations.Comment: 9 pages, 7 figures, accepted for publication in Monthly Notices of the Royal Astronomical Society Main Journa

In vivo manipulation of the extracellular matrix induces vascular regression in a basal chordate.

We investigated the physical role of the extracellular matrix (ECM) in vascular homeostasis in the basal chordate Botryllus schlosseri, which has a large, transparent, extracorporeal vascular network encompassing an area &gt;100 cm2 We found that the collagen cross-linking enzyme lysyl oxidase is expressed in all vascular cells and that in vivo inhibition using β-aminopropionitrile (BAPN) caused a rapid, global regression of the entire network, with some vessels regressing &gt;10 mm within 16 h. BAPN treatment changed the ultrastructure of collagen fibers in the vessel basement membrane, and the kinetics of regression were dose dependent. Pharmacological inhibition of both focal adhesion kinase (FAK) and Raf also induced regression, and levels of phosphorylated FAK in vascular cells decreased during BAPN treatment and FAK inhibition but not Raf inhibition, suggesting that physical changes in the vessel ECM are detected via canonical integrin signaling pathways. Regression is driven by apoptosis and extrusion of cells through the basal lamina, which are then engulfed by blood-borne phagocytes. Extrusion and regression occurred in a coordinated manner that maintained vessel integrity, with no loss of barrier function. This suggests the presence of regulatory mechanisms linking physical changes to a homeostatic, tissue-level response

A Hedonism Hub in the Human Brain

Human values are abstract ideals that motivate behavior. The motivational nature of human values raises the possibility that they might be underpinned by brain structures that are particularly involved in motivated behavior and reward processing. We hypothesized that variation in subcortical hubs of the reward system and their main connecting pathway, the superolateral medial forebrain bundle (slMFB) is associated with individual value orientation. We conducted Pearson's correlation between the scores of 10 human values and the volumes of 14 subcortical structures and microstructural properties of the medial forebrain bundle in a sample of 87 participants, correcting for multiple comparisons (i.e.,190). We found a positive association between the value that people attach to hedonism and the volume of the left globus pallidus (GP).We then tested whether microstructural parameters (i.e., fractional anisotropy and myelin volume fraction) of the slMFB, which connects with the GP, are also associated to hedonism and found a significant, albeit in an uncorrected level, positive association between the myelin volume fraction within the left slMFB and hedonism scores. This is the first study to elucidate the relationship between the importance people attach to the human value of hedonism and structural variation in reward-related subcortical brain regions

The Work of Roberto Busa SJ: Open Spaces between Computation and Hermeneutics

A review of the achievements of Fr. Busa over the course of his 60 years of work in the area of computational linguistics: internal hypertexts, the systematization of allographs, lemmatization, homographs and typologies; the lexical system; the laws of economy for graphemes, for semantic typology, for heterogeneity among terms, and of the two lexical hemispheres. Finally, the project of disciplined languages is mentioned, a response to the linguistic challenge resulting from informational globalization

How does quality enter into health care purchasing decisions?

A number of employers, business consortia, and public purchasers are promoting value-based purchasing as a way to improve the quality of patient care. Some purchasers are using publicly available information on health plan and provider performance to make their health plan and provider choices, while others are using their market power to drive improvements in patient care and safety. This article examines six key strategies used by purchasers