Ground-based Photon Path Measurements from Solar Absorption Spectra of the O2 A-band

High-resolution solar absorption spectra obtained from Table Mountain Facility (TMF, 34.38degN, 117.68degW, 2286 m elevation) have been analyzed in the region of the O2 A-band. The photon paths of direct sunlight in clear sky cases are retrieved from the O2 absorption lines and compared with ray-tracing calculations based on the solar zenith angle and surface pressure. At a given zenith angle, the ratios of retrieved to geometrically derived photon paths are highly precise (approx.0.2%), but they vary as the zenith angle changes. This is because current models of the spectral lineshape in this band do not properly account for the significant absorption that exists far from the centers of saturated lines. For example, use of a Voigt function with Lorentzian far wings results in an error in the retrieved photon path of as much as 5%, highly correlated with solar zenith angle. Adopting a super-Lorentz function reduces, but does not completely eliminate this problem. New lab measurements of the lineshape are required to make further progress

Mapping CH_4 : CO_2 ratios in Los Angeles with CLARS-FTS from Mount Wilson, California

The Los Angeles megacity, which is home to more than 40% of the population in California, is the second largest megacity in the United States and an intense source of anthropogenic greenhouse gases (GHGs). Quantifying GHG emissions from the megacity and monitoring their spatiotemporal trends are essential to be able to understand the effectiveness of emission control policies. Here we measure carbon dioxide (CO_2) and methane (CH_4) across the Los Angeles megacity using a novel approach – ground-based remote sensing from a mountaintop site. A Fourier transform spectrometer (FTS) with agile pointing optics, located on Mount Wilson at 1.67 km above sea level, measures reflected near-infrared sunlight from 29 different surface targets on Mount Wilson and in the Los Angeles megacity to retrieve the slant column abundances of CO_2, CH_4 and other trace gases above and below Mount Wilson. This technique provides persistent space- and time-resolved observations of path-averaged dry-air GHG concentrations, XGHG, in the Los Angeles megacity and simulates observations from a geostationary satellite. In this study, we combined high-sensitivity measurements from the FTS and the panorama from Mount Wilson to characterize anthropogenic CH_4 emissions in the megacity using tracer–tracer correlations. During the period between September 2011 and October 2013, the observed XCH_4 : XCO_2 excess ratio, assigned to anthropogenic activities, varied from 5.4 to 7.3 ppb CH_4 (ppm CO_2)^(−1), with an average of 6.4 ± 0.5 ppb CH_4 (ppm CO_2)^(−1) compared to the value of 4.6 ± 0.9 ppb CH_4 (ppm CO_2)^(−1) expected from the California Air Resources Board (CARB) bottom-up emission inventory. Persistent elevated XCH_4 : XCO_2 excess ratios were observed in Pasadena and in the eastern Los Angeles megacity. Using the FTS observations on Mount Wilson and the bottom-up CO_2 emission inventory, we derived a top-down CH_4 emission of 0.39 ± 0.06 Tg CH_4 year^(−1) in the Los Angeles megacity. This is 18–61% larger than the state government's bottom-up CH_4 emission inventory and consistent with previous studies

Monthly trends of methane emissions in Los Angeles from 2011 to 2015 inferred by CLARS-FTS observations

This paper presents an analysis of methane emissions from the Los Angeles Basin at monthly timescales across a 4-year time period – from September 2011 to August 2015. Using observations acquired by a ground-based near-infrared remote sensing instrument on Mount Wilson, California, combined with atmospheric CH_4–CO_2 tracer–tracer correlations, we observed −18 to +22 % monthly variability in CH_4 : CO_2 from the annual mean in the Los Angeles Basin. Top-down estimates of methane emissions for the basin also exhibit significant monthly variability (−19 to +31 % from annual mean and a maximum month-to-month change of 47 %). During this period, methane emissions consistently peaked in the late summer/early fall and winter. The estimated annual methane emissions did not show a statistically significant trend over the 2011 to 2015 time period

Vicarious calibration of the Tropospheric Monitoring Instrument (TROPOMI) short-wave infrared (SWIR) module over the Railroad Valley Playa

The short-wave infrared (SWIR) module of the Tropospheric Monitoring Instrument (TROPOMI) on board the ESA's Sentinel-5 precursor (S5p) satellite has been very stable during its 5 years in orbit. Calibration was performed on the ground, complemented by measurements during in-flight instrument commissioning. The radiometric response and general performance of the SWIR module are monitored by on-board calibration sources. We show that after 5 years in orbit, TROPOMI-SWIR has continued to show excellent performance with degradation of at most 0.1 % in transmission and having lost less than 0.3 % of the detector pixels. Independent validation of the instrument calibration, via vicarious calibration, can be done through comparisons with ground-based reflectance data. In this work, ground measurements at the Railroad Valley Playa, a valley in central Nevada that is often used as a reference for satellite measurements, are used to perform vicarious calibration of the TROPOMI-SWIR measurements. This is done using dedicated measurement campaigns as well as automated reflectance measurements within the RADCALNET programme. As such, TROPOMI-SWIR is an excellent test case to explore the methodology of vicarious calibration applied to infrared spectroscopy. Using methodology developed for the vicarious calibration of the OCO-2 and GOSAT missions, the absolute radiometry of TROPOMI-SWIR performance is independently verified to be stable down to ∼ 6 %–10 % using the Railroad Valley when both the absolute and relative radiometric calibrations are applied. Differences with the on-board calibration originate from the bidirectional reflection distribution function (BRDF) effects of the desert surface, the large variety in viewing angles, and the different sizes of footprints of the TROPOMI pixels. Vicarious calibration is shown to be an additional valuable tool in validating radiance-level performances of infrared instruments such as TROPOMI-SWIR in the field of atmospheric composition. It remains clear that for instruments of similar design and resolution to TROPOMI-SWIR, on-board calibration sources will continue to provide superior results due to the limitations of the vicarious calibration method.</p

Near-infrared remote sensing of Los Angeles trace gas distributions from a mountaintop site

The Los Angeles basin is a significant anthropogenic source of major greenhouse gases (CO2 and CH4) and the pollutant CO, contributing significantly to regional and global climate change. We present a novel approach for monitoring the spatial and temporal distributions of greenhouse gases in the Los Angeles basin using a high-resolution spectroscopic remote sensing technique. A new Fourier transform spectrometer called CLARS-FTS has been deployed since May, 2010, at Jet Propulsion Laboratory (JPL)'s California Laboratory for Atmospheric Remote Sensing (CLARS) on Mt. Wilson, California, for automated long-term measurements of greenhouse gases. The instrument design and performance of CLARS-FTS are presented. From its mountaintop location at an altitude of 1673 m, the instrument points at a programmed sequence of ground target locations in the Los Angeles basin, recording spectra of reflected near-IR solar radiation. Column-averaged dry-air mole fractions of greenhouse gases (XGHG) including XCO2, XCH4, and XCO are retrieved several times per day for each target. Spectra from a local Spectralon&reg; scattering plate are also recorded to determine background (free tropospheric) column abundances above the site. Comparisons between measurements from LA basin targets and the Spectralon&reg; plate provide estimates of the boundary layer partial column abundances of the measured species. Algorithms are described for transforming the measured interferograms into spectra, and for deriving column abundances from the spectra along with estimates of the measurement precision and accuracy. The CLARS GHG measurements provide a means to infer relative, and possibly absolute, GHG emissions

Noise Properties of the BOOMERANG Instrument

In this paper we report a short description of the BOOMERANG experiment explaining his scientific goal and the technologies implied. We concentrate then on the analysis of the noise properties discussing in particular the scan synchronous noise. Finally we present the calibration technique and the sensitivity of all the channels

ℓ-space spectroscopy of the Cosmic Microwave Background with the BOOMERanG experiment

The BOOMERanG experiment has recently produced detailed maps of the Cosmic Microwave Background, where sub-horizon structures are resolved with good signal to noise ratio. A power spectrum (spherical harmonics) analysis of the maps detects three peaks, at multipoles ℓ = (213_(-13)^(+10)),(541_(-32)^(+20))(845_(-25)^(+12)). In this paper we discuss the data analysis and the implications of these results for cosmology

B2K: The polarization-sensitive BOOMERanG experiment

We describe the new BOOMERanG payload, which is being prepared for a new circum-antarctic flight, with the aim to detect the linear polarization of the Cosmic Microwave Background (CMB). In addition to polarization capabilities, obtained by means of special bolometers, the instrument has been improved in the attitude reconstruction system and in the calibration system

Measurements of Humidity in the Atmosphere and Validation Experiments (MOHAVE)-2009: overview of campaign operations and results

International audienceThe Measurements of Humidity in the Atmosphere and Validation Experiment (MOHAVE) 2009 campaign took place on 11-27 October 2009 at the JPL Table Mountain Facility in California (TMF). The main objectives of the campaign were to (1) validate the water vapor measurements of several instruments, including, three Raman lidars, two microwave radiometers, two Fourier-Transform spectrometers, and two GPS receivers (column water), (2) cover water vapor measurements from the ground to the mesopause without gaps, and (3) study upper tropospheric humidity variability at timescales varying from a few minutes to several days. A total of 58 radiosondes and 20 Frost-Point hygrometer sondes were launched. Two types of radiosondes were used during the campaign. Non negligible differences in the readings between the two radiosonde types used (Vaisala RS92 and InterMet iMet-1) made a small, but measurable impact on the derivation of water vapor mixing ratio by the Frost-Point hygrometers. As observed in previous campaigns, the RS92 humidity measurements remained within 5 % of the Frost-point in the lower and mid-troposphere, but were too dry in the upper troposphere. Over 270 h of water vapor measurements from three Raman lidars (JPL and GSFC) were compared to RS92, CFH, and NOAA-FPH. The JPL lidar profiles reached 20 km when integrated all night, and 15 km when integrated for 1 h. Excellent agreement between this lidar and the frost-point hygrometers was found throughout the measurement range, with only a 3 % (0.3 ppmv) mean wet bias for the lidar in the upper troposphere and lower stratosphere (UTLS). The other two lidars provided satisfactory results in the lower and mid-troposphere (2-5 % wet bias over the range 3-10 km), but suffered from contamination by fluorescence (wet bias ranging from 5 to 50 % between 10 km and 15 km), preventing their use as an independent measurement in the UTLS. The comparison between all available stratospheric sounders allowed to identify only the largest biases, in particular a 10 % dry bias of the Water Vapor Millimeter-wave Spectrometer compared to the Aura-Microwave Limb Sounder. No other large, or at least statistically significant, biases could be observed. Total Precipitable Water (TPW) measurements from six different co-located instruments were available. Several retrieval groups provided their own TPW retrievals, resulting in the comparison of 10 different datasets. Agreement within 7 % (0.7 mm) was found between all datasets. Such good agreement illustrates the maturity of these measurements and raises confidence levels for their use as an alternate or complementary source of calibration for the Raman lidars. Tropospheric and stratospheric ozone and temperature measurements were also available during the campaign. The water vapor and ozone lidar measurements, together with the advected potential vorticity results from the high-resolution transport model MIMOSA, allowed the identification and study of a deep stratospheric intrusion over TMF. These observations demonstrated the lidar strong potential for future long-term monitoring of water vapor in the UTLS