Anodic Alumina Membranes: From Electrochemical Growth to Use as Template for Fabrication of Nanostructured Electrodes

The great success of anodic alumina membranes is due to their morphological features coupled to both thermal and chemical stability. The electrochemical fabrication allows accurate control of the porous structure: in fact, the membrane morphological characteristics (pore length, pore diameter and cell density) can be controlled by adjusting the anodizing parameters (bath, temperature, voltage and time). This article deals with both the fabrication and use of anodic alumina membranes. In particular, we will show the specific role of the addition of aluminum ions to phosphoric acid-based anodizing solution in modifying the morphology of anodic alumina membranes. Anodic alumina membranes were obtained at −1◦ C in aqueous solutions of 0.4 M H3 PO4 added with different amounts of Al(OH)3 . For sake of completeness, the formation of PAA in pure 0.4 M H3 PO4 in otherwise identical conditions was also investigated. We found that the presence of Al(OH)3 in solution highly affects the morphology of the porous layer. In particular, at high Al(OH)3 concentration (close to saturation) more compact porous layers were formed with narrow pores separated by thick oxide. The increase in the electric charge from 20 to 160 C cm−2 also contributes to modifying the morphology of porous oxide. The obtained anodic alumina membranes were used as a template to fabricate a regular array of PdCo alloy nanowires that is a valid alternative to Pt for hydrogen evolution reaction. The PdCo alloy was obtained by electrodeposition and we found that the composition of the nanowires depends on the concentration of two metals in the deposition solution

Prelude to the Anthropocene: Two new North American Land Mammal Ages (NALMAs)

Human impacts have left and are leaving distinctive imprints in the geological record. Here we show that in North America, the human-caused changes evident in the mammalian fossil record since c. 14,000 years ago are as pronounced as earlier faunal changes that subdivide Cenozoic epochs into the North American Land Mammal Ages (NALMAs). Accordingly, we define two new North American Land Mammal Ages, the Santarosean and the Saintagustinean, which subdivide Holocene time and complete a biochronologic system that has proven extremely useful in dating terrestrial deposits and in revealing major features of faunal change through the past 66 million years. The new NALMAs highlight human-induced changes to the Earth system, and inform the debate on whether or not defining an Anthropocene epoch is justified, and if so, when it began

characterization of the 8 kbp region of the mtdnas of several cytoplasm male sterile sunflower lines coding for atpa and orf522 genes

ABSTRACTThe characterization of the region of mtDNA coiling for atpA and orf522 genes in several different isogenic couples of fertile and male-sterile sunflower lines reveals that the rearrangements occurred in all the male-sterile lines are identical. The only segment of the 5 khp insert of the CMS89 line which is transcribed in flowers at different developmental stages is part of the orf522 gene. A possible nuclear origin of the 5 kbp insert is proposed

Pandemia e Infodemia. Informazione, conoscenza, automazione

This article aims to explore the connection between the conflicts in information policies occurring during the present pandemic situation and the potential abuse of automation technologies in the processing of information. From a historical point of view, the connection between an effective elaboration of information and the development of automation technologies has been devised by authors such as Norbert Wiener, Claude Shannon and Alan Turing, at the very beginning of the modern theory of information. This seemed to be justified by historical circumstances that are still quoted in order to discipline and “militarise” the spreading of information during the pandemic. By taking reference to authors such as Gilbert Simondon and Bernard Stiegler, on the contrary, it may be shown that automation cannot by itself guarantee the most appropriate diffusion and sharing of information during a global crisis, whereas, according to these authors, a certain margin of indetermination – freedom and concreteness – must be implemented in any automatic process to let a machine, even the most algorythmic one, work properly and rightly serve the cause of its users

Transcriptome changes induced by Arbuscular mycorrhizal symbiosis in leaves of durum wheat (Triticum durum Desf.) promote higher salt tolerance

The salinity of soil is a relevant environmental problem around the world, with climate change raising its relevance, particularly in arid and semiarid areas. Arbuscular Mycorrhizal Fungi (AMF) positively affect plant growth and health by mitigating biotic and abiotic stresses, including salt stress. The mechanisms through which these benefits manifest are, however, still unclear. This work aimed to identify key genes involved in the response to salt stress induced by AMF using RNA-Seq analysis on durum wheat (Triticum turgidum L. subsp. durum Desf. Husn.). Five hundred sixty-three differentially expressed genes (DEGs), many of which involved in pathways related to plant stress responses, were identified. The expression of genes involved in trehalose metabolism, RNA processing, vesicle trafficking, cell wall organization, and signal transduction was significantly enhanced by the AMF symbiosis. A downregulation of genes involved in both enzymatic and non-enzymatic oxidative stress responses as well as amino acids, lipids, and carbohydrates metabolisms was also detected, suggesting a lower oxidative stress condition in the AMF inoculated plants. Interestingly, many transcription factor families, including WRKY, NAC, and MYB, already known for their key role in plant abiotic stress response, were found differentially expressed between treatments. This study provides valuable insights on AMF-induced gene expression modulation and the beneficial effects of plant-AMF interaction in durum wheat under salt stress

SNP genotyping elucidates the genetic diversity of Magna Graecia grapevine germplasm and its historical origin and dissemination

Background: Magna Graecia is the ancient name for the modern geopolitical region of South Italy extensively populated by Greek colonizers, shown by archeological and historical evidence to be the oldest wine growing region of Italy, crucial for the spread of specialized viticulture around Mediterranean shores. Here, the genetic diversity of Magna Graecia grape germplasm was assessed and its role in grapevine propagation around the Mediterranean basin was underlined. Results: A large collection of grapevines from Magna Graecia was compared with germplasm from Georgia to the Iberian Peninsula using the 18 K SNP array. A high level of genetic diversity of the analyzed germplasm was determined; clustering, structure analysis and DAPC (Discriminant Analysis of Principal Components) highlighted the genetic relationships among genotypes from South Italy and the Eastern Mediterranean (Greece). Gene flow from east (Georgia) to west (Iberian Peninsula) was identified throughout the large number of detected admixed samples. Pedigree analysis showed a complex and well-structured network of first degree relationships, where the cultivars from Magna Graecia were mainly involved. Conclusions: This study provided evidence that Magna Graecia germplasm was shaped by historical events that occurred in the area due to the robust link between South Italian and Greek genotypes, as well as, by the availability of different thermal resources for cultivars growing in such different winegrowing areas. The uniqueness of this ampelographic platform was mainly an outcome of complex natural or human-driven crosses involving elite cultivars

Mission Operations and Navigation Toolkit Environment

MONTE (Mission Operations and Navigation Toolkit Environment) Release 7.3 is an extensible software system designed to support trajectory and navigation analysis/design for space missions. MONTE is intended to replace the current navigation and trajectory analysis software systems, which, at the time of this reporting, are used by JPL's Navigation and Mission Design section. The software provides an integrated, simplified, and flexible system that can be easily maintained to serve the needs of future missions in need of navigation services

Photometric and spectroscopic analysis of the Type II SN 2020jfo with a short plateau

We present high-cadence photometric and spectroscopic observations of SN~2020jfo in ultraviolet and optical/near-infrared bands starting from $\sim 3$ to $\sim 434$ days after the explosion, including the earliest data with the 10.4\,m GTC. SN~2020jfo is a hydrogen-rich Type II SN with a relatively short plateau duration ($67.0 \pm 0.6$ days). When compared to other Type II supernovae (SNe) of similar or shorter plateau lengths, SN~2020jfo exhibits a fainter peak absolute $V$-band magnitude ($M_V = -16.90 \pm 0.34$ mag). SN~2020jfo shows significant H$\alpha$ absorption in the plateau phase similar to that of typical SNe~II. The emission line of stable [Ni~II] $\lambda$7378, mostly seen in low-luminosity SNe~II, is very prominent in the nebular-phase spectra of SN~2020jfo. Using the relative strengths of [Ni~II] $\lambda$7378 and [Fe~II] $\lambda$7155, we derive the Ni/Fe production (abundance) ratio of 0.08--0.10, which is $\sim 1.5$ times the solar value. The progenitor mass of SN~2020jfo from nebular-phase spectral modelling and semi-analytical modelling falls in the range of 12--15\,$M_\odot$. Furthermore, semi-analytical modelling suggests a massive H envelope in the progenitor of SN~2020jfo, which is unlikely for SNe~II having short plateaus.Comment: 20 pages (plus 5 pages appendix), 19 figures, Accepted for publication in MNRA