Pure hydrogen low-temperature plasma exposure of HOPG and graphene: Graphane formation?

Single- and multilayer graphene and highly ordered pyrolytic graphite (HOPG) were exposed to a pure hydrogen low-temperature plasma (LTP). Characterizations include various experimental techniques such as photoelectron spectroscopy, Raman spectroscopy and scanning probe microscopy. Our photoemission measurement shows that hydrogen LTP exposed HOPG has a diamond-like valence-band structure, which suggests double-sided hydrogenation. With the scanning tunneling microscopy technique, various atomic-scale charge-density patterns were observed, which may be associated with different C-H conformers. Hydrogen-LTP-exposed graphene on SiO₂ has a Raman spectrum in which the D peak to G peak ratio is over 4, associated with hydrogenation on both sides. A very low defect density was observed in the scanning probe microscopy measurements, which enables a reverse transformation to graphene. Hydrogen-LTP-exposed HOPG possesses a high thermal stability, and therefore, this transformation requires annealing at over 1000 °C

Preparation and properties of amorphous MgB2_2/MgO superstructures: A new model disordered superconductor

In this paper we introduce a novel method for fabricating MgB$_2$/MgO multilayers and demonstrate the potential for using them as a new model for disordered superconductors. In this approach we control the annealing of the MgB$_2$ to yield an interesting new class of disordered (amorphous) superconductors with relatively high transition temperatures. The multilayers appear to exhibit quasi-two-dimensional superconductivity with controlled anisotropy. We discuss the properties of the multilayers as the thickness of the components of the bilayers vary.Comment: 7 pages, 8 figure

A Parallax Distance to the Microquasar GRS 1915+105 and a Revised Estimate of its Black Hole Mass

Using the Very Long Baseline Array, we have measured a trigonometric parallax for the micro quasar GRS 1915+105, which contains a black hole and a K-giant companion. This yields a direct distance estimate of 8.6 (+2.0,-1.6) kpc and a revised estimate for the mass of the black hole of 12.4 (+2.0,-1.8) Msun. GRS 1915+105 is at about the same distance as some HII regions and water masers associated with high-mass star formation in the Sagittarius spiral arm of the Galaxy. The absolute proper motion of GRS 1915+105 is -3.19 +/- 0.03 mas/y and -6.24 +/- 0.05 mas/y toward the east and north, respectively, which corresponds to a modest peculiar speed of 22 +/-24 km/s at the parallax distance, suggesting that the binary did not receive a large velocity kick when the black hole formed. On one observational epoch, GRS 1915+105 displayed superluminal motion along the direction of its approaching jet. Considering previous observations of jet motions, the jet in GRS 1915+105 can be modeled with a jet inclination to the line of sight of 60 +/- 5 deg and a variable flow speed between 0.65c and 0.81c, which possibly indicates deceleration of the jet at distances from the black hole >2000 AU. Finally, using our measurements of distance and estimates of black hole mass and inclination, we provisionally confirm our earlier result that the black hole is spinning very rapidly.Comment: 20 pages; 2 tables; 6 figure

The Closest Look at 1H0707-495: X-ray Reverberation Lags with 1.3 Ms of Data

Reverberation lags in AGN were first discovered in the NLS1 galaxy, 1H0707-495. We present a follow-up analysis using 1.3 Ms of data, which allows for the closest ever look at the reverberation signature of this remarkable source. We confirm previous findings of a hard lag of ~100 seconds at frequencies v ~ [0.5 - 4] e-4 Hz, and a soft lag of ~30 seconds at higher frequencies, v ~ [0.6 - 3] e-3 Hz. These two frequency domains clearly show different energy dependences in their lag spectra. We also find evidence for a signature from the broad Fe K line in the high frequency lag spectrum. We use Monte Carlo simulations to show how the lag and coherence measurements respond to the addition of Poisson noise and to dilution by other components. With our better understanding of these effects on the lag, we show that the lag-energy spectra can be modelled with a scenario in which low frequency hard lags are produced by a compact corona responding to accretion rate fluctuations propagating through an optically thick accretion disc, and the high frequency soft lags are produced by short light-travel delay associated with reflection of coronal power-law photons off the disc.Comment: 11 pages, 10 figures. Accepted for publication in MNRA

Enhanced external radiative efficiency for 20.8 efficient single-junction GaInP solar cells

We demonstrate 1.81 eV GaInP solar cells approaching the Shockley-Queisser limit with 20.8% solar conversion efficiency, 8% external radiative efficiency, and 80–90% internal radiative efficiency at one-sun AM1.5 global conditions. Optically enhanced voltage through photon recycling that improves light extraction was achieved using a back metal reflector. This optical enhancement was realized at one-sun currents when the non-radiative Sah-Noyce-Shockley junction recombination current was reduced by placing the junction at the back of the cell in a higher band gap AlGaInP layer. Electroluminescence and dark current-voltage measurements show the separate effects of optical management and non-radiative dark current reduction

The Stability of Strange Star Crusts and Strangelets

We construct strangelets, taking into account electrostatic effects, including Debye screening, and arbitrary surface tension sigma of the interface between vacuum and quark matter. We find that there is a critical surface tension sigma_crit below which large strangelets are unstable to fragmentation and below which quark star surfaces will fragment into a crystalline crust made of charged strangelets immersed in an electron gas. We derive a model-independent relationship between sigma_crit and two parameters that characterize any quark matter equation of state. For reasonable model equations of state, we find sigma_crit typically of order a few MeV/fm^2. If sigma <= sigma_crit, the size-distribution of strangelets in cosmic rays could feature a peak corresponding to the stable strangelets that we construct.Comment: 11 pages, LaTe

CHEMICALLY MODIFIED PHOTOSYNTHETIC BACTERIAL REACTION CENTERS: CIRCULAR DICHROISM, RAMAN RESONANCE, LOW TEMPERATURE ABSORPTION, FLUORESCENCE AND ODMR SPECTRA AND POLYPEPTIDE COMPOSITION OF BOROHYDRIDE TREATED REACTION CENTERS FROM Rhodobacter sphaeroides R26

Reaction centers from Rhodobacter sphaeroides have been modified by treatment with sodium borohydride similar to the original procedure [Ditson et al., Biochim. Biophys. Acta 766, 623 (1984)], and investigated spectroscopically and by gel electrophoresis. (1) Low temperature (1.2 K) absorption, fluorescence, absorption- and fluorescence-detected ODMR, and microwave-induced singlet-triplet absorption difference spectra (MIA) suggest that the treatment produces a spectroscopically homogeneous preparation with one of the ‘additional’ bacteriochlorophylls being removed. The modification does not alter the zero field splitting parameters of the primary donor triplet (TP870). (2) From the circular dichroism and Raman resonance spectra in the1500–1800 cm-1 region, the removed pigment is assigned to BchlM, e.g. the "extra" Bchl on the "inactive" M-branch. (3) A strong coupling among all pigment molecules is deduced from the circular dichroism spectra, because pronounced band-shifts and/or intensity changes occur in the spectral components assigned to all pigments. This is supported by distinct differences among the MIA spectra of untreated and modified reaction centers, as well as by Raman resonance. (4) The modification is accompanied by partial proteolytic cleavage of the M-subunit. The preparation is thus spectroscopically homogeneous, but biochemically heterogenous

Recommendations for headache service organisation and delivery in Europe.

Headache disorders are a major public-health priority, and there is pressing need for effective solutions to them. Better health care for headache—and ready access to it—are central to these solutions; therefore, the organisation of headache-related services within the health systems of Europe becomes an important focus. These recommendations are the result of collaboration between the European Headache Federation and Lifting The Burden: the Global Campaign against Headache. The process of development included wide consultation. To meet the very high level of need for headache care both effectively and efficiently, the recommendations formulate a basic three-level model of health-care organisation rationally spread across primary and secondary health-care sectors, taking account of the different skills and expertise in these sectors. They recognise that health services are differently structured in countries throughout Europe, and not always adequately resourced. Therefore, they aim to be adaptable to suit these differences. They are set out in five sections: needs assessment, description of the model, adaptation, standards and educational implications

Magnon dispersion and thermodynamics in CsNiF_3

We present an accurate transfer matrix renormalization group calculation of the thermodynamics in a quantum spin-1 planar ferromagnetic chain. We also calculate the field dependence of the magnon gap and confirm the accuracy of the magnon dispersion derived earlier through an 1/n expansion. We are thus able to examine the validity of a number of previous calculations and further analyze a wide range of experiments on CsNiF_3 concerning the magnon dispersion, magnetization, susceptibility, and specific heat. Although it is not possible to account for all data with a single set of parameters, the overall qualitative agreement is good and the remaining discrepancies may reflect departure from ideal quasi-one-dimensional model behavior. Finally, we present some indirect evidence to the effect that the popular interpretation of the excess specific heat in terms of sine-Gordon solitons may not be appropriate.Comment: 9 pages 10 figure

Spinons, Solitons and Magnons in One-dimensional Heisenberg-Ising Antiferromagnets

We calculate the excitation spectra for the one-$d$ Heisenberg-Ising antiferromagnets by expansions around the Ising limit. For $S=1/2$, the calculated expansion coefficients for the spinon-spectra agree term by term with the solution of Johnson and McCoy. For $S=1$, the solitons become gapless before the Heisenberg limit is reached, signalling a transition to the Haldane phase. By applying a staggered field we calculate the one-magnon spectra for the $S=1$ Heisenberg chain. For $S=3/2$ the quantum renormalization of the spin-wave spectra is calculated to be approximately $1.16$.Comment: 4 pages, RevTex, 3 postscript figures, Latex file and figures have been uuencode