22 research outputs found

    Synthesis and Thermal, Photophysical, Electrochemical Properties of 3,3-di[3-Arylcarbazol-9-ylmethyl]oxetane Derivatives

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    Novel oxetane-functionalized derivatives were synthesized to find the impact of carbazole substituents, such as 1-naphtyl, 9-ethylcarbazole and 4-(diphenylamino)phenyl, on their thermal, photophysical and electrochemical properties. Additionally, to obtain the optimized ground-state geometry and distribution of the frontier molecular orbital energy levels, density functional theory (DFT) calculations were used. Thermal investigations showed that the obtained compounds are highly thermally stable up to 360 C, as molecular glasses with glass transition temperatures in the range of 142–165 C. UV–Vis and photoluminescence studies were performed in solvents of differing in polarity, in the solid state as a thin film on glass substrate, and in powders, and were supported by DFT calculations. They emitted radiation both in solution and in film with photoluminescence quantum yield from 4% to 87%. Cyclic voltammetry measurements revealed that the materials undergo an oxidation process. Next, the synthesized molecules were tested as hole transporting materials (HTM) in perovskite solar cells with the structure FTO/b-TiO2/m-TiO2/perovskite/HTM/Au, and photovoltaic parameters were compared with the reference device without the oxetane derivatives

    Well Defined Carbazol-3,9-Diyl Based Oligomers as Host Materials for Organic Electro-Phosphorescent Devices

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    P. Jules Fouquet, Réduction à l'absurde de tout apriorisme philosophique, Menton, Palmers. In: Revue internationale de l'enseignement, tome 37, Janvier-Juin 1899. pp. 92-93

    A Review of Benzophenone-Based Derivatives for Organic Light-Emitting Diodes

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    Organic light-emitting diodes (OLEDs) have garnered considerable attention in academic and industrial circles due to their potential applications in flat-panel displays and solid-state lighting technologies, leveraging the advantages offered by organic electroactive derivatives over their inorganic counterparts. The thin and flexible design of OLEDs enables the development of innovative lighting solutions, facilitating the creation of customizable and contoured lighting panels. Among the diverse electroactive components employed in the molecular design of OLED materials, the benzophenone core has attracted much attention as a fragment for the synthesis of organic semiconductors. On the other hand, benzophenone also functions as a classical phosphor with high intersystem crossing efficiency. This characteristic makes it a compelling candidate for effective reverse intersystem crossing, with potential in leading to the development of thermally activated delayed fluorescent (TADF) emitters. These emitting materials witnessed a pronounced interest in recent years due to their incorporation in metal-free electroactive frameworks and the capability to convert triplet excitons into emissive singlet excitons through reverse intersystem crossing (RISC), consequently achieving exceptionally high external quantum efficiencies (EQEs). This review article comprehensively overviews the synthetic pathways, thermal characteristics, electrochemical behaviour, and photophysical properties of derivatives based on benzophenone. Furthermore, we explore their applications in OLED devices, both as host materials and emitters, shedding light on the promising opportunities that benzophenone-based compounds present in advancing OLED technology

    2,7(3,6)-Diaryl(arylamino)-substituted Carbazoles as Components of OLEDs: A Review of the Last Decade

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    Organic light emitting diode (OLED) is a new, promising technology in the field of lighting and display applications due to the advantages offered by its organic electroactive derivatives over inorganic materials. OLEDs have prompted a great deal of investigations within academia as well as in industry because of their potential applications. The electroactive layers of OLEDs can be fabricated from low molecular weight derivatives by vapor deposition or from polymers by spin coating from their solution. Among the low-molar-mass compounds under investigation in this field, carbazole-based materials have been studied at length for their useful chemical and electronic characteristics. The carbazole is an electron-rich heterocyclic compound, whose structure can be easily modified by rather simple reactions in order to obtain 2,7(3,6)-diaryl(arylamino)-substituted carbazoles. The substituted derivatives are widely used for the formation of OLEDs due to their good charge carrier injection and transfer characteristics, electroluminescence, thermally activated delayed fluorescence, improved thermal and morphological stability as well as their thin film forming characteristics. On the other hand, relatively high triplet energies of some substituted carbazole-based compounds make them useful components as host materials even for wide bandgap triplet emitters. The present review focuses on 2,7(3,6)-diaryl(arylamino)-substituted carbazoles, which were described in the last decade and were applied as charge-transporting layers, fluorescent and phosphorescent emitters as well as host materials for OLED devices

    New Electroactive Polymers with Electronically Isolated 4,7-Diarylfluorene Chromophores as Positive Charge Transporting Layer Materials for OLEDs

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    The OLED materials were developed in the frame of project funded by the Research Council of Lithuania (grant No. S-LLT-19-2). B.Z. is thankful to the National Natural Science Foundation of China (No. 51773195), and the Research & Development Projects in Key Areas of Guangdong Province, China (No. 2019B010933001). We are also obliged to D. Volyniuk for measurements of the ionization potentials.A group of polyethers containing electroactive pendent 4,7-diarylfluorene chromophores have been prepared by the multi-step synthetic route. Full characterization of their structures has been presented. The polymeric materials represent derivatives of high thermal stability with initial thermal degradation temperatures in a range of 392–397 °C. Glass transition temperatures of the amorphous polymers range from 28 °C to 63 °C and depend on structures of the 4,7-diarylfluorene chromophores. Electron photoemission spectra of thin layers of the electroactive derivatives showed ionization potentials in the range of 5.8–6.0 eV. Hole injecting/transporting properties of the prepared polymeric materials were confirmed during formation of organic light-emitting diodes with tris(quinolin-8-olato)aluminium (Alq3) as a green emitter, which also serves as an electron transporting layer. The device using hole-transporting polymer with electronically isolated 2,7-di(4-biphenyl) fluorene chromophores demonstrated the best overall performance with low turn on voltage of 3 V, high current efficiency exceeding 1.7 cd/A, and with maximum brightness over 200 cd/m2. The organic light-emitting diode (OLED) characteristics were measured in non-optimized test devices. The efficiencies could be further improved by an optimization of device structure, formation conditions, and encapsulation of the devices..---//---This work is licensed under a CC BY 4.0 license.Research Council of Lithuania (grant No. S-LLT-19-2); National Natural Science Foundation of China (No. 51773195); Research & Development Projects in Key Areas of Guangdong Province, China (No. 2019B010933001); Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART

    Chemoselective Assembly and Immunological Evaluation of Multiepitopic Glycoconjugates Bearing Clustered Tn Antigen as Synthetic Anticancer Vaccines

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    International audienceIn this paper we investigated the use of regioselectively addressable functionalized templates (RAFTs) as new scaffolds for the design of anticancer vaccine candidates. We report the synthesis of well-defined multiepitopic RAFT scaffolds and their immunological evaluation. These conjugates exhibit clustered Tn analogue as tumor-associated carbohydrate antigen (TACA, B-cell epitope) and the CD4+ helper T-cell peptide from the type 1 poliovirus. The saccharidic and peptidic epitopes were both synthesized separately and combined regioselectively to the RAFT core using a sequential oxime bond formation strategy. B- and T-antigenicity and immunogenicity of the vaccine candidates were investigated in vitro and in vivo. These studies clearly demonstrate that the saccharidic part of the conjugates is recognized by Tn-specific monoclonal antibodies. Moreover, the antibodies elicited by immunization of mice with our vaccine candidates recognize the native form of Tn epitope expressed on human tumor cells. Together with oxime ligation technique, these results suggest that the RAFT scaffold provides a promising and suitable tool for engineering potent synthetic anticancer vaccine
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