DC magnetic field generation in unmagnetized shear flows

The generation of DC magnetic fields in unmagnetized plasmas with velocity shear is predicted for non relativistic and relativistic scenarios either due to thermal effects or due to the onset of the Kelvin-Helmholtz instability (KHI). A kinetic model describes the growth and the saturation of the DC field. The predictions of the theory are confirmed by multidimensional particle-in-cell simulations, demonstrating the formation of long lived magnetic fields ($t \sim 100s \omega_{pi}^{-1}$) along the full longitudinal extent of the shear layer, with transverse width on the electron length scale ($\sqrt{\gamma_0}c/\omega_{pe}$), reaching magnitudes $eB_{\mathrm{DC}}/m_ec\omega_{pe}\sim \beta_0\sqrt{\gamma_0}$

Liquid mixtures involving fluorinated alcohols: The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol) Experimental and Simulation

Liquid mixtures involving fluorinated alcohols: The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol) Experimental and Simulation Pedro Duartea, Djêide Rodriguesa, Marcelo Silvaa, Pedro Morgadoa, Luís Martinsa,b and Eduardo J. M. Filipea* aCentro de Química Estrutural, Instituto Superior Técnico, 1049-001 Lisboa, Portugal bCentro de Química de Évora, Universidade de Évora, 7000-671 Évora, Portugal Fluorinated alcohols are substances with unique properties and high technological value in the pharmaceutical and chemical industries. Trifluoroethanol (TFE), in particular, displays a number of unusual properties as a solvent. For example, it dissolves nylon at room temperature and is effectively used as solvent in bioengineering. The presence of the three fluorines atoms gives the alcohol a high ionization constant, strong hydrogen bonding capability and stability at high temperatures. In the pharmaceutical industry, TFE finds use as the major raw material for the production of inhalation anesthetics. Mixtures of TFE and water (known as Fluorinols®) are used as working fluids for Rankine cycle heat engines for terrestrial and space applications, as a result of a unique combination of physical and thermodynamic properties such as high thermal efficiency and excellent turbine expansion characteristics. Environmentally, TFE is a CFC substitute with an acceptable short lifetime and with small ozone depletion potential. Additionally, TFE is known to induce conformational changes in proteins and it is used as a co-solvent to analyze structural features of partially folded states. The (ethanol + TFE) system displays an interesting and peculiar behaviour, combining a negative azeotrope with high positive excess volumes. In this work, liquid mixtures of (ethanol + TFE) were investigated. The densities of the mixtures were measured as a function of composition between 278K and 338K and at pressures up to 700 bar. The corresponding excess volumes as a function of temperature and pressure, the isothermal compressibilities and thermal expansivities were calculated from the experimental results. The mixtures are highly non-ideal with excess volumes ranging from 0.8 - 1.0 cm3mol-1. Finally, molecular dynamic simulations were performed to model and interpret the experimental results. The Trappe force field was used to simulate the (TFE + ethanol) mixtures and calculate the corresponding excess volumes. The simulation results are able to reproduce the correct sign and order of magnitude of the experimental VE without fitting to the experimental data. Furthermore, the simulations suggest the presence of a particular type of hydrogen bridge between ethanol and TFE, that can help to rationalize the experimental results

Electron-scale shear instabilities: magnetic field generation and particle acceleration in astrophysical jets

Strong shear flow regions found in astrophysical jets are shown to be important dissipation regions, where the shear flow kinetic energy is converted into electric and magnetic field energy via shear instabilities. The emergence of these self-consistent fields make shear flows significant sites for radiation emission and particle acceleration. We focus on electron-scale instabilities, namely the collisionless, unmagnetized Kelvin-Helmholtz instability (KHI) and a large-scale dc magnetic field generation mechanism on the electron scales. We show that these processes are important candidates to generate magnetic fields in the presence of strong velocity shears, which may naturally originate in energetic matter outburst of active galactic nuclei and gamma-ray bursters. We show that the KHI is robust to density jumps between shearing flows, thus operating in various scenarios with different density contrasts. Multidimensional particle-in-cell (PIC) simulations of the KHI, performed with OSIRIS, reveal the emergence of a strong and large-scale dc magnetic field component, which is not captured by the standard linear fluid theory. This dc component arises from kinetic effects associated with the thermal expansion of electrons of one flow into the other across the shear layer, whilst ions remain unperturbed due to their inertia. The electron expansion forms dc current sheets, which induce a dc magnetic field. Our results indicate that most of the electromagnetic energy developed in the KHI is stored in the dc component, reaching values of equipartition on the order of $10^{-3}$ in the electron time-scale, and persists longer than the proton time-scale. Particle scattering/acceleration in the self generated fields of these shear flow instabilities is also analyzed

Transverse electron-scale instability in relativistic shear flows

Electron-scale surface waves are shown to be unstable in the transverse plane of a shear flow in an initially unmagnetized plasma, unlike in the (magneto)hydrodynamics case. It is found that these unstable modes have a higher growth rate than the closely related electron-scale Kelvin-Helmholtz instability in relativistic shears. Multidimensional particle-in-cell simulations verify the analytic results and further reveal the emergence of mushroom-like electron density structures in the nonlinear phase of the instability, similar to those observed in the Rayleigh Taylor instability despite the great disparity in scales and different underlying physics. Macroscopic ($\gg c/\omega_{pe}$) fields are shown to be generated by these microscopic shear instabilities, which are relevant for particle acceleration, radiation emission and to seed MHD processes at long time-scales

Slow down of a globally neutral relativistic e−e+e^-e^+ beam shearing the vacuum

The microphysics of relativistic collisionless sheared flows is investigated in a configuration consisting of a globally neutral, relativistic $e^-e^+$ beam streaming through a hollow plasma/dielectric channel. We show through multidimensional PIC simulations that this scenario excites the Mushroom instability (MI), a transverse shear instability on the electron-scale, when there is no overlap (no contact) between the $e^-e^+$ beam and the walls of the hollow plasma channel. The onset of the MI leads to the conversion of the beam's kinetic energy into magnetic (and electric) field energy, effectively slowing down a globally neutral body in the absence of contact. The collisionless shear physics explored in this configuration may operate in astrophysical environments, particularly in highly relativistic and supersonic settings where macroscopic shear processes are stable

Structural and chemical characterization of silica spheres before and after modification by silanization for trypsin immobilization.

In the last decades, silica particles of a variety of sizes and shapes have been characterized and chemically modified for several applications, from chromatographic separation to dental supplies. The present study proposes the use of aminopropyl triethoxysilane (APTS) silanized silica particles to immobilize the proteolytic enzyme trypsin for the development of a bioreactor. The major advantage of the process is that it enables the polypeptides hydrolysis interruption simply by removing the silica particles from the reaction bottle. Silanized silica surfaces showed significant morphological changes at micro- and nanoscale level. Chemical characterization showed changes in elemental composition, chemical environment, and thermal degradation. Their application as supports for trypsin immobilization showed high immobilization efficiency at reduced immobilization times, combined with more acidic conditions. Indirect immobilization quantification by reversed-phase ultrafast high performance liquid chromatography proved to be a suitable approach due to its high linearity and sensitivity. Immobilized trypsin activities on nonmodified and silanized silica showed promising features (e.g., selective hydrolysis) for applications in proteins/peptides primary structure elucidation for proteomics. Silanized silica system produced some preferential targeting peptides, probably due to the hydrophobicity of the nanoenvironment conditioned by silanization