Tribochemistry of graphene on iron and its possible role in lubrication of steel

Recent tribological experiments revealed that graphene is able to lubricate macroscale steel-on-steel sliding contacts very effectively both in dry and humid conditions. This effect has been attributed to a mechanical action of graphene related to its load-carrying capacity. Here we provide further insight into the functionality of graphene as lubricant by analysing its tribochemical action. By means of first principles calculations we show that graphene binds strongly to native iron surfaces highly reducing their surface energy. Thanks to a passivating effect, the metal surfaces coated by graphene become almost inert and present very low adhesion and shear strength when mated in a sliding contact. We generalize the result by establishing a connection between the tribological and the electronic properties of interfaces, which is relevant to understand the fundamental nature of frictional forces.Comment: 19 pages, 6 figure

Insigths into the tribochemistry of silicon-doped carbon based films by ab initio analysis of water/surface interactions

Diamond and diamond-like carbon (DLC) are used as coating materials for numerous applications, ranging from biomedicine to tribology. Recently, it has been shown that the hydrophilicity of the carbon films can be enhanced by silicon doping, which highly improves their biocompatibility and frictional performances. Despite the relevance of these properties for applications, a microscopic understanding on the effects of silicon is still lacking. Here we apply ab initio calculations to study the interaction of water molecules with Si-incorporated C(001) surfaces. We find that the presence of Si dopants considerably increases the energy gain for water chemisorption and decreases the energy barrier for water dissociation by more than 50%. We provide a physical rational for the phenomenon by analysing the electronic charge displacements occuring upon adsorption. We also show that once hydroxylated, the surface is able to bind further water molecules much strongly than the clean surface via hydrogen-bond networks. This two-step process is consistent with and can explain the enhanced hydrophilic character observed in carbon-based films doped by silicon

A multiwavelength view of BL Lacs neutrino candidates

The discovery of high-energy astrophysical neutrinos by IceCube kicked off a new line of research to identify the electromagnetic counterparts producing these neutrinos. Among the extragalactic sources, active galactic nuclei (AGN), and in particular Blazars, are promising candidate neutrino emitters. Their structure, with a relativistic jet pointing to the Earth, offers a natural accelerator of particles and for this reason a perfect birthplace of high energy neutrinos. A good characterisation of the spectral energy distribution (SED) of these sources can improve the understanding of the physical composition of the source and the emission processes involved. Starting from our previous works in which we assumed a correlation between the $\gamma$-ray and the neutrino flux of the BL Lacs of the 2FHL catalogue (detected by Fermi above 50GeV), we select those BL Lac in spatial correlation with the IceCube events. We obtain a sample of 7 sources and we start an observational campaign to have a better characterisation of the synchrotron peak. During the analysis of the data a new source has been added because of its position inside the angular uncertainty of a muon track event detected by IceCube. This source, namely TXS0506+056, was in a high-state during the neutrino event and we will consider it as benchmark to check the proprieties of the other sources of the sample during the related neutrino detection. We obtain a better characterisation of the SED for the sources of our sample. A prospective extreme Blazar, a very peculiar low synchrotron peak (LSP) source with a large separation of the two peaks and a \textit{twin} of TXS0506+056 come up. We also provide the $\gamma$-ray light curve to check the trend of the sources around the neutrino detection but no clears patterns are in common among the sources.Comment: 10 pages, 4 figures, accepted to MNRA

Neutrino emission from BL Lac objects: the role of radiatively inefficient accretion flows

The origin of the astrophysical high-energy neutrinos discovered by IceCube is currently a major mystery. The recent detection of IceCube-170922A, a $\sim$300 TeV neutrino potentially correlated with the flaring $\gamma$-ray source TXS 0506+056, directs attention toward BL Lac objects (BL Lacs), the subclass of blazars with weak emission lines. While high-energy neutrinos can be produced via photohadronic interactions between protons accelerated in their jets and ambient low-energy photons, the density of the latter in such objects had generally been thought to be too low for efficient neutrino emission. Here we consider the role of radiatively inefficient accretion flows (RIAFs), which can plausibly exist in the nuclei of BL Lacs, as the source of target photons for neutrino production. Based on simple model prescriptions for the spectra of RIAFs at different accretion rates, we find that they can be sufficienly intense to allow appreciable neutrino emission for the class of low-synchrotron-peak BL Lacs such as TXS 0506+056. In constrast, for high-synchrotron-peak BL Lacs including Mkn 421 and Mkn 501, the contribution of RIAFs is subdominant and their neutrino production efficiency can remain low, consistent with their non-detection by IceCube to date.Comment: 5 pages, 4 figures, accepted to MNRAS as Lette

Extrasolar and Bl Lac observations at OARPAF

This paper reports the work done at the Osservatorio Astronomico Regionale Parco Antola comune di Fascia (OARPAF), as a part of my master thesis. The paper is divided in three parts: the first part describes the instrumentation at the OARPAF; the second part shows the characterization of the instrumentation, from the pointing model of the telescope to the conception and the realization of the software for data analysis; the third part illustrates the results of the photometric calibration

High-energy neutrinos from FR0 radio-galaxies?

The sources responsible for the emission of high-energy ($\gtrsim$ 100 TeV) neutrinos detected by IceCube are still unknown. Among the possible candidates, active galactic nuclei with relativistic jets are often examined, since the outflowing plasma seems to offer the ideal environment to accelerate the required parent high-energy cosmic rays. The non-detection of single point sources or -- almost equivalently -- the absence, in the IceCube events, of multiplets originating from the same sky position, constrains the cosmic density and the neutrino output of these sources, pointing to a numerous population of faint sources. Here we explore the possibility that FR0 radiogalaxies, the population of compact sources recently identified in large radio and optical surveys and representing the bulk of radio-loud AGN population, can represent suitable candidates for neutrino emission. Modeling the spectral energy distribution of a FR0 radiogalaxy recently associated to a $\gamma$-ray source detected by the Large Area Telescope onboard Fermi, we derive the physical parameters of its jet, in particular the power carried by it. We consider the possible mechanisms of neutrino production, concluding that $p\gamma$ reactions in the jet between protons and ambient radiation is too inefficient to sustain the required output. We propose an alternative scenario, in which protons, accelerated in the jet, escape from it and diffuse in the host galaxy, producing neutrinos as a result of $pp$ scattering with the interstellar gas, in strict analogy with the processes taking place in star-forming galaxies.Comment: 5 pages, 3 figures, accepted for publication in MNRA

Belladrilus (Santomesia) auka n. sp. (Oligochaeta, Ocnerodrilidae) from Argentina

From Cordoba Province, Argentina the Ocnerodrilidae Belladrilus (Santomesia) auka n. sp. is described by dissections and serial histological sections. The species is well characterised by the tumid T-shaped male porophore in XVll with an anterior half-moon depression and a posterior cross thickening. The seminal grooves are convergent and thin in the anterior half, straight and wider in the posterior half. Key words: Oligochaeta, Ocnerodrilidae, Cordoba, Argentina, Anatomy, Taxonomy.From Cordoba Province, Argentina the Ocnerodrilidae Belladrilus (Santomesia) auka n. sp. is described by dissections and serial histological sections. The species is well characterised by the tumid T-shaped male porophore in XVll with an anterior half-moon depression and a posterior cross thickening. The seminal grooves are convergent and thin in the anterior half, straight and wider in the posterior half. Key words: Oligochaeta, Ocnerodrilidae, Cordoba, Argentina, Anatomy, Taxonomy.From Cordoba Province, Argentina the Ocnerodrilidae Belladrilus (Santomesia) auka n. sp. is described by dissections and serial histological sections. The species is well characterised by the tumid T-shaped male porophore in XVll with an anterior half-moon depression and a posterior cross thickening. The seminal grooves are convergent and thin in the anterior half, straight and wider in the posterior half. Key words: Oligochaeta, Ocnerodrilidae, Cordoba, Argentina, Anatomy, Taxonomy

Ab Initio Calculation of the Adhesion and Ideal Shear Strength of Planar Diamond Interfaces with Different Atomic Structure and Hydrogen Coverage

n/

Ab initio insights into the interaction mechanisms between H2_2, H2_2O, and O2_2 molecules with diamond surfaces

Diamond displays outstanding chemical, physical, and tribological properties, making it attractive for numerous applications ranging from biomedicine to tribology. However, the reaction of the materials with molecules present in the air, such as oxygen, hydrogen, and water, could significantly change the electronic and tribological properties of the films. In this study, we performed several density functional theory calculations to construct a database for the adsorption energies and dissociation barriers of these molecules on the most relevant diamond surfaces, including C(111), C(001), and C(110). The adsorption configurations, reaction paths, activation energies, and their influence on the structure of diamond surfaces are discussed. The results indicate that there is a strong correlation between adsorption energy and surface energy. Moreover, we found that the dissociation processes of oxygen molecules on these diamond surfaces can significantly alter the surface morphology and may affect the tribological properties of diamond films. These findings can help to advance the development and optimization of devices and antiwear coatings based on diamond