The [4+2]‐Cycloaddition of α‐Nitrosoalkenes with Thiochalcones as a Prototype of Periselective Hetero‐Diels–Alder Reactions—Experimental and Computational Studies

The [4+2]‐cycloadditions of α‐nitrosoalkenes with thiochalcones occur with high selectivity at the thioketone moiety of the dienophile providing styryl‐substituted 4H‐1,5,2‐oxathiazines in moderate to good yields. Of the eight conceivable hetero‐Diels–Alder adducts only this isomer was observed, thus a prototype of a highly periselective and regioselective cycloaddition has been identified. Analysis of crude product mixtures revealed that the α‐nitrosoalkene also adds competitively to the thioketone moiety of the thiochalcone dimer affording bis‐heterocyclic [4+2]‐cycloadducts. The experiments are supported by high‐level DFT calculations that were also extended to related hetero‐Diels–Alder reactions of other nitroso compounds and thioketones. These calculations reveal that the title cycloadditions are kinetically controlled processes confirming the role of thioketones as superdienophiles. The computational study was also applied to the experimentally studied thiochalcone dimerization, and showed that the 1,2‐dithiin and 2H‐thiopyran isomers are in equilibrium with the monomer. Again, the DFT calculations indicate kinetic control of this process

Assays with Commercially Produced Trichogramma (Hymenoptera: Trichogrammatidae) To Determine Suitability for Obliquebanded Leafroller (Lepidoptera: Tortricidae) Control

Laboratory assays were used to compare the ability of commercially produced Trichogramma spp. to parasitize eggs of the obliquebanded leafroller, Choristoneura rosaceana (Harris), in the laboratory and field. Trichogramma platneri Nagarkatti parasitized more obliquebanded leafroller eggs per egg mass than did Trichogramma pretiosum Riley or Trichogramma minutum Riley produced by either of 2 insectaries. T. minutum produced at 1 insectary caused significantly more host mortality by host feeding and repiercing than by parasitism. Variation in parasitoid performance from different insectaries and among shipments from the same insectary was common. Young egg masses were more heavily parasitized than old egg masses. Parasitism increased as the number of conspecific female Trichogramma spp. placed on the same host increased, but the number of eggs parasitized per female decreased. Exposure of host egg masses to female Trichogramma spp. prevented additional oviposition in the same egg mass by conspecific, ovipositionally experienced females but had no effect on parasitism by conspecific, ovipositionally naive females. The method used to attach sentinel egg masses to foliage influenced parasitism rates. Moistening the leaf with water and adhering the egg mass to the moistened leaf had the least impact. Inundative releases of Trichogramma spp. into an apple orchard paralleled laboratory assays by showing greater parasitism of obliquebanded leafroller egg masses by T. platneri than with T. minutum. However, extreme differences observed in field performance between the 2 species was not predicted from the assay

Perturbation theorems for Hele-Shaw flows and their applications

In this work, we give a perturbation theorem for strong polynomial solutions to the zero surface tension Hele-Shaw equation driven by injection or suction, so called the Polubarinova-Galin equation. This theorem enables us to explore properties of solutions with initial functions close to but are not polynomial. Applications of this theorem are given in the suction or injection case. In the former case, we show that if the initial domain is close to a disk, most of fluid will be sucked before the strong solution blows up. In the later case, we obtain precise large-time rescaling behaviors for large data to Hele-Shaw flows in terms of invariant Richardson complex moments. This rescaling behavior result generalizes a recent result regarding large-time rescaling behavior for small data in terms of moments. As a byproduct of a theorem in this paper, a short proof of existence and uniqueness of strong solutions to the Polubarinova-Galin equation is given.Comment: 25 page

Getting the User’s Attention

CAN WE DELIVER INFORMATION the way our users want it--cheap, fast, and good? According to Stewart Bodner, associate chief librarian of the New York Public Library, that\u27s what users desire and what librarians and vendors must provide. But at least in the public library world, convenience trumps quality every time, Bodner went on to tell the audience at the annual meeting of NFAIS (National Federation of Abstracting and Information Services) in Philadelphia this February. NFAIS brought together company representatives and librarians to brainstorm ways to redirect users away from Internet search engines and the open web and toward high-quality information

Laboratory and Field Studies of Resistance of Crab Apple Clones to Rhagoletis pomonella (Diptera: Tephritidae)

Oviposition and larval survival of Rhagoletis pomonella (Walsh) varied significantly among fruit from 25 crab apple speciesand clones evaluated in field and laboratory studies. In general, the relative oviposition preference and larval survival was similar in fruit infested naturally in the field and fruit tested in the laboratory. Flies oviposited more in clones with larger fruit, although this relationship was more pronounced in laboratory tests when fruit was infested by laboratory-reared flies than in fruit infested in the field by wild flies. ‘Aldenhamensis,' ‘Fuji,' ‘Vilmorin,' Malus zumi calocarpa Rehd., and M. hupehensis (Pamp) Rehd. fruit was not infested in the field, but flies oviposited in fruit of all 25 species and clones in choice tests in the laboratory. Eggs hatched but larvae did not survive in fruit of ‘Henry F. DuPont,' ‘Frettingham,' ‘Fuji,' ‘Sparkler,' M. hupehensis, and M. zumi calocarpa. Larval mortality was very high in fruit from ‘Vilmorin,' ‘Sparkler,' ‘NA 40298,' ‘Henrietta Crosby,' ‘Golden Gem,' ‘Almey,' M. baccata L. (Borkh.), and M. sikktmensis (Hook.) Koehn

Resurgence of \u3ci\u3eNilaparvata lugens\u3c/i\u3e (Stål) Populations as Influenced by Method and Timing of Insecticide Applications in Lowland Rice

Resurgence of Nilaparvata lugens (Stål) after insecticide application is a common phenomenon in rice in South and Southeast Asia. Among other insecticides inducing resurgence, carbofuran, decamethrin, and methyl parathion were selected for this study. Of the various methods of carbofuran application tested, foliar sprays were most active in inducing resurgence. Extent of resurgence was highly influenced by time of insecticide application. Sprays of methyl parathion and decamethrin applied 50 and 65 days after transplanting (DT) induced resurgence in the third generation of N. lugens at ca. 90 DT, whereas earlier applications had little effect. The cause(s) for resurgence was not definitely established, but stimulation of N. lugens reproduction appeared to be of more significance than destruction of natural enemies

Interference with the Mate-Finding Communication System of the Obliquebanded Leafroller (Lepidoptera: Tortricidae) Using Synthetic Sex Pheromones

Effect of atmospheric permeation with synthetic sex pheromone on the behavior and control of obliquebanded leafroller, Choristoneura rosaceana (Harris), was studied in small and large plots in commercial apple orchards. Synthetic sex pheromone significantly reduced the ability of male moths to locate pheromone-baited traps and tethered females; however, no differences were found among 3 pheromone rates. Location of pheromone dispensers within the tree canopy did not alter the number of males locating pheromone-baited traps and mating tethered females. Obliquebanded leafroller activity was greatest in the upper positions of the tree canopy and no edge effect was observed around perimeters of large disrupted blocks. The presence of gravid feral females, mated tethered females, high larval densities, and fruit damage within large pheromone disrupted blocks indicate obliqubanded leafrollers mate in orchards treated with synthetic sex pheromone. However, fruit damage caused by obliquebanded leafroller larvae was similar in pheromone, pheromone plus insecticide, and insecticide treatment

Development of an Electro-Optical Longitudinal Bunch Profile Monitor at KARA Towards a Beam Diagnostics Tool for FCC-ee

The Karlsruhe Research Accelerator (KARA) at KIT features an electro-optical (EO) near-field diagnostics setup to conduct turn-by-turn longitudinal bunch profile measurements in the storage ring using electro-optical spectral decoding (EOSD). Within the Future Circular Collider Innovation Study (FCCIS) an EO monitor using the same technique is being conceived to measure the longitudinal profile and center-of-charge of the bunches in the future electron-positron collider FCC-ee. This contribution provides an overview of the EO near-field diagnostics at KARA and discusses the development and its challenges towards an effective beam diagnostics concept for the FCC-ee

Thermo-elasticity for anisotropic media in higher dimensions

In this note we develop tools to study the Cauchy problem for the system of thermo-elasticity in higher dimensions. The theory is developed for general homogeneous anisotropic media under non-degeneracy conditions. For degenerate cases a method of treatment is sketched and for the cases of cubic media and hexagonal media detailed studies are provided.Comment: 33 pages, 5 figure

A moving boundary model motivated by electric breakdown: II. Initial value problem

An interfacial approximation of the streamer stage in the evolution of sparks and lightning can be formulated as a Laplacian growth model regularized by a 'kinetic undercooling' boundary condition. Using this model we study both the linearized and the full nonlinear evolution of small perturbations of a uniformly translating circle. Within the linear approximation analytical and numerical results show that perturbations are advected to the back of the circle, where they decay. An initially analytic interface stays analytic for all finite times, but singularities from outside the physical region approach the interface for $t\to\infty$, which results in some anomalous relaxation at the back of the circle. For the nonlinear evolution numerical results indicate that the circle is the asymptotic attractor for small perturbations, but larger perturbations may lead to branching. We also present results for more general initial shapes, which demonstrate that regularization by kinetic undercooling cannot guarantee smooth interfaces globally in time.Comment: 44 pages, 18 figures, paper submitted to Physica