Chiral skyrmions in thin magnetic films: new objects for magnetic storage technologies?

Axisymmetric magnetic lines of nanometer sizes (chiral vortices or skyrmions) have been predicted to exist in a large group of noncentrosymmetric crystals more than two decades ago. Recently these magnetic textures have been directly observed in nanolayers of cubic helimagnets and monolayers of magnetic metals. We develop a micromagnetic theory of chiral skyrmions in thin magnetic layers for magnetic materials with intrinsic and induced chirality. Such particle-like and stable micromagnetic objects can exist in broad ranges of applied magnetic fields including zero field. Chiral skyrmions can be used as a new type of highly mobile nanoscale data carriers

Disorder-driven electronic localization and phase separation in superconducting Fe1+yTe0.5Se0.5 single crystals

We have investigated the influence of Fe-excess on the electrical transport and magnetism of Fe1+yTe0.5Se0.5 (y=0.04 and 0.09) single crystals. Both compositions exhibit resistively determined superconducting transitions (Tc) with an onset temperature of about 15 K. From the width of the superconducting transition and the magnitude of the lower critical field Hc1, it is inferred that excess of Fe suppresses superconductivity. The linear and non-linear responses of the ac-susceptibility show that the superconducting state for these compositions is inhomogeneous. A possible origin of this phase separation is a magnetic coupling between Fe-excess occupying interstitial sites in the chalcogen planes and those in the Fe-square lattice. The temperature derivative of the resistivity drho/dT in the temperature range Tc < T < Ta with Ta being the temperature of a magnetic anomaly, changes from positive to negative with increasing Fe. A log 1/T divergence of the resistivity above Tc in the sample with higher amount of Fe suggests a disorder driven electronic localization.Comment: 7 page

Modulations in martensitic Heusler alloys originate from nanotwin ordering

Heusler alloys exhibiting magnetic and martensitic transitions enable applications like magnetocaloric refrigeration and actuation based on the magnetic shape memory effect. Their outstanding functional properties depend on low hysteresis losses and low actuation fields. These are only achieved if the atomic positions deviate from a tetragonal lattice by periodic displacements. The origin of the so-called modulated structures is the subject of much controversy: They are either explained by phonon softening or adaptive nanotwinning. Here we used large-scale density functional theory calculations on the Ni2MnGa prototype system to demonstrate interaction energy between twin boundaries. Minimizing the interaction energy resulted in the experimentally observed ordered modulations at the atomic scale, it explained that a/b twin boundaries are stacking faults at the mesoscale, and contributed to the macroscopic hysteresis losses. Furthermore, we found that phonon softening paves the transformation path towards the nanotwinned martensite state. This unified both opposing concepts to explain modulated martensite

Calcite incorporated in silica/collagen xerogels mediates calcium release and enhances osteoblast proliferation and differentiation

Multiphasic silica/collagen xerogels are biomaterials designed for bone regeneration. Biphasic silica/collagen xerogels (B30) and triphasic xerogels (B30H20 or B30CK20) additionally containing hydroxyapatite or calcite were demonstrated to exhibit several structural levels. On the first level, low fibrillar collagen serves as template for silica nanoparticle agglomerates. On second level, this silica-enriched matrix phase is fiber-reinforced by collagen fibrils. In case of hydroxyapatite incorporation in B30H20, resulting xerogels exhibit a hydroxyapatite-enriched phase consisting of hydroxyapatite particle agglomerates next to silica and low fibrillar collagen. Calcite in B30CK20 is incorporated as single non-agglomerated crystal into the silica/collagen matrix phase with embedded collagen fibrils. Both the structure of multiphasic xerogels and the manner of hydroxyapatite or calcite incorporation have an influence on the release of calcium from the xerogels. B30CK20 released a significantly higher amount of calcium into a calcium-free solution over a three-week period than B30H20. In calcium containing incubation media, all xerogels caused a decrease in calcium concentration as a result of their bioactivity, which was superimposed by the calcium release for B30CK20 and B30H20. Proliferation of human bone marrow stromal cells in direct contact to the materials was enhanced on B30CK20 compared to cells on both plain B30 and B30H20

Tree-ring analysis elucidating palaeo-environmental effects captured in an in situ fossil forest – The last 80 years within an early Permian ecosystem

© 2017 Elsevier B.V. The early Permian Chemnitz Fossil L agerstätte (Leukersdorf Formation, Chemnitz Basin, SE Germany) represents a diverse T 0 assemblage of a fossil forest ecosystem around the Sakmarian-Artinskian transition (290.6 ± 1.8 Ma), which was preserved by pyroclastic deposits of a multi-phased volcanic eruption. The multi-aged plant community consists of predominantly hygrophilous elements, which grew on an alluvial plain mineral substrate under sub-humid conditions, representing a wet spot environment. Strong seasonality triggered the formation of annual tree rings in arborescent woody plants, such as pycnoxylic gymnosperms, medullosan seed ferns and calamitaleans. From several hundred fossil trees, the 53 best-preserved specimens were selected and investigated in detail by measuring 2,081 tree rings in individual sequences of up to 77 rings. Ring sequences were analysed by standard dendrochronological methods to determine both annual growth rates and mean sensitivity. Morphological and statistical analyses on single tree rings reveal different tree-ring types according to the different plant groups. Pycnoxylic gymnosperms have distinct and regular tree rings, whereas medullosan seed ferns and calamitaleans show indistinct and regular tree rings as well as so called event rings. Results reveal differences between plant groups regarding their physiological reactions or adaptations to seasonal fluctuations. In comparison to pycnoxylic gymnosperms, both medullosan seed ferns and calamitaleans exhibit reduced growth rates and more sensitive reaction to environmental perturbances as water deficiency pointing to comparably lower adaptation to seasonally dry palaeoclimate. In this context, event rings are in many cases traced back to plant physiological stress during particularly severe drought periods. Altogether, these fossil trees serve as sensitive environmental archives, which shed light on growth conditions several decades back in time from the entombing eruption

Palaeoclimatic and site-specific conditions in the early Permian fossil forest of Chemnitz-Sedimentological, geochemical and palaeobotanical evidence

© 2015 Elsevier B.V. As significant indicators of deep-time palaeoclimate, a number of new palaeontological, pedological and geochemical characteristics are provided for the Chemnitz Fossil Lagerstätte to depict more precisely its environmental conditions. For the first time, several lines of evidence indicate that this fossil forest, instantaneously preserved by volcanic deposits, once received an annual precipitation of around 800-1100 mm, but grew on a nearly unweathered palaeosol. Although the composition of this rich and diverse T0 assemblage suggests a hygrophilous, dense and multi-aged vegetation dominated by conservative lineages, the habitat was affected by environmental disturbances and pronounced seasonality. Repeated changes in local moisture availability are suggested by geochemical proxies, the co-occurrence to intergrowth of calcic and ferric glaebules in the palaeosol and developmental traits of perennial vegetational elements. Specific substrate adaptation is reflected by different root systems and cyclic growth interruptions recorded in the stems, branches and roots of long-lived woody plants. Many differentially adapted terrestrial animals complete the more comprehensive reconstruction of a late Sakmarian ecosystem and its climatic and preservational controls. Albeit spatially confined, this diverse in-situ record may contribute to understand wetland-dryland dynamics of sub-tropical Northern Hemisphere Pangaea

Robust estimates of climate-induced hydrological change in a temperate mountainous region

A sustainable water resources management depends on sound information about the impacts of climate change. This information is, however, not easily derived because natural runoff variability interferes with the climate change signal. This study presents a procedure that leads to robust estimates of magnitude and Time Of Emergence (TOE) of climate-induced hydrological change that also account for the natural variability contained in the time series. Firstly, natural variability of 189 mesoscale catchments in Switzerland is sampled for 10 ENSEMBLES scenarios for the control (1984-2005) and two scenario periods (near future: 2025-2046, far future: 2074-2095) applying a bootstrap procedure. Then, the sampling distributions of mean monthly runoff are tested for significant differences with the Wilcoxon-Mann-Whitney test and for effect size with Cliff's delta d. Finally, the TOE of a climate change induced hydrological change is determined when at least eight out of the ten hydrological projections significantly differ from natural variability. The results show that the TOE occurs in the near future period except for high-elevated catchments in late summer. The significant hydrological projections in the near future correspond, however, to only minor runoff changes. In the far future, hydrological change is statistically significant and runoff changes are substantial. Temperature change is the most important factor determining hydrological change in this mountainous region. Therefore, hydrological change depends strongly on a catchment's mean elevation. Considering that the hydrological changes are predicted to be robust in the near future highlights the importance of accounting for these changes in water resources planning

Stochastic B-series analysis of iterated Taylor methods

For stochastic implicit Taylor methods that use an iterative scheme to compute their numerical solution, stochastic B--series and corresponding growth functions are constructed. From these, convergence results based on the order of the underlying Taylor method, the choice of the iteration method, the predictor and the number of iterations, for It\^o and Stratonovich SDEs, and for weak as well as strong convergence are derived. As special case, also the application of Taylor methods to ODEs is considered. The theory is supported by numerical experiments

Permian scorpions from the Petrified Forest of Chemnitz, Germany

© 2016 Dunlop et al.Background: Paleozoic scorpions (Arachnida: Scorpiones) have been widely documented from the Carboniferous Period; which hosts a remarkable assemblage of more than sixty species including both putative stem- and crown-group fossils. By contrast the succeeding Permian Period is almost completely devoid of records, which are currently restricted to a trace fossil from the early Permian of New Mexico, USA and some limb fragments from the late Permian of the Vologda Region, Russia. Results: ?Opsieobuthus tungeri sp. nov. from the Petrified Forest of Chemnitz, Germany represents the first complete body fossils of scorpions from the Permian. Explosive volcanism preserved these remarkable specimens in situ as part of the palaeosol horizon and bedrock of the Petrified Forest, immediately beneath the Zeisigwald tuff horizon. This dates to the early Permian (Sakmarian) or ca. 291 Ma. Intriguingly, the specimens were obtained from a palaeosol horizon with a compacted network of different-sized woody roots and thus have been preserved in situ in their likely life position, even within their original burrows. Differences in the structure of the comb-like pectines in the two fossils offer evidence for sexual dimorphism, and permit further inferences about the ecology and perhaps even the reproductive biology of these animals. Conclusions: As putative members of a Coal Measures genus, these fossils suggest that at least some Carboniferous scorpion lineages extended their range further into the Permian. This contributes towards a picture of scorpion evolution in which both basal and derived (orthostern) forms coexisted for quite some time; probably from the end of the Carboniferous through to at least the mid Triassic