K-Total Product Cordial Labelling of Graphs

In this paper we introduce the k-Total Product cordial labelling of graphs. Also we investigate the 3-Total Product cordial labelling behaviour of some standard graphs

Feasibility of store-and-forward teledermatology in out-patient care: A prospective study from rural India utilising specialist referral services through an instant messaging platform - "WhatsApp"

Objectives: The COVID-19 pandemic has placed unprecedented demands on the delivery of health care in rural areas of India. We examined the feasibility of store-and-forward mobile teledermatology for outpatient access to specialist dermatologic care in underserved areas in India. Methods: We conducted a prospective study using smartphone-based teledermatology, connecting six underserved clinics manned by primary care physicians (PCP) to three dermatologists, using the instant messaging platform WhatsApp. We assessed the concordance between PCPs and dermatologists (using prevalence adjusted bias adjusted kappa), consultation time, the spectrum of conditions, and the outcome. Results: Of the 730 dermatology patients screened in the clinics, 95 (13%) (36 males and 59 females) required teleconsultation, among which 61.1% were non-infective, 34.7% were infective, and the diagnosis could not be ascertained in 4.2 %. The mean time taken for the first response was 13.5\ub118.4 minutes. Twenty per cent (n=19) required referral, and 80% (n=76) of consultations could be resolved at the clinic, of whom 36.8 % were cured, 38.2% had moderate, 4% had minimal improvement, 13% were lost to follow-up, and 8% refused treatment. Cure was observed in viral infections and eczema. The diagnostic concordance ranged from low values [0.38 (95% CI: 0-0.68)] in infective to moderate [0.66 (95% CI: 0.42 -0.83), p=0.033] in non-infective disorders. Conclusion: Asynchronous mobile teledermatology, using specialist referral via instant messaging platforms, is a powerful modality for providing real-time dermatologic care, while offering a very promising alternative for decreasing healthcare disparities and continuity of services even in adverse situations like the Covid-19 pandemic

A review on microalgae as potential lipid container with wastewater treating functions

Abstract Microalgae are reported as potential source to produce lipids from their biomass cells. Lipid as a group of organic compound is a primary raw material used in biofuel production as well as component for foods, cosmetic products, fertilizers and animal feed. As the resources of manufacturing lipid from synthetic media are costly, the derivation of inexpensive carbon and nutritional sources from wastewater such as palm oil mill effluent (POME) is useful in massive scale. Furthermore, unique characteristic of microalgae as alternative agents to treat POME wastewater is another encouraging aspect of its application. In addition, biodiesel production from algae can produce 5,000 -15,000 gallons of biodiesel per acre/year. However, high yield production of high-lipid-content-algae biomass, determination of effective techniques in order to harvest grown algae, algal oil extraction and trans-esterification of extracted oil for converting into biodiesel are challenging issues need deep investigation. This review is focused on previous studies on POME as possible carbon and nutritional source used to treat environmental pollution caused by POME discharges and to increase the growth rate of microalgae in order to high-lipid content production

Determination of critical environmental, social, infrastructure, and economic indicators as evaluation checklist for pre-project abandonment plan assessment in-line with sustainable development goal plan

The increasing number of project abandonment because of the Novel Coronavirus pandemic 2019 (Covid-19) calls for better management of abandonment projects. The outbreak of Covid-19 has affected the environment, economy, and society aspects globally. In a developed country like Malaysia, the requirement to submit an abandonment plan is stipulated under the Environmental Guidelines in Malaysia (EGIM) 2016. Therefore, this study aimed to develop a Sustainable Pre-Project Abandonment Plan Assessment Checklist in Malaysia that is in line with the Sustainable Development Goal (SDG) 2030 aspirations. This new Sustainable Pre-Project Abandonment Plan Assessment Checklist in Malaysia is comprehensively structured; is expected to minimise the negative impact of the abandonment process towards the environment, socio-economy, and efficient management of infrastructure; and complies with the related legislation in Malaysia. In this study, data was collected and analysed using NVivo12. It consisted of findings from documents reviewed such as legislations, journals, and books. From the NVivo12 analysis, the results showed 28 critical indicators for abandonment plan assessment and related legislation that synchronises with SDG 2030 is required to develop the Proposed Sustainable Pre-Project Abandonment Plan Assessment Checklist in Malaysia

Optimizing of near infrared region reflectance of mix-waste tile aggregate as coating material for cool pavement with surface temperature measurement

The heat generated from dark color asphalt, which is low in surface reflectance mainly contributes to the environmental problem called as urban heat island. Low reflectance at high energy wavelength of sunlight, such as visible light and infrared region will cause the pavement to have high surface temperature, due to high energy absorption from solar radiation. This paper presents the optimization result of cool pavement coating material based on selected tiles aggregate to achieve high near infrared region (NIR) reflectance. Three types of waste tiles were used in this study which are Full Body Porcelain (FBP), Monoporosa (MP) and Porcelain Glaze (PG). All the tiles were prepared in the form of aggregates. A linear model was formed as a function of mix tiles fraction and the analysis of ANOVA suggest that the linear term used for this model is significant. Diagnostics of the model was evaluated using box-cox plot, normal plot of residuals and optimized to predict the mix of the different type of tiles to produce the highest surface NIR reflectance value. The first solution suggests that 100% of MP tile can provide NIR reflectance of 0.53, whereas the second solution suggest that the combination of 50% FBP and 50% of MP tile aggregates could give NIR reflectance value of about 0.51. Experimental work on measuring surface temperature found that optimized samples, M1 and M2 with high NIR reflectance could significantly reduce surface temperature of asphalt pavement at range of 4.1 °C–9.6 °C. In conclusion, the results of optimization is reliable and this method able to provide significant information on optimizing mix of tiles material as to achieve high NIR reflectance value for coating materials of cool-pavement

Two-dimensional nanostructures based '-onics' and '-omics' in personalized medicine

With the maturing techniques for advanced synthesis and engineering of two-dimensional (2D) materials, its nanocomposites, hybrid nanostructures, alloys, and heterostructures, researchers have been able to create materials with improved as well as novel functionalities. One of the major applications that have been taking advantage of these materials with unique properties is biomedical devices, which currently prefer to be decentralized and highly personalized with good precision. The unique properties of these materials, such as high surface to volume ratio, a large number of active sites, tunable bandgap, nonlinear optical properties, and high carrier mobility is a boon to 'onics' (photonics/electronics) and 'omics' (genomics/exposomics) technologies for developing personalized, low-cost, feasible, decentralized, and highly accurate medical devices. This review aims to unfold the developments in point-of-care technology, the application of 'onics' and 'omics' in point-of-care medicine, and the part of two-dimensional materials. We have discussed the prospects of photonic devices based on 2D materials in personalized medicine and briefly discussed electronic devices for the same. © 2022 the author(s), published by De Gruyter, Berlin/Boston.Instrumental Analysis Centre of Shenzhen UniversityMacao Special Administration RegionShenzhenKQTD2015032416270385, (JCYJ20150625103619275, JCYJ20170811093453105)Songshan Lake Materials LaboratoryNational Natural Science Foundation of China, NSFC, (61435010, 6181101252, 61875138)Science and Technology Development Fund, STDF, (007/2017/A1, 132/2017/A3)Department of Education of Guangdong Province, DEGP, (2018KCXTD026)Science, Technology and Innovation Commission of Shenzhen MunicipalityThe authors extend sincere thanks to the funding and support from Aaivalayam, India. One of the authors Manavalan Rajesh Kumar convey his thanks to the contract no. 40/is2

Facile synthesis and defect optimization of 2D-layered MoS2 on TiO2 heterostructure for industrial effluent, wastewater treatments

Supplementary information is available for this paper at https://doi.org/10.1038/s41598-020-78268-4.Copyright © The Author(s) 2020. Current research is paying much attention to heterojunction nanostructures. Owing to its versatile characteristics such as stimulating morphology, affluent surface-oxygen-vacancies and chemical compositions for enhanced generation of reactive oxygen species. Herein, we report the hydrothermally synthesized TiO2@MoS2 heterojunction nanostructure for the effective production of photoinduced charge carriers to enhance the photocatalytic capability. XRD analysis illustrated the crystalline size of CTAB capped TiO2, MoS2@TiO2 and L-Cysteine capped MoS2@TiO2 as 12.6, 11.7 and 10.2 nm, respectively. The bandgap of the samples analyzed by UV–Visible spectroscopy are 3.57, 3.66 and 3.94 eV. PL spectra of anatase phase titania shows the peaks present at and above 400 nm are ascribed to the defects in the crystalline structure in the form of oxygen vacancies. HRTEM reveals the existence of hexagonal layered MoS2 formation on the spherical shaped TiO2 nanoparticles at the interface. X-ray photoelectron spectroscopy recommends the chemical interactions between MoS2 and TiO2, specifically, oxygen vacancies. In addition, the electrochemical impedance spectroscopy studies observed that L-MT sample performed low charge transfer resistance (336.7 Ω cm2) that promotes the migration of electrons and interfacial charge separation. The photocatalytic performance is evaluated by quantifying the rate of Congo red dye degradation under visible light irradiation, and the decomposition efficiency was found to be 97%. The electron trapping recombination and plausible photocatalytic mechanism are also explored, and the reported work could be an excellent complement for industrial wastewater treatment.MHRD-SPARC; UKIERI; DST-SERB; RUSA 2.0; COMPETE agency, PT2020; EU-EC/MSCA-COFUND-2015-FP Nano TRAIN for Growth II; INSPIRE Faculty Scheme; SERB-EMRhttps://doi.org/10.1038/s41598-020-78268-

Realization of Ti MOF/MoS2 Hybrid Nanostructure and Their Catalytic Activity Towards 4-Nitrophenol Reduction

The development of effective catalysts for catalytic reduction of the toxic 4-Nitrophenol (4-NP) into useful 4-Aminophenol (4-AP) has received wide interest. Herein, we report the synthesis of Titanium Metal–Organic Framework (Ti-MOF)/MoS2 hybrid nanostructure as potential catalyst for the reduction of 4-NP. Various characterization tools such as FESEM, TEM, XRD, and XPS have been used to conduct the morphological and structural analysis of the hybrid nano catalyst. The catalytic studies suggest that the as-prepared Ti-MOF, MoS2, and Ti-MOF/MoS2 hybrid nanostructures effectively catalyze the reduction of 4-NP to 4-AP in the presence of NaBH4. The rate constant (Kapp) of MOF/MoS2 hybrid nanostructure is found to be 1.208 min−1, which proves its higher catalytic performance in comparison with the pristine samples. Additionally, its preeminent reusability performance makes MOF/MoS2 hybrid nanostructure to be used as effective and practical catalyst. Through this work, the potential for the heterostructure's high catalytic activity is conversed and a possible reaction mechanism is proposed. Our findings confirm that the hybrid MOF@MoS2 nanoflakes have provided a promising interface for the hydrogenation procedure on the catalytic surface, thereby making it an excellent catalytic material to be further investigated. © 2022 The Authors.The authors greatly acknowledge the Photonics Research facility of Aaivalayam-DIRAC, Coimbatore, India for the funding and laboratory support. One of the authors (Manavalan Rajesh Kumar) thanks to the contract no. 40/is2