37 research outputs found
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In situ detection of cracks during laser powder bed fusion using acoustic emission monitoring
Despite rapid development of laser powder bed fusion (L-PBF) and its monitoring techniques, there is still a lack of in situ crack detection methods, among which acoustic emission (AE) is one of the most sensitive. To elaborate on this topic, in situ AE monitoring was applied to L-PBF manufacturing of a high-strength Al92Mn6Ce2 (at. %) alloy and combined with subsequent X-ray computed tomography. By using a structure borne high-frequency sensor, even a simple threshold-based monitoring was able to detect AE activity associated with cracking, which occurred not only during L-PBF itself, but also after the build job was completed, i.e. in the cooling phase. AE data analysis revealed that crack-related signals can easily be separated from the background noise (e.g. inert gas circulation pump) through their specific shape of a waveform, as well as their energy, skewness and kurtosis. Thus, AE was verified to be a promising method for L-PBF monitoring, enabling to detect formation of cracks regardless of their spatial and temporal occurrence
Challenges and prospects of automated disassembly of fuel cells for a circular economy
The hydrogen economy is driven by the growing share of renewable energy and electrification of the transportation sector. The essential components of a hydrogen economy are fuel cells and electrolysis systems. The scarcity of the resources to build these components and the negative environmental impact of their mining requires a circular economy. Concerning disassembly, economical, ergonomic, and safety reasons make a higher degree of automation necessary.
Our work outlines the challenges and prospects on automated disassembly of fuel cell stacks. This is carried out by summarizing the state-of-the-art approaches in disassembly and conducting manual non-/destructive disassembly experiments of end-of-life fuel cell stacks. Based on that, a chemical and mechanical analysis of the fuel cell components is performed. From this, an automation potential for the disassembly processes is derived and possible disassembly process routes are modeled. Moreover, recommendations are given regarding disassembly system requirements using a morphological box
Suitability of Eroded Particles from Die-Sink Electro Discharge Machining for Additive Manufacturing—Review, Characterization and Processing
In this bipartite study, waste products of die-sink electro discharge machining (die-sink EDM) are investigated. EDM is based on an erosive character of discharges leading to material removal and molten material congeals in the dielectric. The aim is to show a theoretical suitability of these particles for a further usage as a secondary, recycled material in additive manufacturing (AM). Due to the energy- and cost-intensive process of gas atomization for AM powders, there is a need for alternative concepts for particle generation. The first part deals with an intensive review of references from the literature regarding particle size and circularity using image analysis. Secondly, real waste streams were investigated after washing and cleaning processes for oil removal via laser diffraction, dynamic image analysis, SEM with energy dispersive X-ray spectroscopy (EDX) as well as optical emission spectroscopy (ICP OES), categorized within the literature and compared to commercial AM powders. In general, it could be shown that, in principle, recycled particles fulfill main requirements for an AM usage regarding size and shape. Reference powders show median particle sizes of 30 µm to 34 µm and circularities of 0.90 to 0.93, whereas eroded particles exhibit an x50 value of 27 µm and circularity of 0.90, too. However, chemical purity, mainly caused by carbon contamination (5.4 wt% in eroded powder compared to 0.4 wt% in reference powder), must be improved before printing via AM machines. Additionally, several separation techniques have to be applied to remove undesired elements (alumina)
Suitability of Eroded Particles from Die-Sink Electro Discharge Machining for Additive Manufacturing—Review, Characterization and Processing
In this bipartite study, waste products of die-sink electro discharge machining (die-sink EDM) are investigated. EDM is based on an erosive character of discharges leading to material removal and molten material congeals in the dielectric. The aim is to show a theoretical suitability of these particles for a further usage as a secondary, recycled material in additive manufacturing (AM). Due to the energy- and cost-intensive process of gas atomization for AM powders, there is a need for alternative concepts for particle generation. The first part deals with an intensive review of references from the literature regarding particle size and circularity using image analysis. Secondly, real waste streams were investigated after washing and cleaning processes for oil removal via laser diffraction, dynamic image analysis, SEM with energy dispersive X-ray spectroscopy (EDX) as well as optical emission spectroscopy (ICP OES), categorized within the literature and compared to commercial AM powders. In general, it could be shown that, in principle, recycled particles fulfill main requirements for an AM usage regarding size and shape. Reference powders show median particle sizes of 30 µm to 34 µm and circularities of 0.90 to 0.93, whereas eroded particles exhibit an x50 value of 27 µm and circularity of 0.90, too. However, chemical purity, mainly caused by carbon contamination (5.4 wt% in eroded powder compared to 0.4 wt% in reference powder), must be improved before printing via AM machines. Additionally, several separation techniques have to be applied to remove undesired elements (alumina)
Influence of the Cell Type on the Physical Processes of the Mechanical Recycling of Automotive Lithium-Ion Batteries
Lithium-Ion Battery (LIB) manufacturers produce different cell formats (prismatic, cylindrical, pouch, etc.) with different casing materials (steel or aluminium) and cell chemistries (e.g., NMC, NCA, LFP, etc.) for application in electric vehicles. By law, these cells have to be recycled after their lifetime. This study investigates the influence of different cell types on the outcome of a standardized mechanical recycling process consisting of crushing, sieving and air classification. The aim of the study is to find out whether different cell types can be processed together or whether the recovery and product quality can be improved by processing them separately. Pouch cells require low energy consumption for crushing compared to cylindrical and prismatic cells. Steel as a casing material increases the energy requirement during crushing compared to aluminium. The particle size distribution of several product fractions varies significantly between the different cell types. During air classification, the separator, anode, and cathode show a similar separation behaviour and can be processed with the same settings, whereas for the separation of the casing metals, different settling velocities need to be applied depending on the casing material
Influence of Pretreatment Strategy on the Crushing of Spent Lithium-Ion Batteries
The rising production of lithium-ion batteries (LIBs) due to the introduction of electric mobility as well as stationary energy storage devices demands an efficient and sustainable waste management scheme for legislative, economic and ecologic reasons. One crucial part of the recycling of end-of-life (EOL) LIBs is mechanical processes, which generate material fractions for the production of new batteries or further metallurgical refining. In the context of safe and efficient processing of electric vehicles’ LIBs, crushing is usually applied as a first process step to open at least the battery cell and liberate the cell components. However, the cell opening method used requires a specific pretreatment to overcome the LIB’s hazard potentials. Therefore, the dependence on pretreatment and crushing is investigated in this contribution. For this, the specific energy input for liberation is determined and compared for different recycling strategies with respect to dismantling depth and depollution temperatures. Furthermore, the respective crushing product is analyzed regarding granulometric properties, material composition, and liberation and decoating behaviour depending on the pretreatment and grid size of the crushing equipment. As a result, finer particles and components are generated with dried cells. Pyrolysis of cells as well as high dismantling depths do not allow to draw exact conclusions and predictions. Consequently, trends for a successful separation strategy of the subsequent classifying and sorting processes are revealed, and recommendations for the liberation of LIBs are derived