Gestural patterns: a new method of printed textile design using motion capture technology

The aim of this research is to develop a new method, Hybrid Printing System (HPS) to explore digital craft methods to create surface patterns for printed textile design. This novel method of creating ‘handcrafted’ prints is a result of the integration of two technologies such as motion-capture (MOCAP) and digital textile printing (DTP). The research towards such an innovation required a current, historical, contextual and experimental study of use of motion capture in Art &Design. The research contextualises the hand and its relationship to digital crafting methods in printed textile design, the digital medium and the process of audience participation in printed textile design to create a new conceptual framework balanced in practice and theory. The practical research then develops three new methods of motion capture such as, motion tracing, motion sensing and motion tracking to generate gestural motifs and gestural patterns. This thesis and the accompanying set of experimental work demonstrates that HPS culminates in developing new aesthetics through a new mode of creation in a new medium, which will impact the user, the designer and the product as a part of the cyclical process. HPS is an advancement of printed textile design, centred in active participation of its audience at the generative stage of design. This results in a shifting role of a designer and subverts the current model of printed textile design practice. HPS is a democratic design process where the participants design for themselves, have their own voice, which induces a sense of community, togetherness and harmony in the creative process

Itinerant and local-moment magnetism in EuCr2As2 single crystals

We report on the crystal structure, physical properties, and electronic structure calculations for the ternary pnictide compound EuCr2As2. X-ray diffraction studies confirmed that EuCr2As2 crystalizes in the ThCr2Si2-type tetragonal structure (space group I4/mmm). The Eu ions are in a stable divalent state in this compound. Eu moments in EuCr2As2 order magnetically below Tm = 21 K. A sharp increase in the magnetic susceptibility below Tm and the positive value of the paramagnetic Curie temperature obtained from the Curie-Weiss fit suggest dominant ferromagnetic interactions. The heat capacity exhibits a sharp {\lambda}-shape anomaly at Tm, confirming the bulk nature of the magnetic transition. The extracted magnetic entropy at the magnetic transition temperature is consistent with the theoretical value Rln(2S+1) for S = 7/2 of the Eu2+ ion. The temperature dependence of the electrical resistivity \r{ho}(T) shows metallic behavior along with an anomaly at 21 K. In addition, we observe a reasonably large negative magneto-resistance (~ -24%) at lower temperature. Electronic structure calculations for EuCr2As2 reveal a moderately high density of states of Cr-3d orbitals at the Fermi energy, indicating that the nonmagnetic state of Cr is unstable against magnetic order. Our density functional calculations for EuCr2As2 predict a G-type AFM order in the Cr sublattice. The electronic structure calculations suggest a weak interlayer coupling of the Eu moments.Comment: 9 pages, 7 figure

Shape Transition of Nanostructures created on Si(100) surfaces after MeV Implantation

We have studied the modification in the Surface morphology of the Si(100) surfaces after 1.5 MeV Sb implantation. Scanning Probe Microscopy has been utilized to investigate the ion implanted surfaces. We observe the formation of nano-sized defect features on the Si surfaces for various fluences. These nanostructures are elliptical in shape and inflate in sizefor higher fluences. Furthermore, these nanostructures undergo a shape transition from an elliptical shape to a circular-like at a high fluence. We will also discuss the modification in surface roughness as a function of Sb fluence.Comment: 9 pages, 4 figure

Valence Fluctuation in CeMo2Si2C

We report on the valence fluctuation of Ce in CeMo$_{2}$Si$_{2}$C as studied by means of magnetic susceptibility $\chi(T)$, specific heat $C(T)$, electrical resistivity $\rho(T)$ and x-ray absorption spectroscopy. Powder x-ray diffraction revealed that CeMo$_{2}$Si$_{2}$C crystallizes in CeCr$_{2}$Si$_{2}$C-type layered tetragonal crystal structure (space group \textit{P4/mmm}). The unit cell volume of CeMo$_{2}$Si$_{2}$C deviates from the expected lanthanide contraction, indicating non-trivalent state of Ce ions in this compound. The observed weak temperature dependence of the magnetic susceptibility and its low value indicate that Ce ions are in valence fluctuating state. The formal $L_{III}$ Ce valence in CeMo$_{2}$Si$_{2}$C $$ = 3.11 as determined from x-ray absorption spectroscopy measurement is well bellow the value $\simeq$ 3.4 in tetravalent Ce compound CeO$_{2}$. The temperature dependence of specific heat does not show any anomaly down to 1.8 K which rules out any magnetic ordering in the system. The Sommerfeld coefficient obtained from the specific heat data is $\gamma$ = 23.4 mJ/mol\,K$^{2}$. The electrical resistivity follows the $T{^2}$ behavior in the low temperature range below 35 K confirming a Fermi liquid behavior. Accordingly both the Kadowaki Wood ratio $A/\gamma^{2}$ and the Sommerfeld Wilson ratio $\chi(0)/\gamma$ are in the range expected for Fermi-liquid systems. In order to get some information on the electronic states, we calculated the band structure within the density functional theory, eventhough this approach is not able to treat 4f electrons accurately. The non-$f$ electron states crossing the Fermi level have mostly Mo 4d character. They provide the states with which the 4f sates are strongly hybridized, leading to the intermediate valent state.Comment: 18 pages, 10 figures Submitted to Journal of Alloys and Compound

Heavy fermion and Kondo lattice behavior in the itinerant ferromagnet CeCrGe3

Physical properties of polycrystalline CeCrGe$_{3}$ and LaCrGe$_{3}$ have been investigated by x-ray absorption spectroscopy, magnetic susceptibility $\chi(T)$, isothermal magnetization M(H), electrical resistivity $\rho(T)$, specific heat C($T$) and thermoelectric power S($T$) measurements. These compounds are found to crystallize in the hexagonal perovskite structure (space group \textit{P6$_{3}$/mmc}), as previously reported. The $\rho(T)$, $\chi(T)$ and C($T$) data confirm the bulk ferromagnetic ordering of itinerant Cr moments in LaCrGe$_{3}$ and CeCrGe$_{3}$ with $T_{C}$ = 90 K and 70 K respectively. In addition a weak anomaly is also observed near 3 K in the C($T$) data of CeCrGe$_{3}$. The T dependences of $\rho$ and finite values of Sommerfeld coefficient $\gamma$ obtained from the specific heat measurements confirm that both the compounds are of metallic character. Further, the $T$ dependence of $\rho$ of CeCrGe$_{3}$ reflects a Kondo lattice behavior. An enhanced $\gamma$ of 130 mJ/mol\,K$^{2}$ together with the Kondo lattice behavior inferred from the $\rho(T)$ establish CeCrGe$_{3}$ as a moderate heavy fermion compound with a quasi-particle mass renormalization factor of $\sim$ 45.Comment: 7 pages, 7 figures. Accepted by Journal of Physics: Condensed Matte

Valence fuctuation and magnetic ordering in EuNi2(P1-xGex)2 single crystals

Unusual phases and phase transitions are seen at the magnetic-nonmagnetic boundary in Ce, Eu and Yb-based compounds. EuNi$_2$P$_{2}$ is a very unusual valence fluctuating Eu system, because at low temperatures the Eu valence stays close to 2.5 instead of approaching an integer value. Eu valence and thus the magnetic property in this system can be tuned by Ge substitution in P site as EuNi$_2$Ge$_{2}$ is known to exhibit antiferromagnetc (AFM) ordering of divalent Eu moments with $T_N$ = 30 K. We have grown EuNi$_2$(P$_{1-x}$Ge$_x$)$_2$ (0.0 $\leq$ $x$ $\leq$ 0.5) single crystals and studied their magnetic, thermodynamic and transport properties. Increasing Ge doping to $x >$ 0.4 results in a well-defined AFM ordered state with $T_N$ = 12 K for $x$ = 0.5. Moreover, the reduced value of magnetic entropy for $x$ = 0.5 at $T_N$ suggests the presence of valance fluctuation/ Kondo effect in this compound. Interestingly, the specific heat exhibits an enhanced Sommerfeld coefficient upon Ge doping. Subsequently, electronic structure calculations lead to a non-integral valence in EuNi$_2$P$_{2}$ but a stable divalent Eu state in EuNi$_2$Ge$_{2}$ which is in good agreement with experimental results.Comment: 7 pages, 8 figure

Luminescent Metal Nanoclusters: Synthesis and Sensing Applications

In recent years, synthesis of metal nanoclusters and deep understanding of many fundamental properties of the nanoclusters have drawn considerable attention owing to their multimodal application in light harvesting, hydrogen production, optical sensor, drug delivery and cancer therapy. Intriguing molecular-like properties, such as HOMO–LUMO, d-sp or sp-sp transitions, quantized charging and strong luminescence are often observed in metal nanoclusters. The optical properties of metal nanoclusters can be tuned by changing the number of metal atoms, surface functionality and heteroatom doping. However, the fundamental studies on tuning of these parameters and their effect on the photophysical properties of the metal nanoclusters are still in the embryonic stage. In this context, current thesis describes the development of synthesis methods for highly luminescent metal nanoclusters and metal nanoclusters based functional materials, which can fabricate efficient nanomaterials to find out potential applications in optical sensing, light harvesting systems and other photo driven devices.Research was conducted under the supervision of Prof. Amitava Patra of the Materials Science division under SPS [School of Physical Sciences]Research was carried out under CSIR fellowshi