Energetics and kinetics of Li intercalation in irradiated graphene scaffolds

In the present study we investigate the irradiation-defects hybridized graphene scaffold as one potential building material for the anode of Li-ion batteries. Designating the Wigner V22 defect as a representative, we illustrate the interplay of Li atoms with the irradiation-defects in graphene scaffolds. We examine the adsorption energetics and diffusion kinetics of Li in the vicinity of a Wigner V22 defect using density functional theory calculations. The equilibrium Li adsorption sites at the defect are identified and shown to be energetically preferable to the adsorption sites on pristine (bilayer) graphene. Meanwhile the minimum energy paths and corresponding energy barriers for Li migration at the defect are determined and computed. We find that while the defect is shown to exhibit certain trapping effects on Li motions on the graphene surface, it appears to facilitate the interlayer Li diffusion and enhance the charge capacity within its vicinity because of the reduced interlayer spacing and characteristic symmetry associated with the defect. Our results provide critical assessment for the application of irradiated graphene scaffolds in Li-ion batteries.Comment: 23 pages, 5 figure

Strong and Confined Acids Enable a Catalytic Asymmetric Nazarov Cyclization of Simple Divinyl Ketones

We report a catalytic asymmetric Nazarov cyclization of simple, acylic, alkyl-substituted divinyl ketones using our recently disclosed strong and confined imidodiphosphorimidate Brønsted acids. The corresponding monocyclic cyclopentenones are formed in good yields and excellent regio-, diastereo-, and enantioselectivities. Further, the chemical utility of the obtained enantiopure cyclopentenones is demonstrated

Performance Analysis of a Dual-Hop Cooperative Relay Network with Co-Channel Interference

This paper analyzes the performance of a dual-hop amplify-and-forward (AF) cooperative relay network in the presence of direct link between the source and destination and multiple co-channel interferences (CCIs) at the relay. Specifically, we derive the new analytical expressions for the moment generating function (MGF) of the output signal-to-interference-plus-noise ratio (SINR) and the average symbol error rate (ASER) of the relay network. Computer simulations are given to confirm the validity of the analytical results and show the effects of direct link and interference on the considered AF relay network

Turbulence control by developing a spiral wave with a periodic signal injection in the complex Ginzburg-Landau equation

Turbulence control in the two-dimensional complex Ginzburg-Landau equation is investigated. A new approach is proposed for the control purpose. In the presence of a small spiral wave seed initiation, a fully developed turbulence can be completely annihilated by injecting a single periodic signal to a small fixed space area around the spiral wave tip. The control is achieved in a parameter region where the spiral wave of the uncontrolled system is absolutely unstable. The robustness, convenience and high control efficiency of this method is emphasized, and the mechanism underlying these practical advantages are intuitively understood.Comment: 12 pages, figures can be found in the following journa

Truth Discovery in Crowdsourced Detection of Spatial Events

ACKNOWLEDGMENTS This research is based upon work supported in part by the US ARL and UK Ministry of Defense under Agreement Number W911NF-06-3-0001, and by the NSF under award CNS-1213140. Any opinions, findings and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views or represent the official policies of the NSF, the US ARL, the US Government, the UK Ministry of Defense or the UK Government. The US and UK Governments are authorized to reproduce and distribute reprints for Government purposes notwithstanding any copyright notation hereon.Peer reviewedPostprin

Backaction of a charge detector on a double quantum dot

We develop a master equation approach to study the backaction of quantum point contact (QPC) on a double quantum dot (DQD) at zero bias voltage. We reveal why electrons can pass through the zero-bias DQD only when the bias voltage across the QPC exceeds a threshold value determined by the eigenstate energy difference of the DQD. This derived excitation condition agrees well with experiments on QPC-induced inelastic electron tunneling through a DQD [S. Gustavsson et al., Phys. Rev. Lett. 99, 206804(2007)]. Moreover, we propose a new scheme to generate a pure spin current by the QPC in the absence of a charge current.Comment: 6 pages, 4 figure

Cooling a nanomechanical resonator by a triple quantum dot

We propose an approach for achieving ground-state cooling of a nanomechanical resonator (NAMR) capacitively coupled to a triple quantum dot (TQD). This TQD is an electronic analog of a three-level atom in $\Lambda$ configuration which allows an electron to enter it via lower-energy states and to exit only from a higher-energy state. By tuning the degeneracy of the two lower-energy states in the TQD, an electron can be trapped in a dark state caused by destructive quantum interference between the two tunneling pathways to the higher-energy state. Therefore, ground-state cooling of an NAMR can be achieved when electrons absorb readily and repeatedly energy quanta from the NAMR for excitations.Comment: 6 pages, 3 figure