105 research outputs found
Evaluating and improving adaptive educational systems with learning curves
Personalised environments such as adaptive educational systems can be evaluated and compared using performance curves. Such summative studies are useful for determining whether or not new modifications enhance or degrade performance. Performance curves also have the potential to be utilised in formative studies that can shape adaptive model design at a much finer level of granularity. We describe the use of learning curves for evaluating personalised educational systems and outline some of the potential pitfalls and how they may be overcome. We then describe three studies in which we demonstrate how learning curves can be used to drive changes in the user model. First, we show how using learning curves for subsets of the domain model can yield insight into the appropriateness of the model’s structure. In the second study we use this method to experiment with model granularity. Finally, we use learning curves to analyse a large volume of user data to explore the feasibility of using them as a reliable method for fine-tuning a system’s model. The results of these experiments demonstrate the successful use of performance curves in formative studies of adaptive educational systems
Quasi-Elastic Scattering, Random Fields and phonon-coupling effects in PbMg1/3Nb2/3O3
The low-energy part of the vibration spectrum in PbMgNbO
(PMN) relaxor ferroelectric has been studied by neutron scattering above and
below the Burns temperature, T. The transverse acoustic and the lowest
transverse optic phonons are strongly coupled and we have obtained a model for
this coupling. We observe that the lowest optic branch is always underdamped. A
resolution-limited central peak and quasi-elastic scattering appear in the
vicinity of the Burns temperature. It is shown that it is unlikely that the
quasi-elastic scattering originates from the combined effects of coupling
between TA and TO phonons with an increase of the damping of the TO phonon
below T. The quasi-elastic scattering has a peak as a function of
temperature close to the peak in the dielectric constant while the intensity of
the central peak scattering increases strongly below this temperature. These
results are discussed in terms of a random field model for relaxors
Coexistence of the Critical Slowing Down and Glassy Freezing in Relaxor Ferroelectrics
We have developed a dynamical model for the dielectric response in relaxor
ferroelectrics which explicitly takes into account the coexistence of the
critical slowing down and glassy freezing. The application of the model to the
experiment in PMN allowed for the reconstruction of the nonequilibrium spin
glass state order parameter and its comparison with the results of recent NMR
experiment (Blinc et al., Phys. Rev. Lett. 83, No. 2 (1999)). It is shown that
the degree of the local freezing is rather small even at temperatures where the
field-cooled permittivity exceeds the frequency dependent permittivity by an
order of magnitude. This observation indicates the significant role of the
critical slowing down (accompanying the glass freezing) in the system dynamics.
Also the theory predicts an important interrelationship between the frequency
dependent permittivity and the zero-field-cooled permittivity, which proved to
be consistent with the experiment in PMN (A. Levstik et. al., Phys. Rev. B 57,
11204 (1998))
A Neutron Elastic Diffuse Scattering Study of PMN
We have performed elastic diffuse neutron scattering studies on the relaxor
Pb(MgNb)O (PMN). The measured intensity distribution near a
(100) Bragg peak in the (hk0) scattering plane assumes the shape of a butterfly
with extended intensity in the (110) and (10) directions. The
temperature dependence of the diffuse scattering shows that both the size of
the polar nanoregions (PNR) and the integrated diffuse intensity increase with
cooling even for temperatures below the Curie temperature K.Comment: Submitted to PR
Strong Influence of the diffuse component on the lattice dynamics in Pb(MgNb)O
The temperature and zone dependence of the lattice dynamics in
Pb(MgNb)O is characterized using neutron inelastic
scattering. A strong correlation between the diffuse and phonon scattering is
measured. The lattice dynamics in Brillouin zones where the diffuse scattering
is strong is observed to display qualitatively different behavior than those
zones where the diffuse scattering is weak. In the (220) and (200) zones, where
there is a weak diffuse component, the dynamics are well described by coupled
harmonic oscillators. Compared with SrTiO, the coupling is weak and
isotropic, resulting in only a small transfer of spectral weight from one mode
to another. A comparison of the scattering in these zones to the (110) zone,
where a strong diffuse component is present, reveals a strong coupling of the
diffuse (or central) component to the acoustic mode. We speculate that the
coupling to the central peak is the reason for several recent conflicting
interpretations of the lattice dynamics based on data from zones with a strong
diffuse component.Comment: 7 pages, 7 figure
Competing orders in PZN-xPT and PMN-xPT relaxor ferroelectrics
Neutron and x-ray scattering studies on relaxor ferroelectric systems
Pb(ZnNb)O (PZN), Pb(MgNb)O (PMN), and
their solid solutions with PbTiO (PT) have shown that inhomogeneities and
disorder play important roles in the materials properties. Although a
long-range polar order can be established at low temperature - sometimes with
the help of an external electric field; short-range local structures called the
``polar nano-regions'' (PNR) still persist. Both the bulk structure and the PNR
have been studied in details. The coexistence and competition of long- and
short-range polar orders and how they affect the structural and dynamical
properties of relaxor materials are discussed.Comment: Article submitted for JPSJ Special Topics (Novel States of Matter
Induced by Frustration
The Structural Phase Transition of the Relaxor Ferroelectric 68%PbMg1/3Nb2/3O3-32%PbTiO3
Neutron scattering techniques have been used to study the relaxor
ferroelectric 0.68PbMg1/3Nb2/3O3-0.32PbTiO3 denoted in this paper as
0.68PMN-0.32PT. On cooling, these relaxor ferroelectrics have a long-range
ordered ferroelectric phase and the composition is close to that at which the
ferroelectric structure changes from rhombohedral to tetragonal. It was found
that above the Burns temperature of about 600K, the transverse optic mode and
the transverse acoustic mode are strongly coupled and a model was used to
describe this coupling that gave similar parameters to those obtained for the
coupling in PMN. Below the Burns temperature additional quasi-elastic
scattering was found which increased in intensity as the sample was cooled down
to the ferroelectric transition temperature but then decreased in intensity.
This behaviour is similar to that found in PMN. This scattering is associated
with the dynamic polar nano-regions that occur below the Burns temperature. In
addition to this scattering a strictly elastic resolution limited peak was
observed that was much weaker than the corresponding peak in pure PMN and which
decreased in intensity on cooling below the ferroelectric phase whereas for
PMN, which does not have a long-range ordered ferroelectric phase, the
intensity of this component increased monotonically as the sample was cooled.
The results of our study are compared with the recent measurements of Stock et
al. [PRB 73 064107] who studied 0.4PMN-0.6PT. The results are qualitatively
consistent with the random field model developed to describe the scattering
from PMN
Development of Ferroelectric Order in Relaxor (1-x)Pb(Mg1/3Nb2/3)O3 - xPbTiO3
The microstructure and phase transition in relaxor ferroelectric
Pb(Mg1/3Nb2/3)O3 (PMN) and its solid solution with PbTiO3 (PT), PMN-xPT, remain
to be one of the most puzzling issues of solid state science. In the present
work we have investigated the evolution of the phase symmetry in PMN-xPT
ceramics as a function of temperature (20 K < T < 500 K) and composition (0 <=
x <= 0.15) by means of high-resolution synchrotron x-ray diffraction.
Structural analysis based on the experimental data reveals that the
substitution of Ti^4+ for the complex B-site (Mg1/3Nb2/3)^4+ ions results in
the development of a clean rhombohedral phase at a PT-concentration as low as
5%. The results provide some new insight into the development of the
ferroelectric order in PMN-PT, which has been discussed in light of the
kinetics of polar nanoregions and the physical models of the relaxor
ferroelectrics to illustrate the structural evolution from a relaxor to a
ferroelectric state.Comment: Revised version with updated references; 9 pages, 4 figures embedde
A Universal Phase Diagram for PMN-xPT and PZN-xPT
The phase diagram of the Pb(Mg1/3Nb2/3)O3 and PbTiO3 solid solution (PMN-xPT)
indicates a rhombohedral ground state for x < 0.32. X-ray powder measurements
by Dkhil et al. show a rhombohedrally split (222) Bragg peak for PMN-10%PT at
80 K. Remarkably, neutron data taken on a single crystal of the same compound
with comparable q-resolution reveal a single resolution-limited (111) peak down
to 50 K, and thus no rhombohedral distortion. Our results suggest that the
structure of the outer layer of these relaxors differs from that of the bulk,
which is nearly cubic, as observed in PZN by Xu et al.Comment: Replaced Fig. 3 with better versio
Gadd45α activity is the principal effector of Shigella mitochondria-dependent epithelial cell death in vitro and ex vivo
Modulation of death is a pathogen strategy to establish residence and promote survival in host cells and tissues. Shigella spp. are human pathogens that invade colonic mucosa, where they provoke lesions caused by their ability to manipulate the host cell responses. Shigella spp. induce various types of cell death in different cell populations. However, they are equally able to protect host cells from death. Here, we have investigated on the molecular mechanisms and cell effectors governing the balance between survival and death in epithelial cells infected with Shigella. To explore these aspects, we have exploited both, the HeLa cell invasion assay and a novel ex vivo human colon organ culture model of infection that mimics natural conditions of shigellosis. Our results definitely show that Shigella induces a rapid intrinsic apoptosis of infected cells, via mitochondrial depolarization and the ensuing caspase-9 activation. Moreover, for the first time we identify the eukaryotic stress-response factor growth arrest and DNA damage 45α as a key player in the induction of the apoptotic process elicited by Shigella in epithelial cells, revealing an unexplored role of this molecule in the course of infections sustained by invasive pathogens
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