Coefficient of thermal expansion of nanostructured tungsten based coatings assessed by thermally induced substrate curvature method

The in plane coefficient of thermal expansion (CTE) and the residual stress of nanostructured W based coatings are extensively investigated. The CTE and the residual stresses are derived by means of an optimized ad-hoc developed experimental setup based on the detection of the substrate curvature by a laser system. The nanostructured coatings are deposited by Pulsed Laser Deposition. Thanks to its versatility, nanocrystalline W metallic coatings, ultra-nano-crystalline pure W and W-Tantalum coatings and amorphous-like W coatings are obtained. The correlation between the nanostructure, the residual stress and the CTE of the coatings are thus elucidated. We find that all the samples show a compressive state of stress that decreases as the structure goes from columnar nanocrystalline to amorphous-like. The CTE of all the coatings is higher than the one of the corresponding bulk W form. In particular, as the grain size shrinks, the CTE increases from 5.1 10$^{-6}$ K$^{-1}$ for nanocrystalline W to 6.6 10$^{-6}$ K$^{-1}$ in the ultra-nano-crystalline region. When dealing with amorphous W, the further increase of the CTE is attributed to a higher porosity degree of the samples. The CTE trend is also investigated as function of materials stiffness. In this case, as W coatings become softer, the easier they thermally expand.Comment: The research leading to these results has also received funding from the European Research Council Consolidator Grant ENSURE (ERC-2014-CoG No. 647554

Lectures on curvature flow of networks

We present a collection of results on the evolution by curvature of networks of planar curves. We discuss in particular the existence of a solution and the analysis of singularities

Mean curvature flow with triple junctions in higher space dimensions

We consider mean curvature flow of n-dimensional surface clusters. At (n-1)-dimensional triple junctions an angle condition is required which in the symmetric case reduces to the well-known 120 degree angle condition. Using a novel parametrization of evolving surface clusters and a new existence and regularity approach for parabolic equations on surface clusters we show local well-posedness by a contraction argument in parabolic Hoelder spaces.Comment: 31 pages, 2 figure

On the global structure of conformal gradient solitons with nonnegative Ricci tensor

In this paper we prove that any complete conformal gradient soliton with nonnegative Ricci tensor is either isometric to a direct product $\mathbb{R}\times N^{n-1}$, or globally conformally equivalent to the Euclidean space $\mathbb{R}^{n}$ or to the round sphere $\mathbb{S}^{n}$. In particular, we show that any complete, noncompact, gradient Yamabe-type soliton with positive Ricci tensor is rotationally symmetric, whenever the potential function is nonconstant.Comment: Minor correction

Capacitive mixing for the extraction of energy from salinity differences: Survey of experimental results and electrochemical models

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Probable nonradial g-mode pulsation in early A-type stars

A survey for line profile variability in early A-type stars has been performed in order to detect nonradial pulsation signatures. The star HR 6139, with spectral type A2V and estimated T_eff=8800 K, shows evident line profile variations that can be explained by oscillations in prograde g-modes. This feature and the known photometric variability are similar to those observed in the Slowly Pulsating B-type stars. However HR 6139 is much cooler than the cool border of the instability strip of such variables, and it is hotter than the blue edge of the delta Scuti instability strip. There are indications of a tiny variability also in other four objects, whose nature is not yet clear.Comment: 4 pages, 5 figures; accepted for publication in A&A (letter

Pretransitional behavior in a water-DDAB-5CB microemulsion close to the demixing transition. Evidence for intermicellar attraction mediated by paranematic fluctuations

We present a study of a water-in-oil microemulsion in which surfactant coated water nanodroplets are dispersed in the isotropic phase of the thermotropic liquid crystal 5CB. As the temperature is lowered below the isotropic to nematic phase transition of pure 5CB, the system displays a demixing transition leading to a coexistence of a droplet rich isotropic phase with a droplet poor nematic. The transition is anticipated, in the high T side, by increasing pretransitional fluctuations in 5CB molecular orientation and in the nanodroplet concentration. The observed phase behavior supports the notion that the nanosized droplets, while large enough for their statistical behavior to be probed via light scattering, are also small enough to act as impurities, disturbing the local orientational ordering of the liquid crystal and thus experiencing pretransitional attractive interaction mediated by paranematic fluctuations. The pretransitional behavior, together with the topology of the phase diagram, can be understood on the basis of a diluted Lebwohl-Lasher model which describes the nanodroplets simply as holes in the liquid crystal.Comment: 64 pages, 16 figures, J. Chem. Phys. in pres