518 research outputs found
Reply to "Comment on Renormalization group picture of the Lifshitz critical behaviors"
We reply to a recent comment by Diehl and Shpot (cond-mat/0305131)
criticizing a new approach to the Lifshitz critical behavior just presented (M.
M. Leite Phys. Rev. B 67, 104415(2003)). We show that this approach is free of
inconsistencies in the ultraviolet regime. We recall that the orthogonal
approximation employed to solve arbitrary loop diagrams worked out at the
criticized paper even at three-loop level is consistent with homogeneity for
arbitrary loop momenta. We show that the criticism is incorrect.Comment: RevTex, 6 page
Avaliação do desempenho e mudança em contabilidade de gestão: o caso do Direção Regional de Administração Educativa da Região Autónoma da Madeira
Os objetivos desta investigação foram compreender como e por que foi introduzido o istema Integrado de gestão e Avaliação do Desempenho na Administração Pública (SIADAP) na Região Autónoma da Madeira (RAM), como e por que se implementou o SIADAP-RAM na Direção Regional da Administração Educativa (DRAE), e, por fim, como tem sido utilizada a informação proveniente do SIADAP-RAM na DRAE e porquê. Com enquadramento na teoria institucional, o estudo de caso fez uma análise dos documentos legais e, com base nos resultados das entrevistas realizadas aos avaliadores e avaliados, concluiu-se que os avaliadores da DRAE não executam o processo de avaliação do desempenho, estabelecido por lei, de forma uniforme. O SIADAP surgiu em substituição do Sistema de Classificação de Serviço. A mudança surgiu por imposição legal, conforme com o fenómeno de isomorfismo coercivo a que se refere a literatura.info:eu-repo/semantics/draf
Susceptibility Amplitude Ratios Near a Lifshitz Point
The susceptibility amplitude ratio in the neighborhood of a uniaxial Lifshitz
point is calculated at one-loop level using field-theoretic and
-expansion methods. We use the Schwinger parametrization of the
propagator in order to split the quadratic and quartic part of the momenta, as
well as a new special symmetry point suitable for renormalization purposes. For
a cubic lattice (d = 3), we find the result .Comment: 7 pages, late
Susceptibility amplitude ratio for generic competing systems
We calculate the susceptibility amplitude ratio near a generic higher
character Lifshitz point up to one-loop order. We employ a renormalization
group treatment with independent scaling transformations associated to the
various inequivalent subspaces in the anisotropic case in order to compute the
ratio above and below the critical temperature and demonstrate its
universality. Furthermore, the isotropic results with only one type of
competition axes have also been shown to be universal. We describe how the
simpler situations of -axial Lifshitz points as well as ordinary
(noncompeting) systems can be retrieved from the present framework.Comment: 20 pages, no figure
Exploring the reactivity of formylporphyrins with 3-(diethylamino)phenol. Synthesis, spectroscopic properties and singlet oxygen generation of a new porphyrin–rosamine conjugate
The design of novel molecular structures with tunable photophysical properties is an important research field for many applications including optoelectronics, sensing and bioimaging. Porphyrin and rhodamine/rosamine derivatives are among the most studied and relevant chemosensors and imaging probes due to their attractive photophysical properties, such as high absorption coefficients and long emission wavelengths. In this work, we present the synthesis and the structural characterization of a new porphyrin–rosamine conjugate H2P3 and its related triarylmethane precursors H2P1 and H2P2. The photophysical properties of H2P1, H2P2 and H2P3, and their ability to chelate iron(III) and copper(II) ions, were evaluated by absorption and emission spectroscopy. The formation of copper(II) complexes was confirmed by electron paramagnetic resonance (EPR), which also allowed the detection of an intense and stable radical signal for the free-base H2P3. Further studies involving the addition of the 2,2,6,6-tetramethylpiperidine spin trap to derivatives H2P1, H2P2 and H2P3, showed that only H2P3 gives rise to an EPR detectable signal due to a strong generation of singlet oxygen.publishe
Epidemiologia molecular de um surto de bacteriemia por Enterobacter cloacae e Enterobacter agglomerans ocorrido na região de Campinas, São Paulo, Brasil
A total of 73 isolates (57 Enterobacter cloacae and 16 Enterobacter agglomerans), recovered during an outbreak of bacteremia in the Campinas area, São Paulo, Brazil, were studied. Of these isolates, 61 were from parenteral nutrition solutions, 9 from blood cultures, 2 from a sealed bottle of parenteral nutrition solution, and one was of unknown origin. Of the 57 E. cloacae isolates, 54 were biotype 26, two were biotype 66 and one was non-typable. Of 39 E. cloacae isolates submitted to ribotyping, 87.2% showed the same banding pattern after cleavage with EcoRI and BamHI. No important differences were observed in the antimicrobial susceptibility patterns among E. cloacae isolates exhibiting the same biotype, serotype and ribotype. All E. agglomerans isolates, irrespective of their origin, showed same patterns when cleaved with EcoRI and BamHI. The results of this investigation suggest an intrinsic contamination of parenteral nutrition solutions and incriminate these products as a vehicle of infection in this outbreak.Foram estudadas um total de 73 cepas (57 de E. cloacae e 16 E. agglomerans), isoladas durante um surto de bacteriemia ocorrido na região de Campinas, S. Paulo. Entre estas cepas, 61 foram isoladas de solução de nutrição parenteral, 9 de sangue, 2 de bolsa fechada de solução de nutrição parenteral e uma era de origem desconhecida. Entre as 57 cepas de E. cloacae, a maioria das cepas foram do biotipo 26/sorotipo O3 (39 cepas) e do biotipo 26/OR (13). Entre as 39 cepas de E. cloacae ribotipadas, 87,2% apresentaram o mesmo padrão de bandas com EcoRI e BamHI. Cepas de E. cloacae pertencentes ao mesmo biotipo, sorotipo e ribotipo não apresentaram diferenças significativas em relação ao padrão de sensibilidade aos agentes antimicrobianos. Todas as cepas de E. agglomerans, independente da origem, pertenciam ao mesmo ribotipo após a clivagem com EcoRI e BamHI. Os resultados obtidos sugerem uma contaminação intrÃnseca das soluções de nutrição parenteral, incriminando-as como o veÃculo de transmissão dos agentes etiológicos do surto
Surface critical exponents at a uniaxial Lifshitz point
Using Monte Carlo techniques, the surface critical behaviour of
three-dimensional semi-infinite ANNNI models with different surface
orientations with respect to the axis of competing interactions is
investigated. Special attention is thereby paid to the surface criticality at
the bulk uniaxial Lifshitz point encountered in this model. The presented Monte
Carlo results show that the mean-field description of semi-infinite ANNNI
models is qualitatively correct. Lifshitz point surface critical exponents at
the ordinary transition are found to depend on the surface orientation. At the
special transition point, however, no clear dependency of the critical
exponents on the surface orientation is revealed. The values of the surface
critical exponents presented in this study are the first estimates available
beyond mean-field theory.Comment: 10 pages, 7 figures include
Graded Poisson-Sigma Models and Dilaton-Deformed 2D Supergravity Algebra
Fermionic extensions of generic 2d gravity theories obtained from the graded
Poisson-Sigma model (gPSM) approach show a large degree of ambiguity. In
addition, obstructions may reduce the allowed range of fields as given by the
bosonic theory, or even prohibit any extension in certain cases. In our present
work we relate the finite W-algebras inherent in the gPSM algebra of
constraints to algebras which can be interpreted as supergravities in the usual
sense (Neuveu-Schwarz or Ramond algebras resp.), deformed by the presence of
the dilaton field. With very straightforward and natural assumptions on them
--like demanding rigid supersymmetry in a certain flat limit, or linking the
anti-commutator of certain fermionic charges to the Hamiltonian constraint-- in
the ``genuine'' supergravity obtained in this way the ambiguities disappear, as
well as the obstructions referred to above. Thus all especially interesting
bosonic models (spherically reduced gravity, the Jackiw-Teitelboim model etc.)\
under these conditions possess a unique fermionic extension and are free from
new singularities. The superspace supergravity model of Howe is found as a
special case of this supergravity action. For this class of models the relation
between bosonic potential and prepotential does not introduce obstructions as
well.Comment: 22 pages, LaTeX, JHEP class. v3: Final version, to appear in JHE
Lycopene-rich extract from red guava ( Psidium guajava L.) displays cytotoxic effect against human breast adenocarcinoma cell line MCF-7 via an apoptotic-like pathway
This study investigated a lycopene-rich extract from red guava (LEG) for its chemical composition using spectrophotometry, mass spectrometry, attenuated total reflectance-fourier transform infrared spectroscopy (ATR-FTIR), and computational studies. The cytotoxic activity of LEG and the underlying mechanism was studied in human breast adenocarcinoma cells (MCF-7), murine fibroblast cells (NIH-3T3), BALB/c murine peritoneal macrophages, and sheep blood erythrocytes by evaluating the cell viability with 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) method and flow cytometry. Spectrophotometry analysis showed that LEG contained 20% of lycopene per extract dry weight. Experimental and theoretical ATR-FTIR suggests the presence of lycopene, whereas MS/MS spectra obtained after fragmentation of the molecular ion [M]+• of 536.4364 show fragment ions at m/z 269.2259, 375.3034, 444.3788, and 467.3658, corroborating the presence of lycopene mostly related to all-trans configuration. Treatment with LEG (1600 to 6.25μg/mL) for 24 and 72h significantly affected the viability of MCF-7 cells (mean half maximal inhibitory concentration [IC50]=29.85 and 5.964μg/mL, respectively) but not NIH-3T3 cells (IC50=1579 and 911.5μg/mL, respectively). Furthermore LEG at concentrations from 800 to 6.25μg/mL presented low cytotoxicity against BALB/c peritoneal macrophages (IC50≥800μg/mL) and no hemolytic activity. LEG (400 and 800μg/mL) caused reduction in the cell proliferation and induced cell cycle arrest, DNA fragmentation, modifications in the mitochondrial membrane potential, and morphologic changes related to granularity and size in MCF-7 cells; however, it failed to cause any significant damage to the cell membrane or display necrosis or traditional apoptosis. In conclusion, LEG was able to induce cytostatic and cytotoxic effects on breast cancer cells probably via induction of an apoptotic-like pathway.The authors acknowledge the computational time provided by CENAPAD/SP on the project proj697. Alexandra Plácido is gratefully to FCT by her grant SFRH/BD/97995/2013, financed by POPH–QREN–Tipologia 4.1–Formação Avançada, subsidized by Fundo Social Europeu and Ministério da Ciência, Tecnologia e Ensino Superior. The work at REQUIMTE/LAQV received financial support from the European Union (FEDER funds through COMPETE) and National Funds (FCT) through project UID/QUI/50006/2013. Adriany das G. N. Amorim is grateful to CAPES by for the doctoral fellowship process no. 99999.004236/2014-09 in Federal University of Piauà (UFPI). Eder A. Barbosa is grateful to PNPD/CAPES for its post-doctoral fellowship.info:eu-repo/semantics/publishedVersio
- …