Management and creation of a new tourist route in the National Park of the Sibillini Mountains using GIS Software, for economic development

This analysis is focused in a small portion of territory in central Italy where the National Park of Sibillini mountains is located. This Park strongly needs a tourist and economic development, so the possibility of creating a new tourist route has been considered. GIS software was used to create and manage the route, using orthophotos and digitizing the required data. The main goal of this study is represented by the creation of an evaluation system for the route, composed by numerous informations managed statistically through GIS software, assessing slope, type of route, road surface, hiking difficulties and passage through towns. This procedure allows a significant improvement in the local economy and a more rational use of available resources, including human ones

Do Postures of Distal Effectors Affect the Control of Actions of Other Distal Effectors? Evidence for a System of Interactions between Hand and Mouth

The present study aimed at determining whether, in healthy humans, postures assumed by distal effectors affect the control of the successive grasp executed with other distal effectors. In experiments 1 and 2, participants reached different objects with their head and grasped them with their mouth, after assuming different hand postures. The postures could be implicitly associated with interactions with large or small objects. The kinematics of lip shaping during grasp varied congruently with the hand posture, i.e. it was larger or smaller when it could be associated with the grasping of large or small objects, respectively. In experiments 3 and 4, participants reached and grasped different objects with their hand, after assuming the postures of mouth aperture or closure (experiment 3) and the postures of toe extension or flexion (experiment 4). The mouth postures affected the kinematics of finger shaping during grasp, that is larger finger shaping corresponded with opened mouth and smaller finger shaping with closed mouth. In contrast, the foot postures did not influence the hand grasp kinematics. Finally, in experiment 5 participants reached-grasped different objects with their hand while pronouncing opened and closed vowels, as verified by the analysis of their vocal spectra. Open and closed vowels induced larger and smaller finger shaping, respectively. In all experiments postures of the distal effectors induced no effect, or only unspecific effects on the kinematics of the reach proximal/axial component. The data from the present study support the hypothesis that there exists a system involved in establishing interactions between movements and postures of hand and mouth. This system might have been used to transfer a repertoire of hand gestures to mouth articulation postures during language evolution and, in modern humans, it may have evolved a system controlling the interactions existing between speech and gestures

Analysis of landslide Susceptibility and Tree Felling Due to an Extreme Event at Mid-Latitudes: Case Study of Storm Vaia, Italy

Storm Vaia on 29 October 2018, hit northeastern Italy and produced extensive damage in the immediacy of the event, including extensive tree felling in some places, as well as debris flow or earth flow landslides. This study aims to assess the susceptibility of the area following extreme events by evaluating the environmental criticality during strong winds and intense precipitation. Specifically, tree felling susceptibility due to wind and landslide susceptibility due mainly to precipitation were analysed by taking into consideration the geomorphological and environmental criticality of the areas under study. In particular, the area was modelled using fluid dynamics software, allowing an understanding of wind accelerations in relation to morphology, showing excellent agreement between the tree falls that occurred during the event and the areas with the highest wind gusts. With regard to landslides, an algorithm was prepared through GIS software that took into account the debris and earth flows that were activated during the extreme event in question, allowing the creation of a susceptibility map that delineated areas of high potential hazard. The final result is a landslide and tree-fall susceptibility map that determines the fragility of the territory during an extreme event. The procedures applied in the study area can be considered as a working method that allows critical values to be obtained for extreme events that can produce damage to the environment and beyond. It follows that this research also has an immediate application purpose by helping the political decision-maker in the choice of interventions to be implemented

Trend analysis of streamflows in relation to precipitation. A case study in central Italy

The monitoring of water resources is becoming increasingly important for humid temperate climates in light of climate change, which shows a generalised increase in temperatures and a decrease in precipitation, which is not generalised but relative to the area of interest. In this context, it is interesting to understand what the climatic changes have been, in terms of precipitation and how they have affected streamflows, by analysing them on a monthly basis. At the basin scale, interpolations were carried out with geostatistical methods using GIS software, spatialising the areal distribution of precipitation and obtaining an average value that can be correlated with water flows. As a pilot project, this research analysed the Upper Potenza basin in relation to the flow rates of the Potenza River over two reference periods, from 1964 to 1979 and from 2005 to 2020. The results show a decreasing trend in streamflows within the studied basin, while the precipitation trend decreases for the period 1964–1979 and increases for the period 2005–2020. Effective precipitation, in turn, shows a rather pronounced decrease in the more recent 2005–2020 period, due to climate change influencing the increase in temperature and consequently, the increase in evapotranspiration. In this context, it is significant to note that the Pearson correlation coefficient of streamflow to effective rainfall for both periods is about 0.8, suggesting that the net of anthropogenic disturbances, streamflow and actual precipitation maintain a high correlation. This model could be exported to other territories, in order to gain a global view for a better understanding and subsequent adaptation to ongoing climate change

Expedient synthesis of pseudo-Pro-containing peptides: Towards constrained peptidomimetics and foldamers

The reaction of sulfonyl peptides containing l- or d-configured Ser or Thr with bis(succinimidyl) carbonate in the presence of a catalytic amount of a base affords, in solution or in the solid phase, the corresponding peptides with one or two, consecutive or alternate oxazolidin-2-ones (Oxd). The Oxd ring can be regarded to as a pseudo-Pro with an exclusively trans conformation of the preceding peptide bond; homochiral Oxd-containing peptides adopt extended conformations, while the presence of a d-configured Oxd favours folded conformations. © The Royal Society of Chemistry 2012

Hydrogeochemical and Stable Isotope Data of the Groundwater of a Multi-Aquifer System in the Maknessy Basin (Mediterranean Area, Central Tunisia)

The Maknessy plain in central Tunisia is one of the most important agricultural basins in Tunisia. Given the semi-arid climate conditions, the irrigation of cultivated crops relies principally on the abstraction from groundwater resources. The assessment of the quality of the used water for agricultural purposes is crucial for safe production. Thus, the objective of this work is to assess the physicochemical quality of the irrigation water resources in this catchment area using a combined chemical, isotopic, and statistical approach. The waters analyzed are represented by two types of groundwater, mainly calcium hyper chloride and calcium sulfate. A multivariate statistical analysis (PCA and HCA) and a geochemical approach have been applied to study water quality as a function of chemical parameters, showing that the EC and TDS are the parameters influencing water quality. The stable isotopic compositions of the sampled waters range from -7.53 to -4.90% vs. VSMOW and from -53.6 to -32.2% vs. VSMOW for delta O-18 and delta H-2; they show the exchange between groundwater and rock and the evaporation effect. The isotopic data form three groups such as recent water, paleowater, and mixing water indicate the evaporation effect and interaction of the groundwater, and confirm that this aquifer has been recharged by current rainwater. So, these aquifers were recharged by precipitation derived from a mixture of cloud masses from the Atlantic Ocean and the Mediterranean Sea. The findings of this research are of important relevance for effective water resources management in this agro-based region. Indeed, the increased exploitation of these resources will induce a continuous reduction in the available resources and progressive degradation of the used water quality that may adversely impact the safe agricultural production and the economic resilience of the local population

Spatial Effects of NAO on Temperature and Precipitation Anomalies in Italy

The NAO teleconnective pattern has a great influence on the European climate; however, the exact quantification of NAO pattern in the different areas is sometimes lacking, and at other times, highlights even large differences between the various studies. This motivation led to the identification of the aim of this research in the study of the relationship between the NAO index and temperature and precipitation anomalies over the period 1991-2020, through the analysis of 87 rain gauges and 86 thermometric stations distributed as homogeneously as possible over the Italian territory. The results were sometimes at odds with the scientific literature on the subject, as significance was also found outside the winter season, e.g., in the spring for temperatures and in the autumn for precipitation, and in some cases, correlations were found, especially in August, even in southern Italy, which is usually considered a poorly correlated area. In addition, the linear relationship between the NAO index and temperature and precipitation anomalies was verified, with many weather stations obtaining significant coefficients of determinations as high as 0.5-0.6 in December, with 29 degrees of freedom, and a p-value set at 95%. Finally, for both climatic parameters, the presence of clusters and outliers at seasonal and monthly levels was assessed, obtaining a spatial distribution using the local Moran index, and summarising them in maps. This analysis highlighted important clusters in Northern and Central Italy, while clusters in the summer months occur in the South. These results provide information that may further elucidate local atmospheric dynamics in relation to NAO phases, as well as encourage future studies that may link other teleconnective indices aimed at better explaining the variance of climate parameters

The geoenvironmental factors influencing slope failures in the Majerda basin, Algerian-Tunisian border

In mountainous regions globally, landslides pose severe threats to both human lives and infrastructure, with the Mediterranean region, in particular, being highly susceptible to these destructive events that result in substantial damage to settlements and infrastructure. In this study, we employ a GIS-based approach to comprehensively characterize terrain instabilities along the Algerian-Tunisian border, recognizing the critical need for effective land planning and disaster mitigation strategies in this context. Our methodology integrates geological, geophysical, and geotechnical reconnaissance techniques and multi-criteria analysis, with a particular focus on geotechnical parameters. Our findings reveal significant slope instability within the study area; it is particularly concentrated in the mid-altitude slopes of the eastern basin, with high and very high susceptibility zones covering 20.89% of the study area. Validation of our model through ROC analysis demonstrates its high accuracy, with an area under the curve (AUC) value of 0.92. Crucially, slope gradients and precipitation emerge as key contributors to landslide occurrence, alongside Triassic lithofacies, which is a significant geological factor influencing susceptibility. These results emphasize the necessity of identifying high-landslide-susceptibility regions for sustainable land management and risk reduction, which will ultimately enhance the resilience of the studied region and mitigate the associated natural hazard risks

Analysis of Snow Cover in the Sibillini Mountains in Central Italy

Research on solid precipitation and snow cover, especially in mountainous areas, suffers from problems related to the lack of on-site observations and the low reliability of measurements, which is often due to instruments that are not suitable for the environmental conditions. In this context, the study area is the Monti Sibillini National Park, and it is no exception, as it is a mountainous area located in central Italy, where the measurements are scarce and fragmented. The purpose of this research is to provide a characterization of the snow cover with regard to maximum annual snow depth, average snow depth during the snowy period, and days with snow cover on the ground in the Monti Sibillini National Park area, by means of ground weather stations, and also analyzing any trends over the last 30 years. For this research, in order to obtain reliable snow cover data, only data from weather stations equipped with a sonar system and manual weather stations, where the surveyor goes to the site each morning and checks the thickness of the snowpack and records, it were collected. The data were collected from 1 November to 30 April each year for 30 years, from 1991 to 2020; six weather stations were taken into account, while four more were added as of 1 January 2010. The longer period was used to assess possible ongoing trends, which proved to be very heterogeneous in the results, predominantly negative in the case of days with snow cover on the ground, while trends were predominantly positive for maximum annual snow depth and distributed between positive and negative for the average annual snow depth. The shorter period, 2010–2022, on the other hand, ensured the presence of a larger number of weather stations and was used to assess the correlation and presence of clusters between the various weather stations and, consequently, in the study area. Furthermore, in this way, an up-to-date nivometric classification of the study area was obtained (in terms of days with snow on the ground, maximum height of snowpack, and average height of snowpack), filling a gap where there had been no nivometric study in the aforementioned area. The interpolations were processed using geostatistical techniques such as co-kriging with altitude as an independent variable, allowing fairly precise spatialization, analyzing the results of cross-validation. This analysis could be a useful tool for hydrological modeling of the area, as well as having a clear use related to tourism and vegetation, which is extremely influenced by the nivometric variables in its phenology. In addition, this analysis could also be considered a starting point for the calibration of more recent satellite products dedicated to snow cover detection, in order to further improve the compiled climate characterizatio

Interpolation of rainfall through polynomial regression in the Marche Region (Central Italy)

Notwithstanding its small size (less than 10000 km2), because of its varied topography, ranging from the Apennines Range (up to more than 2000 m amsl) to coastal environments, the Marche Region (the Adriatic side of Central Italy), is characterized by many different types of climate. In this region there are no fully satisfactory models to interpolate and generalize rainfall data from the 111available meteorological recording stations; however, in this study an innovative way to interpret data linking precipitation to many topographic parameters is introduced. Based on those considerations, statistical analyses were carried out on rainfall historical series in order to assess significantly variations during the last 60 years and to create a model capable of explaining rainfall distribution based on geo-graphical and topographic parameters. Thus on one hand was highlighted a significant decrease of rainfall from 1961-1990 to 1991-2016, over the whole period, in the hilly and mountainous sectors (100-200 mm), while closer to the coast the difference is slight (about 0 – 100 mm), on the other the new model highlights the presence of some outliers, which may lead to a better comprehension of climatic dynamics in this area