Triply Threaded [4]Rotaxanes

[4]Rotaxanes featuring three axles threaded through a single ring have been prepared through active metal template synthesis. Nickel-catalyzed sp3-sp3 homocouplings of alkyl bromide ‘half threads’ through 37- and 38-membered 2,2':6',2"-terpyridyl macrocycles generates triply-threaded [4]rotaxanes in up to 11 % yield. An analogous 39-membered macrocycle produced no rotaxane products under similar conditions. The constitutions of the [4]rotaxanes were determined by NMR spectroscopy and mass spectrometry. Doubly-threaded [3]rotaxanes were also obtained from the reactions but no [2]rotaxanes were isolated, suggesting that upon demetallation the axle of a singly-threaded rotaxane can slip through a macrocycle that is sufficiently large to accommodate three threads

Towards the Theory of Cosmological Phase Transitions

We discuss recent progress (and controversies) in the theory of finite temperature phase transitions. This includes the structure of the effective potential at a finite temperature, the infrared problem in quantum statistics of gauge fields, the theory of formation of critical and subcritical bubbles and the theory of bubble wall propagation.Comment: 50 p

Photophysical properties of thin films and solid phase of switchable supermolecular anthracene-based rotaxanes

Polycrystalline powders and thin films of a novel rotaxane, methyl-exopyridine-anthracene rotaxane (EPAR-Me), and of the related thread and stoppers 10-[3,5-di (ter butyl)phenoxy]decyl-2-({2-[(9-anthrylcarbonyl) amino] acetyl}amino) acetate (ANTPEP), have been characterised by photoluminescence, absorption and photoluminescence excitation spectroscopy. A rather unusual, i.e. unstructured and largely red-shifted, photoluminescence spectral behaviour of the rotaxane has been found. Preliminary time resolved measurements indicate a fast energy transfer from the anthracene unit to different species the nature of which is still not assigned.

Reliability of fluctuation-induced transport in a Maxwell-demon-type engine

We study the transport properties of an overdamped Brownian particle which is simultaneously in contact with two thermal baths. The first bath is modeled by an additive thermal noise at temperature $T_A$. The second bath is associated with a multiplicative thermal noise at temperature $T_B$. The analytical expressions for the particle velocity and diffusion constant are derived for this system, and the reliability or coherence of transport is analyzed by means of their ratio in terms of a dimensionless P\'{e}clet number. We find that the transport is not very coherent, though one can get significantly higher currents.Comment: 14 pages, 5 figure

On the covariant quantization of tensionless bosonic strings in AdS spacetime

The covariant quantization of the tensionless free bosonic (open and closed) strings in AdS spaces is obtained. This is done by representing the AdS space as an hyperboloid in a flat auxiliary space and by studying the resulting string constrained hamiltonian system in the tensionless limit. It turns out that the constraint algebra simplifies in the tensionless case in such a way that the closed BRST quantization can be formulated and the theory admits then an explicit covariant quantization scheme. This holds for any value of the dimension of the AdS space.Comment: 1+16 pages; v4 two clarifications adde

Probing exotic phenomena at the interface of nuclear and particle physics with the electric dipole moments of diamagnetic atoms: A unique window to hadronic and semi-leptonic CP violation

The current status of electric dipole moments of diamagnetic atoms which involves the synergy between atomic experiments and three different theoretical areas -- particle, nuclear and atomic is reviewed. Various models of particle physics that predict CP violation, which is necessary for the existence of such electric dipole moments, are presented. These include the standard model of particle physics and various extensions of it. Effective hadron level combined charge conjugation (C) and parity (P) symmetry violating interactions are derived taking into consideration different ways in which a nucleon interacts with other nucleons as well as with electrons. Nuclear structure calculations of the CP-odd nuclear Schiff moment are discussed using the shell model and other theoretical approaches. Results of the calculations of atomic electric dipole moments due to the interaction of the nuclear Schiff moment with the electrons and the P and time-reversal (T) symmetry violating tensor-pseudotensor electron-nucleus are elucidated using different relativistic many-body theories. The principles of the measurement of the electric dipole moments of diamagnetic atoms are outlined. Upper limits for the nuclear Schiff moment and tensor-pseudotensor coupling constant are obtained combining the results of atomic experiments and relativistic many-body theories. The coefficients for the different sources of CP violation have been estimated at the elementary particle level for all the diamagnetic atoms of current experimental interest and their implications for physics beyond the standard model is discussed. Possible improvements of the current results of the measurements as well as quantum chromodynamics, nuclear and atomic calculations are suggested.Comment: 46 pages, 19 tables and 16 figures. A review article accepted for EPJ

Differences in the pattern and regulation of mineral deposition in human cell lines of osteogenic and non-osteogenic origin

Bone marrow-derived mesenchymal stem cells (MSCs) are widely used as a cellular model of bone formation, and can mineralize in vitro in response to osteogenic medium (OM). It is unclear, however, whether this property is specific to cells of mesenchymal origin. We analysed the OM response in 3 non-osteogenic lines, HEK293, HeLa and NTera, compared to MSCs. Whereas HEK293 cells failed to respond to OM conditions, the 2 carcinoma-derived lines NTera and HeLa deposited a calcium phosphate mineral comparable to that present in MSC cultures. However, unlike MSCs, HeLa and NTera cultures did so in the absence of dexamethasone. This discrepancy was confirmed, as bone morphogenetic protein inhibition obliterated the OM response in MSCs but not in HeLa or NTera, indicating that these 2 models can deposit mineral through a mechanism independent of established dexamethasone or bone morphogenetic protein signalling