604 research outputs found

    Who uses bottled gas ? evidence from households in developing countries

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    Household surveys in Guatemala, India, Indonesia, Kenya, Pakistan, and Sri Lanka were analyzed using a two-stage Heckman model to examine the factors influencing the decision to use liquefied petroleum gas (stage 1) and, among users, the quantity consumed per person (stage 2). In the first stage, liquefied petroleum gas selection in all six countries increased with household expenditure and the highest level of education attained by female and male household members. Electricity connection increased, and engagement in agriculture and increasing household size decreased, liquefied petroleum gas selection in five countries; urban residence increased selection in four countries; and rising firewood and kerosene prices increased selection in three countries each. In the second stage, the quantity of liquefied petroleum gas consumed increased with rising household expenditure and decreasing price of liquefied petroleum gas in every country. Urban residence increased and engagement in agriculture decreased liquefied petroleum gas consumption. Surveys in Albania, Brazil, Mexico, and Peru, which did not report quantities, were also examined by calculating quantities using national average prices. Although fuel prices faced by individual households could not be tested, the findings largely supported those from the first six countries. Once the education levels of men and women were separately accounted for, the gender of the head of household was not statistically significant in most cases across the ten countries. Where it was significant (five equations), the sign of the coefficient was positive for men, possibly suggesting that female-headed households are burdened with unmeasured economic disadvantages, making less cash available for purchasing liquefied petroleum gas.Energy Production and Transportation,Markets and Market Access,Energy Conservation&Efficiency,Renewable Energy,Energy and Environment

    High Sensitivity DNA Detection Using Gold Nanoparticle Functionalised Polyaniline Nanofibres

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    Polyaniline (PANI) nanofibres (PANI-NF) have been modified with chemically grown gold nanoparticles to give a nanocomposite material (PANI-NF–AuNP) and deposited on gold electrodes. Single stranded capture DNA was then bound to the gold nanoparticles and the underlying gold electrode and allowed to hybridise with a complementary target strand that is uniquely associated with the pathogen, Staphylococcus aureus (S. aureus), that causes mastitis. Significantly, cyclic voltammetry demonstrates that deposition of the gold nanoparticles increases the area available for DNA immobilisation by a factor of approximately 4. EPR reveals that the addition of the Au nanoparticles efficiently decreases the interactions between adjacent PANI chains and/or motional broadening. Finally, a second horseradish peroxidase (HRP) labelled DNA strand hybridises with the target allowing the concentration of the target DNA to be detected by monitoring the reduction of a hydroquinone mediator in solution. The sensors have a wide dynamic range, excellent ability to discriminate DNA mismatches and a high sensitivity. Semi-log plots of the pathogen DNA concentration vs. faradaic current were linear from 150 × 10−12 to 1 × 10−6 mol L−1 and pM concentrations could be detected without the need for molecular, e.g., PCR or NASBA, amplification

    Time Domain Reflectometry Waveform Analysis with Second-Order Bounded Mean Oscillation

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    Tangent-line methods and adaptive waveform interpretation with Gaussian filtering (AWIGF) have been proposed for determining reflection positions of time domain reflectometry (TDR) waveforms. However, the accuracy of those methods is limited for short-probe TDR sensors. Second-order bounded mean oscillation (BMO) may be an alternative method to determine reflection positions of short-probe TDR waveforms. For this study, an algorithm of second-order BMO is developed. Example waveforms are analyzed with tangent-line methods, AWIGF method, and second-order BMO to illustrate the difference among the three methods. For some waveforms, second-order BMO appears be able to give more plausible results. Automatic implementation was challenging for the second-order BMO. With second-order BMO, it is difficult to set a default threshold suitably for all TDR waveforms. Thus, manual adjustment may be required to select a suitable threshold for second-order BMO analysi

    Field Test and Sensitivity Analysis of a Sensible Heat Balance Method to Determine Soil Ice Contents

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    Feasibility of the sensible heat balance (SHB) method for determining in situ soil ice content with heat pulse (HP) sensors was evaluated using field measurements. The required accuracy of HP sensor measurements for SHB was further assessed with a sensitivity analysis. Improving accuracy of thermal conductivity measurements and using short time steps are necessary to accurately estimate ice contents with the SHB method. Soil ice content impacts winter vadose zone hydrology. It may be possible to estimate changes in soil ice content with a sensible heat balance (SHB) method, using measurements from heat pulse (HP) sensors. Feasibility of the SHB method is unknown because of difficulties in measuring soil thermal properties in partially frozen soils. The objectives of this study were (i) to examine the SHB method for determining in situ ice content, and (ii) to evaluate the required accuracy of HP sensors for use in the SHB method. Heat pulse sensors were installed in a bare field to measure soil temperatures and thermal properties during freezing and thawing events. In situ soil ice contents were determined at 60-min intervals with SHB theory. Sensitivity of the SHB method to temperature, heat capacity, thermal conductivity, and time step size was analyzed based on numerically produced soil freezing and thawing events. The in situ ice contents determined with the SHB method were sometimes unrealistically large or even negative. Thermal conductivity accuracy and time step size were the key factors contributing to SHB errors, while temperature and heat capacity accuracy had less influence. Ice content estimated with a 15-min SHB time step was more accurate than that estimated with a 60-min time step. Sensitivity analysis indicated that measurement errors in soil temperature and thermal conductivity should be less than ±0.05°C and ±20%, respectively, but the error in the soil heat capacity could vary by ±50%. Thus, improving the accuracy of thermal conductivity measurements and using short time steps are required to accurately estimate soil ice contents with the SHB method

    Bulk Density Effects on Soil Hydrologic and Thermal Characteristics: a Numerical Investigation

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    Soil bulk density (ρb) is commonly treated as static in studies of land surface dynamics. Magnitudes of errors associated with this assumption are largely unknown. Our objectives were to: i) quantify ρb effects on soil hydrologic and thermal properties, and ii) evaluate effects of ρb on surface energy balance and heat and water transfer. We evaluated six soil properties, volumetric heat capacity, thermal conductivity, soil thermal diffusivity, water retention characteristics, hydraulic conductivity, and vapor diffusivity, over a range of ρb, using a combination of six models. Thermal conductivity, water retention, hydraulic conductivity, and vapor diffusivity were most sensitive to ρb, each changing by fractions greater than the associated fractional changes in ρb. A 10% change in ρb led to 10-11% change in thermal conductivity, 6-11% change in saturated and residual water content, 49-54% change in saturated hydraulic conductivity, and 80% change in vapor diffusivity. Subsequently, three field seasons were simulated with a numerical model (HYDRUS-1D) for a range of ρb values. When ρb increased from 1.2 to 1.5 Mg m-3; 25% increase, soil temperature variation decreased by 2.1°C in shallow layers and increased by 1°C in subsurface layers. Surface water content differed by 0.02 m3 m-3 for various ρb values during drying events but differences mostly disappeared in the subsurface. Matric potential varied by \u3e100 m of water. Surface energy balance showed clear trends with ρb. Latent heat flux decreased 6%, sensible heat flux increased 9%, and magnitude of ground heat flux varied by 18% with a 25% ρb increase). Transient ρb impacted surface conditions and fluxes, and clearly it warrants consideration in field and modeling investigations

    Low-Cost, Class D Testing of Spacecraft Photovoltaic Systems Can Reduce Risk

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    The end-to-end verification of a spacecraft photovoltaic power generation system requires light! A lowcost, portable, and end-to-end photovoltaic-system test appropriate for NASA's new generation of Class D missions is presented. High risk, low-cost, and quick-turn satellites rarely have the resources to execute the traditional approaches from higher-class (A-C) missions. The Class D approach, as demonstrated on the Lunar Atmospheric and Dust Environment Explorer (LADEE), utilizes a portable, metalhalide, theatre lamp for an end-to-end photovoltaic system test. While not as precise and comprehensive as the traditional Large Area Pulsed Solar Simulator (LAPSS) test, the LADEE method leverages minimal resources into an ongoing assessment program that can be applied through numerous stages of the mission. The project takes a true Class D approach in assessing the technical value of a costly, highfidelity performance test versus a simpler approach with less programmatic risk. The resources required are a fraction of that for a LAPSS test, and is easy to repeat due to its portability. Further, the test equipment can be handed down to future projects without building an on-site facility. At the vanguard of Class D missions, the LADEE team frequently wrestled with and challenged the status quo. The philosophy of risk avoidance at all cost, typical to Class A-C missions, simply could not be executed. This innovative and simple testing solution is contextualized to NASA Class D programs and a specific risk encountered during development of the LADEE Electrical Power System (EPS). Selection of the appropriate lamp and safety concerns are discussed, with examples of test results. Combined with the vendor's panellevel data and periodic inspection, the method ensures system integrity from Integration and Test (I&T) through launch. Following launch, mission operations tools are utilized to assess system performance based on a scant amount of available data

    Electric field and aging effects of uniaxial ferroelectrics Sr x Ba1-x Nb2O6 probed by Brillouin scattering

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    This study was supported in part by the Marubun Research Promotion Foundation and JSPS KAKENHI Grant Number JP17K05030.Static and dynamic heterogeneity of disordered system is one of the current topics in materials science. In disordered ferroelectric materials with random fields, dynamic polar nanoregions (PNRs) appear at Burns temperature and freeze into nanodomain state below Curie temperature (T C). This state is very sensitive to external electric field and aging by which it gradually switches into macrodomain state. However, the role of PNRs in such states below T C is still a puzzling issue of materials science. Electric field and aging effects of uniaxial ferroelectric Sr x Ba1-x Nb2O6 (x = 0.40, SBN40) single crystals were studied using Brillouin scattering to clarify the critical nature of PNRs in domain states below T C. On field heating, a broad anomaly in longitudinal acoustic (LA) velocity at low temperature region was due to an incomplete alignment of nanodomains caused by the interaction between PNRs. A sharp anomaly near T C was attributed to the complete switching of nanodomain to macrodomain state owing to the lack of interaction among PNRs. After isothermal aging below T C, the noticeable increase of LA velocity was observed. It was unaffected by cyclic temperature measurements up to T C, and recovered to initial state outside of a narrow temperature range above and below aging temperature.Japan Society for the Promotion of Scienc

    Low-Cost, Class D Testing of Spacecraft Photovoltaic Systems Can Reduce Risk

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    The end-to-end verification of a spacecraft photovoltaic power generation system requires light! Specifically, the standard practice for doing so is the Large Area Pulsed Solar Simulation (LAPSS). A LAPSS test can characterize a photovoltaic system's efficiency via its response to rapidly applied impulses of simulated sunlight. However, a Class D program on a constrained budget and schedule may not have the resources to ship an entire satellite for a LAPSS test alone. Such was the case with the Lunar Atmospheric and Dust Environment Explorer (LADEE) program, which was also averse to the risk of hardware damage during shipment. When the Electrical Power System (EPS) team was denied a spacecraft-level LAPSS test, the lack of an end-to-end power generation test elevated to a project-level technical risk. The team pulled together very limited resources to not only eliminate the risk, but build a process to monitor the health of the system through mission operations. We discuss a process for performing a low-cost, end-to-end test of the LADEE photovoltaic system. The approach combines system-level functional test, panel-level performance results, and periodic inspection (and repair) up until launch. Following launch, mission operations tools are utilized to assess system performance based on a scant amount of data. The process starts in manufacturing at the subcontractor. The panel manufacturer provides functional test and LAPSS data on each individual panel. We apply an initial assumption that the per-panel performance is sufficient to meet the power generation requirements. The manufacturer's data is also carried as the performance allocation for each panel during EPS system modeling and initial mission operations. During integration and test, a high-power, professional theater lamp system provides simulated sunlight to each panel on the spacecraft, thereby permitting a true end-to-end system test. A passing test results in a step response to nearly full-rated current at the appropriate solar array switch in the power system. A metal-halide bulb, infrared imagers, and onboard spacecraft measurements are utilized to minimize risk of thermal damage during test. Data is provided to support test results for both passing and marginal panels. Prior to encapsulation in the launch vehicle, each panel is inspected for damage by the panel manufacturer. Cracked cells or other damage is amended on-site. Because the photovoltaic test system is inexpensive and portable, each repaired panel can be re-verified immediately. Post-launch, the photovoltaic system is again characterized for per-panel deviations from the manufacturer's performance test. This proved especially tricky as the LADEE spacecraft performs only one current measurement on the entire array. The algorithm for Matlab tools to assess panel performance based on spacecraft attitude is discussed. While not as precise and comprehensive as LAPSS, the LADEE approach leverages minimal resources into an ongoing assessment program that can be applied through numerous stages of the mission. The project takes a true Class D approach in assessing the technical value of a spacecraft level performance test versus the programmatic risk of shipping the spacecraft to another facility. The resources required are a fraction of that for a LAPSS test, and is easy to repeat. Further, the test equipment can be handed down to future projects without building an on-site facility

    Complete compensation of criss-cross deflection in a negative ion accelerator by magnetic technique

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    During 2016, a joint experimental campaign was carried out by QST and Consorzio RFX on the Negative Ion Test Stand (NITS) at the QST Naka Fusion Institute, Japan, with the purpose of validating some design solutions adopted in MITICA, which is the full-scale prototype of the ITER NBI, presently under construction at Consorzio RFX, Padova, Italy. The main purpose of the campaign was to test a novel technique, for suppressing the beamlet criss-cross magnetic deflection. This new technique, involving a set of permanent magnets embedded in the Extraction Grid, named Asymmetric Deflection Compensation Magnets (ADCM), is potentially more performing and robust than the traditional electrostatic compensation methods. The results of this first campaign confirmed the effectiveness of the new magnetic configuration in reducing the criss-cross magnetic deflection. Nonetheless, contrary to expectations, a complete deflection correction was not achieved. By analyzing in detail the results, we found indications that a physical process, taking place just upstream of the plasma grid, was giving an important contribution to the final deflection of the negative ion beam. This process appears to be related to the drift of negative ions inside the plasma source, in the presence of a magnetic field transverse to the extraction direction, and results in a non-uniform ion current density extracted at the meniscus. Therefore, the numerical models adopted in the design were improved by including this previously disregarded effect, so as to obtain a much better matching with the experimental results. Based on the results of the first campaign, new permanent magnets were designed and installed on the Extraction Grid of NITS. A second QST-Consorzio RFX joint experimental campaign was then carried out in 2017, demonstrating the complete correction of the criss-cross deflection and confirming the validity of the novel magnetic configuration and of the hypothesis behind the new models. This contribution presents the results of the second joint experimental campaign on NITS along with the overall data analysis of both campaigns, and the description of the improved models. A general picture is given of the relation among magnetic field, beam energy, meniscus non-uniformity and beamlet deflection, constituting a useful database for the design of future machines

    A Comparison of Second‐Order Derivative Based Models for Time Domain Reflectometry Waveform Analysis

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    Core Ideas Two methods, AWIGF and second‐order BMO, were evaluated on long‐ and short‐probe TDR waveforms. A corner‐preserving filter was designed to improve the performance of AWIGF. With the new filter, AWIGF performance was consistent with second‐order BMO analysis. Adaptive waveform interpretation with Gaussian filtering (AWIGF) and second‐order bounded mean oscillation Z2(u,t,r) are time domain reflectometry (TDR) analysis models. The AWIGF was originally designed for relatively long‐probe (\u3e150 mm) TDR waveforms, while Z2(u,t,r) was originally designed for relatively short‐probe (\u3c50 mm) TDR waveforms. The performances of AWIGF and Z2(u,t,r) on both long and short TDR probes have not been evaluated. The main objective of this study was to evaluate theoretically and experimentally the AWIGF and Z2(u,t,r) performances on long and short TDR probes. The evaluations are performed via mathematical analysis, and measurements of long probe and short probe waveforms in CaCl2 solutions with various electrical conductivities (EC), adding Gaussian noise, and testing the stability of Z2(u,t,r) and AWIGF. A corner‐preserving filter (CPF) is proposed to improve the stability of AWIGF on short‐probe TDR waveforms. The CPF preserves the second order derivatives of the waveforms, and emphasizes the reflection positions (t2) compared to the original Gaussian filter. Both theoretical and experimental tests illustrate the consistency of Z2(u,t,r) and AWIGF. The standard deviations of relative permittivity (Δr) are \u3c5% for all noise levels. In conclusion, Z2(u,t,r) and AWIGF can provide stable analysis for long and short probe TDR waveforms. The AWIGF with CPF is capable of stably analyzing challenging short probe TDR waveforms. The original AWIGF exhibits the lowest standard deviation of Δr at a given EC, whereas AWIGF with CPF filter exhibits the lowest bias of Δr across solutions varying in EC
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