Revised Crustal Architecture of the Southeastern Carpathian Foreland from Active and Passive Seismic Data

Integration of active and passive source seismic data is employed in order to study the nature of the relationships between crustal seismicity and geologic structures in the southeastern (SE) Carpathian foreland of Romania and the possible connection with the Vrancea Seismogenic Zone (VSZ) of intermediatedepth seismicity, one of the most active earthquakeprone areas in Europe. Crustal epicenters and focal mechanisms are correlated with four deep industry seismic profiles, the reprocessed Danube and Carpathian Integrated Action on Process in the Lithosphere and Neotectonics (DACIA PLAN) profile and the Deep Reflection Acquisition Constraining Unusual Lithospheric Activity II and III (DRACULA) profiles in order to understand the link between neotectonic foreland deformation and Vrancea mantle seismicity. Projection of crustal foreland hypocenters onto deep seismic profiles identifies several active crustal faults in the SE Carpathian foreland and suggests a mechanical coupling between the mantle located VSZ and the overlying foreland crust. The coupled associated deformation appears to take place on the Trotus Fault, the Sinaia Fault, and the newly detected Ialomita Fault. Seismic reflection imaging reveals the absence of west dipping reflectors in the crystalline crust and a slightly east dipping to horizontal Moho in the proximity of the Vrancea area. These findings argue against previously purported mechanisms to generate mantle seismicity in the VSZ including oceanic lithosphere subduction in place and oceanic slab break off, furthermore suggesting that the Vrancea seismogenic body is undetached from the overlying crust in the foreland

Role of a Phase: Change Moho in Stabilization and Preservation of the Southern Uralide Orogen, Russia

Geophysical (URSEIS experiment) and geological data from the Southern Uralides of central Russia provide the basis for a geodynamic model involving eclogitization of the Uralian crustal root in Late Triassic to Early Jurassic time as a mechanism for stabilization and preservation of this Paleozoic orogen. The crustal structure of the orogen implies eastward subduction of the East European continental crust, and balanced restoration implies a significant volume of crust (comprised of ~70% European crust, and ~30% accreted terranes) was carried to sub-Moho depths of up to 70 km. The lack of a clearly defined near-vertical incidence reflection Moho corroborated by coincident wide-angle reflection data suggest that the Moho is a sub-horizontal gradational boundary at ~50--53 km depth beneath the axis of the Southern Uralides. Previous modeling of a subdued (-50 mgal) regional Bouguer gravity minimum across the orogen suggests a subsurface load that is interpreted here as substantiation for a metamorphic phasechange of the lower crust to mantle-like eclogite facies rocks. Timing of eclogitization appears to be constrained by (1) superposition of a nearly flat Moho across the Paleozoic Uralian orogenic fabric, and (2) zircon and apatite fission-track minimum ages of 180--200 Ma, marking an upper age limit to cooling of rocks exposed at the surface, and, implicitly, to significant uplift and erosion in the Southern Uralides. The proposed eclogitization of the Southern Uralian root zone may have led to an isostatically balanced system with subdued topography, and thereby presumably served to stabilize and preserve the orogenic structure

Spectroscopy of Quasar Candidates from SDSS Commissioning Data

The Sloan Digital Sky Survey has obtained images in five broad-band colors for several hundred square degrees. We present color-color diagrams for stellar objects, and demonstrate that quasars are easily distinguished from stars by their distinctive colors. Follow-up spectroscopy in less than ten nights of telescope time has yielded 22 new quasars, 9 of them at $z> 3.65$, and one with $z = 4.75$, the second highest-redshift quasar yet known. Roughly 80% of the high-redshift quasar candidates selected by color indeed turn out to be high-redshift quasars.Comment: 4 pages, 3 figures, to appear in the proceedings of "After the Dark Ages: When Galaxies were Young (the Universe at 2<z<5)", 9th Annual October Astrophysics Conference in Marylan

New discoveries at Woolsey Mound, MC118, northern Gulf of Mexico

Woolsey Mound, a 1km-diameter carbonate-gas hydrate complex in the northern Gulf of Mexico, is the site of the Gulf’s only seafloor monitoring station-observatory in its only research reserve, Mississippi Canyon 118. Active venting, outcropping hydrate, and a thriving chemosynthetic community recommend the site for study. Since 2005, the Gulf of Mexico Hydrates Research Consortium has been conducting multidisciplinary studies to 1. Characterize the site, 2. Establish a facility for real-time monitoring-observing of gas hydrates in a natural setting, 3. Study the effects of gas hydrates on seafloor stability, 4. Establish fluid migration routes and estimates of fluid-flux at the site, 5. Establish the interrelationships between the organisms at the vent site and the association-dissociation of hydrates. A variety of novel geological, geophysical, geochemical and biological studies has been designed and conducted, some in survey mode, others in monitoring mode. Geophysical studies involving merging multiple seismic data acquisition systems accompanied by the application of custom processing techniques verify communication of surface features with deep structures. Supporting geological data derive from innovative recovery techniques. Geochemical sensors, used experimentally in survey mode, including aboard an AUV, double as monitoring devices. A suite of pore-fluid sampling devices has returned data that capture change at the site in daily increments; using only noise as an energy source, hydrophones have returned daily fluctuations in physical properties. Ever-expanding capabilities of a custom-ROV have been determined by research needs. Processing of new as well as conventional data via unconventional means has resulted in the discovery of new features…..vents, faults, benthic fauna…..and modification of others including pockmarks, hydrate outcrops, vent activity, and water-column chemical plumes. Though real-time monitoring awaits communications and power link to land, periodic data-collection reveals a carbonate-hydrate mound, part of an immensely complex hydrocarbon system

Simulation of carbon dioxide mineralization and its effect on fault leakage rates in the South Georgia rift basin, southeastern U.S.

Over the past few decades, measured levels of atmospheric carbon dioxide have substantially increased. One of the ways to limit the adverse impacts of increased carbon dioxide concentrations is to capture and store it inside Earth's subsurface, a process known as CO2 sequestration. The success of this method is critically dependent on the ability to confine injected CO2 for up to thousands of years. Establishing effective maintenance of sealing systems of reservoirs is of importance to prevent CO2 leakage. In addition, understanding the nature and rate of potential CO2 leakage related to this injection process is essential to evaluating seal effectiveness and ultimately mitigating global warming.In this study, we evaluated the impact of common chemical reactions between CO2 and subsurface materials in situ as well as the relationship between CO2 plume distribution and the CO2 leakage within the seal zone that cause mineralization. Using subsurface seismic data and well log information, a three-dimensional model consisting of a reservoir and seal zones was created and evaluated for the South Georgia Rift (SGR) basin in the southeastern U.S. The Computer Modeling Group (CMG, 2017), was used to model the effect of CO2 mineralization on the optimal values of fault permeability permeabilitydue to fluid substitution between the formation water and CO2. The model simulated the chemical reactions between carbon dioxide and mafic minerals to produce stable minerals of carbonate rock that form in the fault. Preliminary results show that CO2 migration can be controlled effectively for fault permeability values between 0.1-1 mD. Within this range, mineralization effectively reduced CO2 leakage within the seal zone.Peer reviewedGeolog

Ligand Migration and Cavities within Scapharca Dimeric HbI: Studies by Time-Resolved Crystallo- graphy, Xe Binding, and Computational Analysis

SummaryAs in many other hemoglobins, no direct route for migration of ligands between solvent and active site is evident from crystal structures of Scapharca inaequivalvis dimeric HbI. Xenon (Xe) and organic halide binding experiments, along with computational analysis presented here, reveal protein cavities as potential ligand migration routes. Time-resolved crystallographic experiments show that photodissociated carbon monoxide (CO) docks within 5 ns at the distal pocket B site and at more remote Xe4 and Xe2 cavities. CO rebinding is not affected by the presence of dichloroethane within the major Xe4 protein cavity, demonstrating that this cavity is not on the major exit pathway. The crystal lattice has a substantial influence on ligand migration, suggesting that significant conformational rearrangements may be required for ligand exit. Taken together, these results are consistent with a distal histidine gate as one important ligand entry and exit route, despite its participation in the dimeric interface

Approaches for advancing scientific understanding of macrosystems

The emergence of macrosystems ecology (MSE), which focuses on regional- to continental-scale ecological patterns and processes, builds upon a history of long-term and broad-scale studies in ecology. Scientists face the difficulty of integrating the many elements that make up macrosystems, which consist of hierarchical processes at interacting spatial and temporal scales. Researchers must also identify the most relevant scales and variables to be considered, the required data resources, and the appropriate study design to provide the proper inferences. The large volumes of multi-thematic data often associated with macrosystem studies typically require validation, standardization, and assimilation. Finally, analytical approaches need to describe how cross-scale and hierarchical dynamics and interactions relate to macroscale phenomena. Here, we elaborate on some key methodological challenges of MSE research and discuss existing and novel approaches to meet them

NYU-VAGC: a galaxy catalog based on new public surveys

Here we present the New York University Value-Added Galaxy Catalog (NYU-VAGC), a catalog of local galaxies (mostly below a redshift of about 0.3) based on a set of publicly-released surveys (including the 2dFGRS, 2MASS, PSCz, FIRST, and RC3) matched to the Sloan Digital Sky Survey (SDSS) Data Release 2. Excluding areas masked by bright stars, the photometric sample covers 3514 square degrees and the spectroscopic sample covers 2627 square degrees (with about 85% completeness). Earlier, proprietary versions of this catalog have formed the basis of many SDSS investigations of the power spectrum, correlation function, and luminosity function of galaxies. We calculate and compile derived quantities (for example, K-corrections and structural parameters for galaxies). The SDSS catalog presented here is photometrically recalibrated, reducing systematic calibration errors across the sky from about 2% to about 1%. We include an explicit description of the geometry of the catalog, including all imaging and targeting information as a function of sky position. Finally, we have performed eyeball quality checks on a large number of objects in the catalog in order to flag deblending and other errors. This catalog is complementary to the SDSS Archive Servers, in that NYU-VAGC's calibration, geometrical description, and conveniently small size are specifically designed for studying galaxy properties and large-scale structure statistics using the SDSS spectroscopic catalog.Comment: accepted by AJ; full resolution version available at http://sdss.physics.nyu.edu/vagc/va_paper.ps; data files available at http://sdss.physics.nyu.edu/vagc

Five High-Redshift Quasars Discovered in Commissioning Imaging Data of the Sloan Digital Sky Survey

We report the discovery of five quasars with redshifts of 4.67 - 5.27 and z'-band magnitudes of 19.5-20.7 M_B ~ -27. All were originally selected as distant quasar candidates in optical/near-infrared photometry from the Sloan Digital Sky Survey (SDSS), and most were confirmed as probable high-redshift quasars by supplementing the SDSS data with J and K measurements. The quasars possess strong, broad Lyman-alpha emission lines, with the characteristic sharp cutoff on the blue side produced by Lyman-alpha forest absorption. Three quasars contain strong, broad absorption features, and one of them exhibits very strong N V emission. The amount of absorption produced by the Lyman-alpha forest increases toward higher redshift, and that in the z=5.27 object (D_A ~ 0.7) is consistent with a smooth extrapolation of the absorption seen in lower redshift quasars. The high luminosity of these objects relative to most other known objects at z >~ 5 makes them potentially valuable as probes of early quasar properties and of the intervening intergalactic medium.Comment: 13 pages in LaTex format, two postscirpt figures. Submitted to the Astronomical Journa