Direct Emission of I_2 Molecule and IO Radical from the Heterogeneous Reactions of Gaseous Ozone with Aqueous Potassium Iodide Solution

Recent studies indicated that gaseous halogens mediate key tropospheric chemical processes. The inclusion of halogen-ozone chemistry in atmospheric box models actually closes the ~50% gap between estimated and measured ozone losses in the marine boundary layer. The additional source of gaseous halogens is deemed to involve previously unaccounted for reactions of O_3(g) with sea surface water and marine aerosols. Here, we report that molecular iodine, I_2(g), and iodine monoxide radical, IO(g), are released ([I_2(g)] > 100[IO(g)]) during the heterogeneous reaction of gaseous ozone, O_3(g), with aqueous potassium iodide, KI(aq). It was found that (1) the amounts of I_2(g) and IO(g) produced are directly proportional to [KI(aq)] up to 5 mM and (2) IO(g) yields are independent of bulk pH between 2 and 11, whereas I_2(g) production is markedly enhanced at pH < 4. We propose that O_3(g) reacts with I− at the air/water interface to produce I_2(g) and IO(g) via HOI and IOOO− intermediates, respectively

Strategyproof matching with regional minimum and maximum quotas

This paper considers matching problems with individual/regional minimum/maximum quotas. Although such quotas are relevant in many real-world settings, there is a lack of strategyproof mechanisms that take such quotas into account. We first show that without any restrictions on the regional structure, checking the existence of a feasible matching that satisfies all quotas is NP-complete. Then, assuming that regions have a hierarchical structure (i.e., a tree), we show that checking the existence of a feasible matching can be done in time linear in the number of regions. We develop two strategyproof matching mechanisms based on the Deferred Acceptance mechanism (DA), which we call Priority List based Deferred Acceptance with Regional minimum and maximum Quotas (PLDA-RQ) and Round-robin Selection Deferred Acceptance with Regional minimum and maximum Quotas (RSDA-RQ). When regional quotas are imposed, a stable matching may no longer exist since fairness and nonwastefulness, which compose stability, are incompatible. We show that both mechanisms are fair. As a result, they are inevitably wasteful. We show that the two mechanisms satisfy different versions of nonwastefulness respectively; each is weaker than the original nonwastefulness. Moreover, we compare our mechanisms with an artificial cap mechanism via simulation experiments, which illustrate that they have a clear advantage in terms of nonwastefulness and student welfare

Numerical Simulation of Water Quality Structure in Ise Bay at Tokai Heavy Rain Using Atmosphere-Ocean-Wave-Water Quality Coupled Model

Source: ICHE Conference Archive - https://mdi-de.baw.de/icheArchiv

Analysis of Patients Visiting Niigata University Medical and Dental Hospital with Chief Complaints of Metal Allergy and/or Focal Infection in the Previous 8 Years

Dental metal allergyand dental focal infection are possible causes of dermatological diseases, but have been the subjects of few reports to date. We have been treating such patients in our special clinicfor more than 20 years.The purpose of the present study was to investigate the mouths of patients visitingour dental hospital over an 8-year period, with the aim of clarifyingwhether dental metal allergy andjor dental focal infection affects their dermatologic conditions.We surveyed all clinicalrecords of the 185 patients who visited Niigata UniversityMedicaland Dental Hospitalwith chiefcomplaints of dental metal allergysince 2002. Diagnosticsof skin diseases, periodontal records, periapical lesions, dental caries, dental metal series patch test results and Electron Probed Micro-Analysis(EPMA)data were investigated. Ninety-two(49%) patients were sufferingfrom pustulosis palmaris et plantaris and 20 (11%)patients had lichen planus. Eighty-two(49%)patients showed positive reactions on patch testing. Based on the result of patch tests, Nishowed the highest positivity rate (62%,51 patients), but on EPMA,the number of patients with Ni as an allergen was 14 (27%).On the other hand, more than 98%of patients who showed positive reactions on patch test to Pd and Au had these metals in their dental prostheses. In addition, 112 (60%)patients showed the possibilityof dental focal infections

Switching Head-Tail Funnel UNITER for Dual Referring Expression Comprehension with Fetch-and-Carry Tasks

This paper describes a domestic service robot (DSR) that fetches everyday objects and carries them to specified destinations according to free-form natural language instructions. Given an instruction such as "Move the bottle on the left side of the plate to the empty chair," the DSR is expected to identify the bottle and the chair from multiple candidates in the environment and carry the target object to the destination. Most of the existing multimodal language understanding methods are impractical in terms of computational complexity because they require inferences for all combinations of target object candidates and destination candidates. We propose Switching Head-Tail Funnel UNITER, which solves the task by predicting the target object and the destination individually using a single model. Our method is validated on a newly-built dataset consisting of object manipulation instructions and semi photo-realistic images captured in a standard Embodied AI simulator. The results show that our method outperforms the baseline method in terms of language comprehension accuracy. Furthermore, we conduct physical experiments in which a DSR delivers standardized everyday objects in a standardized domestic environment as requested by instructions with referring expressions. The experimental results show that the object grasping and placing actions are achieved with success rates of more than 90%.Comment: Accepted for presentation at IROS202

Analysis of Patients Visiting Niigata University Medical and Dental Hospital with Chief Complaints of Metal Allergy and/or Focal Infection in the Previous 8 Years

Dental metal allergy and dental focal infection are possible causes of dermatological diseases, but have been the subjects of few reports to date. We have been treating such patients in our special clinic for more than 20 years.The purpose of the present study was to investigate the mouths of patients visiting our dental hospital over an 8-year period, with the aim of clarifying whether dental metal allergy and/or dental focal infection affects their dermatologic conditions.We surveyed all clinical records of the 185 patients who visited Niigata University Medical and Dental Hospital with chief complaints of dental metal allergy since 2002. Diagnostics of skin diseases, periodontal records, periapical lesions, dental caries, dental metal series patch test results and Electron Probed Micro-Analysis (EPMA) data were investigated. Ninety-two (49%) patients were suffering from pustulosis palmaris et plantaris and 20 (11%) patients had lichen planus. Eighty-two (49%) patients showed positive reactions on patch testing. Based on the result of patch tests, Ni showed the highest positivity rate (62%, 51 patients), but on EPMA, the number of patients with Ni as an allergen was 14 (27%). On the other hand, more than 98% of patients who showed positive reactions on patch test to Pd and Au had these metals in their dental prostheses. In addition, 112 (60%) patients showed the possibility of dental focal infection

Improving Fairness and Efficiency in Matching with Distributional Constraints: An Alternative Solution for the Japanese Medical Residency Match

Regional imbalance of doctors is a serious issue in many countries. In an attempt to average the geographical distribution of doctors, the Japanese government introduced ``regional caps'' recently, restricting the total number of medical residents matched within each region. Motivated by this policy change, Kamada and Kojima (2013) proposed a mechanism called the flexible deferred acceptance mechanism (FDA) that makes every doctor weakly better off than the current system. In this paper, we further study this problem and develop an alternative mechanism that we call the priority-list based deferred acceptance mechanism (PLDA). Both mechanisms enable hospitals in the same region to fill their capacities flexibly until the regional cap is filled. FDA lets hospitals take turns to (tentatively) choose the best remaining doctor, while PLDA lets each region directly decide which doctor is (tentatively) matched with which hospital based on its priority list. We show that PLDA performs better than FDA in terms of efficiency and fairness through theoretical and computational analyses

Improving Fairness and Efficiency in Matching with Distributional Constraints: An Alternative Solution for the Japanese Medical Residency Match

Regional imbalance of doctors is a serious issue in many countries. In an attempt to average the geographical distribution of doctors, the Japanese government introduced ``regional caps'' recently, restricting the total number of medical residents matched within each region. Motivated by this policy change, Kamada and Kojima (2013) proposed a mechanism called the flexible deferred acceptance mechanism (FDA) that makes every doctor weakly better off than the current system. In this paper, we further study this problem and develop an alternative mechanism that we call the priority-list based deferred acceptance mechanism (PLDA). Both mechanisms enable hospitals in the same region to fill their capacities flexibly until the regional cap is filled. FDA lets hospitals take turns to (tentatively) choose the best remaining doctor, while PLDA lets each region directly decide which doctor is (tentatively) matched with which hospital based on its priority list. We show that PLDA performs better than FDA in terms of efficiency and fairness through theoretical and computational analyses

Analysis of Patients Visiting Niigata University Medical and Dental Hospital with Chief Complaints of Metal Allergy And/or Focal Infection in the Previous 8 Years

Dental metal allergy and dental focal infection are possible causes of dermatological diseases, but have been the subjects of few reports to date. We have been treating such patients in our special clinic for more than 20 years.The purpose of the present study was to investigate the mouths of patients visiting our dental hospital over an 8-year period, with the aim of clarifying whether dental metal allergy and/or dental focal infection affects their dermatologic conditions.We surveyed all clinical records of the 185 patients who visited Niigata University Medical and Dental Hospital with chief complaints of dental metal allergy since 2002. Diagnostics of skin diseases, periodontal records, periapical lesions, dental caries, dental metal series patch test results and Electron Probed Micro-Analysis (EPMA) data were investigated. Ninety-two (49%) patients were suffering from pustulosis palmaris et plantaris and 20 (11%) patients had lichen planus. Eighty-two (49%) patients showed positive reactions on patch testing. Based on the result of patch tests, Ni showed the highest positivity rate (62%, 51 patients), but on EPMA, the number of patients with Ni as an allergen was 14 (27%). On the other hand, more than 98% of patients who showed positive reactions on patch test to Pd and Au had these metals in their dental prostheses. In addition, 112 (60%) patients showed the possibility of dental focal infection