Aromatic nitrations by mixed acid. Slow liquid-liquid reaction regime

Aromatic nitrations by mixed acid have been selected as a specific case of a heterogeneous liquid-liquid reaction. An extensive experimental programme has been followed using adiabatic and heat-flow calorimetry and pilot reactor experiments, supported by chemical analysis. A series of nitration experiments has been carried out to study the influences of different initial and operating conditions such as temperature, stirring speed and sulphuric acid concentration. In parallel, a mathematical model to predict the overall conversion rate has been developed. In this paper the mathematical modelling and the implementation and experimental validation for benzene, toluene and chlorobenzene mononitration in the kinetic control regime (slow liquid-liquid reaction) are presented and discussed

Magnetic properties of the ternary oxide glasses, Li2O-B2 O3-Fe2O3 from 57Fe Mössbauer spectroscopy

57Fe Mössbauer spectroscopy has been combined with bulk magnetic measurements to determine the valence state and coordination of iron as well as the magnetic properties of the ternary oxide glasses, Li2O-B 2O3-Fe 2O3. In all investigated glasses (≤ 8.4 at % Fe), the Fe3+ ions coexist in tetrahedral and octahedral coordinations ; the presence of Fe2+ ions ( < 15 %), which is observed in some glasses, is related to preparation conditions. The magnetic properties of the glasses are governed by the iron content. At low iron concentration (< 3 at %), isolated Fe3+ ions coexist with antiferromagnetic dimers and trimers. At large iron content (3.8 to 8.4 at %) the glasses undergo a mictomagnetic transition to a speromagnetic ordered state. The freezing temperature (Tf), which is frequency dependent, is found to follow a Fulcher law in one sample (5.8 at % Fe) investigated in detail

INTERACTIONS AND PRECIPITATIONS IN DILUTE TERNARY Fe Sb M ALLOYS (M = Ti, V, Cr, Mn, Co, AND Ni)

No abstract availabl

57Fe ABSORPTION AND EMISSION SPECTROSCOPY IN SOME COBALT ACETYLACETONATE COMPLEXES [Co (acac)3, Co (acac)2, Co (acac)2·2H2O]

No abstract availabl

PRECONCENTRATION OF COPPER FROM DIFFERENT SAMPLES BY DISPERSIVE LIQUID-LIQUID MICROEXTRACTION

Sample preparation is a critical step of any analytical protocol. Nowadays the goals to be reached are the best results, in the shortest time, with minimal contamination, low reagent consumption and generation of minimal waste. Dispersive liquid-liquid microextraction is a miniaturized sample preparation procedure inside Green Chemistry because the low volume of dissolvent employed. All parameters that influence on the preconcentration of copper have been optimized. The detection limit was 7.9 μg L-1. The proposed method was successfully applied to the preconcentration and determination of copper in food, vegetation, and water samples and in two standard reference materials

A synchrotron jet from a post-asymptotic giant branch star

The evolution of low- and intermediate-initial-mass stars beyond the asymptotic giant branch (AGB) remains poorly understood. High-velocity outflows launched shortly after the AGB phase are thought to be the primary shaping mechanism of bipolar and multipolar planetary nebulae. However, little is known about the launching and driving mechanism for these jets, whose momentum and energy often far exceed the energy that can be provided by radiation pressure alone. Here, we report on the direct evidence of a magnetically collimated jet shaping the bipolar morphology of the circumstellar envelope of a post-AGB star. We present radio continuum observations of the post-AGB star IRAS 15445-5449 (OH 326.5-0.4) which has water masers tracing a fast bipolar outflow. Our observations confirm the earlier observed steep negative spectral index of the spectral energy distribution (SED) above similar to 3 GHz, and resolve, for the first time, the emission to originate from a radio jet, proving the existence of such jets around a post-AGB star. The SED is consistent with a synchrotron jet embedded in a sheath of thermal electrons. We find a close correspondence between the extent and direction of the synchrotron jet and the bipolar shape of the object observed at other wavelengths, suggesting that the jet is responsible for the source morphology. The jet is collimated by a magnetic field of the order of mG at almost 7000 au from the central star. We recover observations from the Australia Telescope Compact Array archive that indicate that the emission measure of the thermal component has increased by a factor of 3 between 1998 and 2005 after which it has remained constant. The short time-scale evolution of the radio emission suggests a short lifetime for the jet. The observations of a synchrotron jet from a post-AGB star with characteristics similar to those from protostars and young stellar objects, for instance, suggest that magnetic launching and collimation is a common feature of astrophysical jets

BINCOR: An r package for estimating the correlation between two unevenly spaced time series

This paper presents a computational program named BINCOR (BINned CORrelation) for estimating the correlation between two unevenly spaced time series. This program is also applicable to the situation of two evenly spaced time series not on the same time grid. BINCOR is based on a novel estimation approach proposed by Mudelsee (2010) for estimating the correlation between two climate time series with different timescales. The idea is that autocorrelation (e.g. an AR1 process) means that memory enables values obtained on different time points to be correlated. Binned correlation is performed by resampling the time series under study into time bins on a regular grid, assigning the mean values of the variable under scrutiny within those bins. We present two examples of our BINCOR package with real data: instrumental and paleoclimatic time series. In both applications BINCOR works properly in detecting well-established relationships between the climate records compared. © Technische Universitaet Wien