Luminescent solar concentrators for building integrated photovoltaics: opportunities and challenges

This review examines the application of luminescent solar concentrators (LSCs) for building integrated photovoltaics (BIPV), both in terms of opaque façade elements and as semi-transparent windows. Many luminophores have been developed for LSC applications, and their efficiencies examined in lab-scale (<25 cm$^2$) devices. This analytical review illustrates, using ray-tracing simulations, the technical challenges to maintaining efficiency when scaling these energy conversion devices to pilot- (1000 cm$^2$) and commercial-scale (100 000 cm$^2$) modules. Based on these considerations, ambitious but feasible target efficiencies for LSCs based on ideal quantum dot (QD) luminophores are suggested as follows – for opaque and semi-transparent (50% average visible transmission), respectively: (i) 11.0% and 5.5% for lab-scale devices; (ii) 10.0% and 5.0% for pilot-scale modules; and (iii) 9.0% and 4.5% for commercial-scale modules. It is worth noting though, that the QD design requirements – particularly with regard to the overlap integral between the absorption and emission spectrum – become very critical as the LSC area increases. Whereas it is difficult to see opaque LSCs successfully competing against standard flat-plate photovoltaic modules for building integration, the application of semi-transparent LSCs as power-generating window elements has potential. Therefore, an economic analysis of the inclusion of LSCs into commercial glazing elements is presented and the potential for novel technologies – such as down-conversion (quantum-cutting) and controlling the direction of emitted light – to move this technology towards application is also discussed

Stability of a bi-layer free film: simultaneous or individual rupture events?

We consider the stability of a long free film of liquid composed of two immiscible layers of differing viscosities, where each layer experiences a van der Waals force between its interfaces. We analyse the different ways the system can exhibit interfacial instability when the liquid layers are sufficiently thin. For an excess of surfactant on one gas–liquid interface the coupling between the layers is relatively weak and the instability manifests as temporally separated rupture events in each layer. Conversely, in the absence of surfactant the coupling between the layers is much stronger and the instability manifests as rupture of both layers simultaneously. These features are consistent with recent experimental observations

Climatology of nocturnal rainfall for Northeast Kansas, 1950–2012

Nighttime rainfall has long been thought of as an important component to the central Great Plains hydroclimate during the wettest three-month period known as the “late spring - early summer precipitation maximum” from May–July (MJJ), though the climatological characteristics in Kansas are not very well documented in the literature. The nighttime rainfall characteristics are examined based on hourly precipitation data for Topeka, KS and other Kansas stations for a 63-year period from 1950–2012 for May–July. Nighttime rainfall is a major contributor to the overall moisture budget in the Great Plains, contributing over 50% of the overall rainfall total for the three-month period, with an increase in the percentage from May to July. Most nocturnal rainfall events initiate around the local midnight hour, with earlier start times in May compared to June and July. The greatest hourly precipitation tends to occur around the same time, with a gradual step down into the mid-morning hours. Geographically, areas in the eastern portion of the state receive more nighttime rainfall on average for all three months than areas to the west

The Marangoni flow of soluble amphiphiles

Surfactant distribution heterogeneities at a fluid/fluid interface trigger the Marangoni effect, i.e. a bulk flow due to a surface tension gradient. The influence of surfactant solubility in the bulk on these flows remains incompletely characterized. Here we study Marangoni flows sustained by injection of hydrosoluble surfactants at the air/water interface. We show that the flow extent increases with a decrease of the critical micelle concentration, i.e. the concentration at which these surfactants self-assemble in water. We document the universality of the surface velocity field and predict scaling laws based on hydrodynamics and surfactant physicochemistry that capture the flow features.Comment: 5 pages, 4 figures, submitte

Effect of decorrelation on 3-D grating detection with static and dynamic random-dot stereograms

Three experiments examined the effects of image decorrelation on the stereoscopic detection of sinusoidal depth gratings in static anddynamic random-dot stereograms (RDS). Detection was found to tolerate greater levels of image decorrelation as: (i) density increasedfrom 23 to 676 dots/deg2; (ii) spatial frequency decreased from 0.88 to 0.22 cpd; (iii) amplitude increased above 0.5 arcmin; and (iv) dotlifetime decreased from 1.6 s (static RDS) to 80 ms (dynamic RDS). In each case, the specific pattern of tolerance to decorrelation couldbe explained by its consequences for image sampling, filtering, and the influence of depth noise

Effect of decorrelation on 3-D grating detection with static and dynamic random-dot stereograms

Three experiments examined the effects of image decorrelation on the stereoscopic detection of sinusoidal depth gratings in static anddynamic random-dot stereograms (RDS). Detection was found to tolerate greater levels of image decorrelation as: (i) density increasedfrom 23 to 676 dots/deg2; (ii) spatial frequency decreased from 0.88 to 0.22 cpd; (iii) amplitude increased above 0.5 arcmin; and (iv) dotlifetime decreased from 1.6 s (static RDS) to 80 ms (dynamic RDS). In each case, the specific pattern of tolerance to decorrelation couldbe explained by its consequences for image sampling, filtering, and the influence of depth noise

Limitation of room temperature phosphorescence efficiency in metal organic frameworks due to triplet-triplet annihilation

The effect of triplet-triplet annihilation (TTA) on the room-temperature phosphorescence (RTP) in metal-organic frameworks (MOFs) is studied in benchmark RTP MOFs based on Zn metal centers and isophthalic or terephthalic acid linkers (ZnIPA and ZnTPA). The ratio of RTP to singlet fluorescence is observed to decrease with increasing excitation power density. Explicitly, in ZnIPA the ratio of the RTP to fluorescence is 0.58 at 1.04 mW cm(−2), but only 0.42 at (the still modest) 52.6 mW cm(−2). The decrease in ratio is due to the reduction of RTP efficiency at higher excitation due to TTA. The density of triplet states increases at higher excitation power densities, allowing triplets to diffuse far enough during their long lifetime to meet another triplet and annihilate. On the other hand, the shorter-lived singlet species can never meet an annihilate. Therefore, the singlet fluorescence scales linearly with excitation power density whereas the RTP scales sub-linearly. Equivalently, the efficiency of fluorescence is unaffected by excitation power density but the efficiency of RTP is significantly reduced at higher excitation power density due to TTA. Interestingly, in time-resolved measurements, the fraction of fast decay increases but the lifetime of long tail of the RTP remains unaffected by excitation power density. This may be due to the confinement of triplets to individual grains, leading decay to be faster until there is only one triplet per grain left. Subsequently, the remaining “lone triplets” decay with the unchanging rate expressed by the long tail. These results increase the understanding of RTP in MOFs by explicitly showing the importance of TTA in determining the (excitation power density dependent) efficiency of RTP. Also, for applications in optical sensing, these results suggest that a method based on long tail lifetime of the RTP is preferable to a ratiometric approach as the former will not be affected by variation in excitation power density whereas the latter will be

Dual-color dynamic anti-counterfeiting labels with persistent emission after visible excitation allowing smartphone authentication

A significant impediment to the deployment of anti-counterfeiting technologies is the reliance on specialized hardware. Here, anti-counterfeiting labels are developed that are both excited and detected using a smartphone. The persistent luminescence pattern and color changes on the timescale of hundreds of milliseconds to seconds. The labels can be authenticated by comparing still images from the red and green channels of video acquired at known times after flashlight excitation against expected reference patterns. The labels are based on a green-emitting SrAl(2)O(4): Eu(2+),Dy(3+) (SAED), and red-emitting CaS:Eu(2+) phosphors whose lifetimes are varied: (i) for SAED from 0.5 to 11.7 s by annealing the commercial material in air; and (ii) CaS:Eu(2+) from 0.1 to 0.6 s by varying the dopant concentration. Examples of anti-counterfeiting labels exhibiting changing emission patterns and colors on a seven-segment display, barcode, and emoji are demonstrated. These results demonstrate that phosphors with visible absorption and tunable persistent luminescence lifetimes on the order of hundreds of milliseconds to seconds are attractive for anti-counterfeiting applications as they allow authentication to be performed using only a smartphone. Further development should allow richer color shifts and enhancement of security by embedding further covert anti-counterfeiting features

The California-Kepler Survey. III. A Gap in the Radius Distribution of Small Planets

The size of a planet is an observable property directly connected to the physics of its formation and evolution. We used precise radius measurements from the California-Kepler Survey (CKS) to study the size distribution of 2025 $\textit{Kepler}$ planets in fine detail. We detect a factor of $\geq$2 deficit in the occurrence rate distribution at 1.5-2.0 R$_{\oplus}$. This gap splits the population of close-in ($P$ < 100 d) small planets into two size regimes: R$_P$ < 1.5 R$_{\oplus}$ and R$_P$ = 2.0-3.0 R$_{\oplus}$, with few planets in between. Planets in these two regimes have nearly the same intrinsic frequency based on occurrence measurements that account for planet detection efficiencies. The paucity of planets between 1.5 and 2.0 R$_{\oplus}$ supports the emerging picture that close-in planets smaller than Neptune are composed of rocky cores measuring 1.5 R$_{\oplus}$ or smaller with varying amounts of low-density gas that determine their total sizes.Comment: Paper III in the California-Kepler Survey series, accepted to the Astronomical Journa