Hyperfine transitions of 13CN from pre-protostellar sources

Recent quantum mechanical calculations of rate coefficients for collisional transfer of population between the hyperfine states of 13CN enable their population densities to be determined. We have computed the relative populations of the hyperfine states of the N = 0, 1, 2 rotational states for kinetic temperatures 5 $\le$ T $\le$ 20 K and molecular hydrogen densities 1 $\le$ n(H2) $\le$10 10 cm --3. Spontaneous and induced radiative transitions were taken into account. Our calculations show that, if the lines are optically thin, the populations of the hyperfine states, F, within a given rotational manifold are proportional to their statistical weights, (2F + 1) -- i.e. in local thermodynamic equilibrium -- over the entire range of densities. We have re-analysed IRAM 30 m telescope observations of 13CN hyperfine transitions (N = 1 $\rightarrow$ 0) in four starless cores. A comparison of these observations with our calculations confirms that the hyperfine states are statistically populated in these sources.Comment: MNRAS, Oxford University press, 2015, http://mnras.oxfordjournals.org/content/452/1/19.full?keytype=ref\&ijkey=CCx468pl8lXgoXx. \<10.1093/mnras/stv1322\&gt

Intermittency of interstellar turbulence: extreme velocity-shears and CO emission on milliparsec scale

The condensation of diffuse gas into molecular clouds occurs at a rate driven largely by turbulent dissipation. This process still has to be caught in action and characterized. A mosaic of 13 fields was observed in the CO(1-0) line with the IRAM-PdB interferometer in the translucent environment of two low-mass dense cores. The large size of the mosaic compared to the resolution (4 arcsec) is unprecedented in the study of the small-scale structure of diffuse molecular gas. Eight weak and elongated structures of thicknesses as small as 3 mpc (600 AU) and lengths up to 70mpc are found. These are not filaments because once merged with short-spacing data, they appear as the sharp edges of larger-scale structures. Six out of eight form quasi-parallel pairs at different velocities and different position angles. This cannot be the result of chance alignment. The velocity-shears estimated for the three pairs include the highest ever measured far from star forming regions (780 km/s/pc). Because the large scale structures have sharp edges, with little or no overlap, they have to be thin CO-layers. Their edges mark a sharp transition between a CO-rich component and a gas undetected in the CO line because of its low CO abundance, presumably the cold neutral medium. We propose that these sharp edges are the first directly-detected manifestations of the intermittency of interstellar turbulence. The large velocity-shears reveal an intense straining field, responsible for a local dissipation rate several orders of magnitude above average, possibly at the origin of the thin CO-layers.Comment: 16 pages, 11 figures, Accepted for publication in Astronomy and Astrophysic

The 15N-enrichment in dark clouds and Solar System objects

The line intensities of the fundamental rotational transitions of H13CN and HC15N were observed towards two prestellar cores, L183 and L1544, and lead to molecular isotopic ratios 140 6 14N/15N 6 250 and 140 6 14N/15N 6 360, respectively. The range of values reflect genuine spatial variations within the cores. A comprehensive analysis of the available measurements of the nitrogen isotopic ratio in prestellar cores show that molecules carrying the nitrile functional group appear to be systematically 15N-enriched com- pared to those carrying the amine functional group. A chemical origin for the differential 15N-enhance- ment between nitrile- and amine-bearing interstellar molecules is proposed. This sheds new light on several observations of Solar System objects: (i) the similar N isotopic fractionation in Jupiter's NH3 and solar wind N+; (ii) the 15N-enrichments in cometary HCN and CN (that might represent a direct inter- stellar inheritance); and (iii) 15N-enrichments observed in organics in primitive cosmomaterials. The large variations in the isotopic composition of N-bearing molecules in Solar System objects might then simply reflect the different interstellar N reservoirs from which they are originating

Intermittency of interstellar turbulence: Parsec-scale coherent structure of intense velocity-shear

Guided by the duality of turbulence (random versus coherent we seek coherent structures in the turbulent velocity field of molecular clouds, anticipating their importance in cloud evolution. We analyse a large map (40' by 20') obtained with the HERA multibeam receiver (IRAM-30m telescope) in a high latitude cloud of the Polaris Flare at an unprecedented spatial (11") and spectral (0.05 km/s) resolutions in the 12CO(2-1) line. We find that two parsec-scale components of velocities differing by ~2 km/s, share a narrow interface ($<0.15$ pc) that appears as an elongated structure of intense velocity-shear, ~15 to 30 km/s/pc. The locus of the extrema of line--centroid-velocity increments (E-CVI) in that field follows this intense-shear structure as well as that of the 12CO(2-1) high-velocity line wings. The tiny spatial overlap in projection of the two parsec-scale components implies that they are sheets of CO emission and that discontinuities in the gas properties (CO enrichment and/or increase of gas density) occur at the position of the intense velocity shear. These results disclose spatial and kinematic coherence between scales as small as 0.03 pc and parsec scales. They confirm that the departure from Gaussianity of the probability density functions of E-CVIs is a powerful statistical tracer of the intermittency of turbulence. They disclose a link between large scale turbulence, its intermittent dissipation rate and low-mass dense core formation

Dissipative structures of diffuse molecular gas: I - Broad HCO+^+(1-0) emission

Results: We report the detection of broad HCO+(1-0) lines (10 mK < T < 0.5 K). The interpretation of 10 of the HCO+ velocity components is conducted in conjunction with that of the associated optically thin 13CO emission. The derived HCO+ column densities span a broad range, $10^{11}< N(HCO+)/\Delta v <4 \times 10^{12} \rm cm^2/(km/s^{-1}$, and the inferred HCO+ abundances, $2 \times 10^{-10}<X(HCO+) < 10^{-8}$, are more than one order of magnitude above those produced by steady-state chemistry in gas weakly shielded from UV photons, even at large densities. We compare our results with the predictions of non-equilibrium chemistry, swiftly triggered in bursts of turbulence dissipation and followed by a slow thermal and chemical relaxation phase, assumed isobaric. The set of values derived from the observations, i.e. large HCO+ abundances, temperatures in the range of 100--200 K and densities in the range 100--1000 cm3, unambiguously belongs to the relaxation phase. The kinematic properties of the gas suggest in turn that the observed HCO+ line emission results from a space-time average in the beam of the whole cycle followed by the gas and that the chemical enrichment is made at the expense of the non-thermal energy. Last, we show that the "warm chemistry" signature (i.e large abundances of HCO+, CH+, H20 and OH) acquired by the gas within a few hundred years, the duration of the impulsive chemical enrichment, is kept over more than thousand years. During the relaxation phase, the \wat/OH abundance ratio stays close to the value measured in diffuse gas by the SWAS satellite, while the OH/HCO+ ratio increases by more than one order of magnitude.Comment: 14 page

Small-scale dissipative structures of diffuse ISM turbulence: I- CO diagnostics

Observations of translucent molecular gas in $^{12}$CO and $^{13}$CO emission lines, at high spectral and spatial resolutions, evidence different kinds of structures at small scales: (1) optically thin $^{12}$CO emission, (2) optically thick $^{12}$CO emission, visible in $^{13}$CO(1-0), and (3) regions of largest velocity shear in the field, found from a statistical analysis. They are all elongated with high aspect ratio, preferentially aligned with the plane-of-the-sky projection of the magnetic fields. The latter structures coincide with the former, shown to trace gas warmer and more diluted than average. Combining our data to large-scale observations of poorer spatial resolution, we show that the regions of largest velocity shear remain coherent over more than a parsec. These filaments are proposed to be the sites of the intermittent dissipation of turbulence

Cosmic ray induced ionisation of a molecular cloud shocked by the W28 supernova remnant

Cosmic rays are an essential ingredient in the evolution of the interstellar medium, as they dominate the ionisation of the dense molecular gas, where stars and planets form. However, since they are efficiently scattered by the galactic magnetic fields, many questions remain open, such as where exactly they are accelerated, what is their original energy spectrum, and how they propagate into molecular clouds. In this work we present new observations and discuss in detail a method that allows us to measure the cosmic ray ionisation rate towards the molecular clouds close to the W28 supernova remnant. To perform these measurements, we use CO, HCO$^+$, and DCO$^+$ millimetre line observations and compare them with the predictions of radiative transfer and chemical models away from thermodynamical equilibrium. The CO observations allow us to constrain the density, temperature, and column density towards each observed position, while the DCO$^+$/HCO$^+$ abundance ratios provide us with constraints on the electron fraction and, consequently, on the cosmic ray ionisation rate. Towards positions located close to the supernova remnant, we find cosmic ray ionisation rates much larger ($\gtrsim100$) than those in standard galactic clouds. Conversely, towards one position situated at a larger distance, we derive a standard cosmic ray ionisation rate. Overall, these observations support the hypothesis that the $\gamma$ rays observed in the region have a hadronic origin. In addition, based on CR diffusion estimates, we find that the ionisation of the gas is likely due to $0.1 -1$ GeV cosmic rays. Finally, these observations are also in agreement with the global picture of cosmic ray diffusion, in which the low-energy tail of the cosmic ray population diffuses at smaller distances than the high-energy counterpart.Comment: Accepted to A\&

The ionization fraction gradient across the Horsehead edge: An archetype for molecular clouds

The ionization fraction plays a key role in the chemistry and dynamics of molecular clouds. We study the H13CO+, DCO+ and HOC+ line emission towards the Horsehead, from the shielded core to the UV irradiated cloud edge, i.e., the Photodissociation Region (PDR), as a template to investigate the ionization fraction gradient in molecular clouds. We analyze a PdBI map of the H13CO+ J=1-0 line, complemented with IRAM-30m H13CO+ and DCO+ higher-J line maps and new HOC+ and CO+ observations. We compare self-consistently the observed spatial distribution and line intensities with detailed depth-dependent predictions of a PDR model coupled with a nonlocal radiative transfer calculation. The chemical network includes deuterated species, 13C fractionation reactions and HCO+/HOC+ isomerization reactions. The role of neutral and charged PAHs in the cloud chemistry and ionization balance is investigated. The detection of HOC+ reactive ion towards the Horsehead PDR proves the high ionization fraction of the outer UV irradiated regions, where we derive a low [HCO+]/[HOC+]~75-200 abundance ratio. In the absence of PAHs, we reproduce the observations with gas-phase metal abundances, [Fe+Mg+...], lower than 4x10(-9) (with respect to H) and a cosmic-rays ionization rate of zeta=(5+/-3)x10(-17) s(-1). The inclusion of PAHs modifies the ionization fraction gradient and increases the required metal abundance. The ionization fraction in the Horsehead edge follows a steep gradient, with a scale length of ~0.05 pc (or ~25''), from [e-]~10(-4) (or n_e ~ 1-5 cm(-3)) in the PDR to a few times ~10(-9) in the core. PAH^- anions play a role in the charge balance of the cold and neutral gas if substantial amounts of free PAHs are present ([PAH] >10(-8)).Comment: 13 pages, 7 figures, 6 tables. Accepted for publication in A&A (english not edited

Collisional excitation of singly deuterated ammonia NH2_2D by H2_2

The availability of collisional rate coefficients with H$_2$ is a pre-requisite for interpretation of observations of molecules whose energy levels are populated under non local thermodynamical equilibrium conditions. In the current study, we present collisional rate coefficients for the NH$_2$D / para--H$_2$($J_2 = 0,2$) collisional system, for energy levels up to $J_\tau = 7_7$ ($E_u$$\sim$735 K) and for gas temperatures in the range $T = 5-300$K. The cross sections are obtained using the essentially exact close--coupling (CC) formalism at low energy and at the highest energies, we used the coupled--states (CS) approximation. For the energy levels up to $J_\tau = 4_2$ ($E_u$$\sim$215 K), the cross sections obtained through the CS formalism are scaled according to a few CC reference points. These reference points are subsequently used to estimate the accuracy of the rate coefficients for higher levels, which is mainly limited by the use of the CS formalism. Considering the current potential energy surface, the rate coefficients are thus expected to be accurate to within 5\% for the levels below $J_\tau = 4_2$, while we estimate an accuracy of 30\% for higher levels

Detection of the HC3_3NH+^+ and HCNH+^+ ions in the L1544 pre-stellar core

The L1544 pre-stellar core was observed as part of the ASAI (Astrochemical Surveys At IRAM) Large Program. We report the first detection in a pre-stellar core of the HCNH$^+$ and HC$_3$NH$^+$ ions. The high spectral resolution of the observations allows to resolve the hyperfine structure of HCNH$^+$. Local thermodynamic equilibrium analysis leads to derive a column density equal to (2.0$\pm$0.2)$\times$10$^{13}$cm$^{-2}$ for HCNH$^+$ and (1.5$\pm$0.5)$\times$10$^{11}$cm$^{-2}$ for HC$_3$NH$^+$. We also present non-LTE analysis of five transitions of HC$_3$N, three transitions of H$^{13}$CN and one transition of HN$^{13}$C, all of them linked to the chemistry of HCNH$^+$ and HC$_3$NH$^+$. We computed for HC$_3$N, HCN, and HNC a column density of (2.0$\pm$0.4)$\times$10$^{13}$cm$^{-2}$, (3.6$\pm$0.9)$\times10^{14}$cm$^{-2}$, and (3.0$\pm$1.0)$\times$10$^{14}$cm$^{-2}$, respectively. We used the gas-grain chemical code Nautilus to predict the abundances all these species across the pre-stellar core. Comparison of the observations with the model predictions suggests that the emission from HCNH$^+$ and HC$_3$NH$^+$ originates in the external layer where non-thermal desorption of other species was previously observed. The observed abundance of both ionic species ([HCNH$^+$]$\,\simeq3\times10^{-10}$ and [HC$_3$NH$^+$]$\,\simeq[1.5-3.0]\times10^{-12}$, with respect to H$_2$) cannot be reproduced at the same time by the chemical modelling, within the error bars of the observations only. We discuss the possible reasons for the discrepancy and suggest that the current chemical models are not fully accurate or complete. However, the modelled abundances are within a factor of three consistent with the observations, considering a late stage of the evolution of the pre-stellar core, compatible with previous observations.Comment: Accepted for publication in MNRAS, 13 pages, 9 figure