Phenalene-phosphazene complexes: effect of exocyclic charge densities on the cyclotriphosphazene ring system

The synthesis and properties of a new series of 1,9-diamino-substituted phenalene complexes of the cyclotriphosphazene ring system is described. One of the compounds is shown to be amphoteric, and this behavior allows an examination of the response of the phosphazene linkage to variations in exocyclic charge density at the spiro center in a plane perpendicular to the cyclotriphosphazene ring system. ^(31)P NMR spectroscopy indicates that substituent lone pairs with this orientation are not effective in long-range delocalization within the phosphazene linkage (in accord with our theoretical model of spiro delocalization). An X-ray crystal structure of one compound (7) identifies the presence of clathrated molecules of chloroform together with doubly hydrogen-bonded pairs of the phenalene-phosphazene complexes in the lattice. Crystal data for 7 (C_(13)H_8Cl_4N_5P_3•CHCl_3): monoclinic space group P2_1/c, a = 12.401 (4) Å, b = 28.404 (6) Å, c = 12.962 (3) Å, β = 91.76 (2)°, V = 4564 (2) Å^3, Z = 8, R = 0.050 for 4525 reflections

Experimental Outlook for the Pentaquark

A critical look is taken at both positive and null evidence for the $\Theta^+$ pentaquark. Potential problems with experiments will be discussed and the question of what conclusion can be drawn from both the positive and the null results is examined. First the question of existence of the $\Theta^+$ pentaquark is considered, followed by a discussion of new experiments that are either planned or in progress to answer questions about its mass, width and isospin. Finally, indirect evidence for the parity of the $\Theta^+$ is examined, and suggestions for experiments to measure its parity directly are given.Comment: MESON2004 conference proceedings, 10 pages, 1 figur

Photoproduction of the ω\omega meson on the proton at large momentum transfer

The differential cross section, $d\sigma/dt$ for $\omega$ meson exclusive photoproduction on the proton above the resonance region ($2.6<W<2.9$ GeV) was measured up to a momentum transfer $-t = 5$ GeV$^2$ using the CLAS detector at Jefferson Laboratory. The $\omega$ channel was identified by detecting a proton and $\pi^+$ in the final state and using the missing mass technique. While the low momentum transfer region shows the typical diffractive pattern expected from Pomeron and Reggeon exchange, at large $-t$ the differential cross section has a flat behavior. This feature can be explained by introducing quark interchange processes in addition to the QCD-inspired two-gluon exchange.Comment: 5 pages, 5 figure

The Keck/OSIRIS Nearby AGN Survey (KONA) I. The Nuclear K-band Properties of Nearby AGN

We introduce the Keck Osiris Nearby AGN survey (KONA), a new adaptive optics-assisted integral-field spectroscopic survey of Seyfert galaxies. KONA permits at ~0.1" resolution a detailed study of the nuclear kinematic structure of gas and stars in a representative sample of 40 local bona fide active galactic nucleus (AGN). KONA seeks to characterize the physical processes responsible for the coevolution of supermassive black holes and galaxies, principally inflows and outflows. With these IFU data of the nuclear regions of 40 Seyfert galaxies, the KONA survey will be able to study, for the first time, a number of key topics with meaningful statistics. In this paper we study the nuclear K-band properties of nearby AGN. We find that the luminosities of the unresolved Seyfert 1 sources at 2.1 microns are correlated with the hard X-ray luminosities, implying that the majority of the emission is non-stellar. The best-fit correlation is logLK = 0.9logL2-10 keV + 4 over 3 orders of magnitude in both K-band and X-ray luminosities. We find no strong correlation between 2.1 microns luminosity and hard X-ray luminosity for the Seyfert 2 galaxies. The spatial extent and spectral slope of the Seyfert 2 galaxies indicate the presence of nuclear star formation and attenuating material (gas and dust), which in some cases is compact and in some galaxies extended. We detect coronal-line emission in 36 galaxies and for the first time in five galaxies. Finally, we find 4/20 galaxies that are optically classified as Seyfert 2 show broad emission lines in the near-IR, and one galaxy (NGC 7465) shows evidence of a double nucleus.Comment: Accepted for publication in ApJ, 19 pages with 18 figure

A 43-Gbps Lithium Niobate Modulator Driver Module

This paper describes the realization of a 43-Gbps Lithium Niobate modulator driver module. The NRZ driver module utilizes four stages of GaAs p-HEMT MMIC amplifiers integrated with an output level detector and feedback loop to provide thermal stability and external control of the output swing. The bias and loop control circuitry are contained in the housing on a PC board external to the sealed MIC section. The integrated module (50.8 x 73.4 x 9.5 mm 3) provides 6.0 Vp-p controllable single-ended output voltage while dissipating only 4 watt