6,419 research outputs found
Volume-controlled buckling of thin elastic shells: Application to crusts formed on evaporating partially-wetted droplets
Motivated by the buckling of glassy crusts formed on evaporating droplets of
polymer and colloid solutions, we numerically model the deformation and
buckling of spherical elastic caps controlled by varying the volume between the
shell and the substrate. This volume constraint mimics the incompressibility of
the unevaporated solvent. Discontinuous buckling is found to occur for
sufficiently thin and/or large contact angle shells, and robustly takes the
form of a single circular region near the boundary that `snaps' to an inverted
shape, in contrast to externally pressurised shells. Scaling theory for shallow
shells is shown to well approximate the critical buckling volume, the
subsequent enlargement of the inverted region and the contact line force.Comment: 7 pages in J. Phys. Cond. Mat. spec; 4 figs (2 low-quality to reach
LANL's over-restrictive size limits; ask for high-detailed versions if
required
Granular Pressure and the Thickness of a Layer Jamming on a Rough Incline
Dense granular media have a compaction between the random loose and random
close packings. For these dense media the concept of a granular pressure
depending on compaction is not unanimously accepted because they are often in a
"frozen" state which prevents them to explore all their possible microstates, a
necessary condition for defining a pressure and a compressibility
unambiguously. While periodic tapping or cyclic fluidization have already being
used for that exploration, we here suggest that a succession of flowing states
with velocities slowly decreasing down to zero can also be used for that
purpose. And we propose to deduce the pressure in \emph{dense and flowing}
granular media from experiments measuring the thickness of the granular layer
that remains on a rough incline just after the flow has stopped.Comment: 10 pages, 2 figure
OBJECTIVE AND SOCIAL FACTORS AS DETERMINANTS OF TASK PERCEPTIONS AND RESPONSES: AN INTEGRATED PERSPECTIVE AND EMPIRICAL INVESTIGATION.
The purpose of this study was to test the merits of an integrated perspective derived from the job characteristics and social information processing models of task design. We conducted a complex laboratory study, manipulating objective properties of a task, social information, and changes in both. Results suggested strong support for the integrated perspective. Implications for future theory and research are discussed
Introduction to protein folding for physicists
The prediction of the three-dimensional native structure of proteins from the
knowledge of their amino acid sequence, known as the protein folding problem,
is one of the most important yet unsolved issues of modern science. Since the
conformational behaviour of flexible molecules is nothing more than a complex
physical problem, increasingly more physicists are moving into the study of
protein systems, bringing with them powerful mathematical and computational
tools, as well as the sharp intuition and deep images inherent to the physics
discipline. This work attempts to facilitate the first steps of such a
transition. In order to achieve this goal, we provide an exhaustive account of
the reasons underlying the protein folding problem enormous relevance and
summarize the present-day status of the methods aimed to solving it. We also
provide an introduction to the particular structure of these biological
heteropolymers, and we physically define the problem stating the assumptions
behind this (commonly implicit) definition. Finally, we review the 'special
flavor' of statistical mechanics that is typically used to study the
astronomically large phase spaces of macromolecules. Throughout the whole work,
much material that is found scattered in the literature has been put together
here to improve comprehension and to serve as a handy reference.Comment: 53 pages, 18 figures, the figures are at a low resolution due to
arXiv restrictions, for high-res figures, go to http://www.pabloechenique.co
Ab Initio Study of Screw Dislocations in Mo and Ta: A new picture of plasticity in bcc transition metals
We report the first ab initio density-functional study of screw
dislocations cores in the bcc transition metals Mo and Ta. Our results suggest
a new picture of bcc plasticity with symmetric and compact dislocation cores,
contrary to the presently accepted picture based on continuum and interatomic
potentials. Core energy scales in this new picture are in much better agreement
with the Peierls energy barriers to dislocation motion suggested by
experiments.Comment: 3 figures, 3 table
Hb Long Island: a hemoglobin variant with a methionyl extension at the NH2 terminus and a prolyl substitution for the normal histidyl residue 2 of the beta chain.
Inelastic transport theory from first-principles: methodology and applications for nanoscale devices
We describe a first-principles method for calculating electronic structure,
vibrational modes and frequencies, electron-phonon couplings, and inelastic
electron transport properties of an atomic-scale device bridging two metallic
contacts under nonequilibrium conditions. The method extends the
density-functional codes SIESTA and TranSIESTA that use atomic basis sets. The
inelastic conductance characteristics are calculated using the nonequilibrium
Green's function formalism, and the electron-phonon interaction is addressed
with perturbation theory up to the level of the self-consistent Born
approximation. While these calculations often are computationally demanding, we
show how they can be approximated by a simple and efficient lowest order
expansion. Our method also addresses effects of energy dissipation and local
heating of the junction via detailed calculations of the power flow. We
demonstrate the developed procedures by considering inelastic transport through
atomic gold wires of various lengths, thereby extending the results presented
in [Frederiksen et al., Phys. Rev. Lett. 93, 256601 (2004)]. To illustrate that
the method applies more generally to molecular devices, we also calculate the
inelastic current through different hydrocarbon molecules between gold
electrodes. Both for the wires and the molecules our theory is in quantitative
agreement with experiments, and characterizes the system-specific mode
selectivity and local heating.Comment: 24 pages, 17 figure
Force-extension relation of cross-linked anisotropic polymer networks
Cross-linked polymer networks with orientational order constitute a wide
class of soft materials and are relevant to biological systems (e.g., F-actin
bundles). We analytically study the nonlinear force-extension relation of an
array of parallel-aligned, strongly stretched semiflexible polymers with random
cross-links. In the strong stretching limit, the effect of the cross-links is
purely entropic, independent of the bending rigidity of the chains. Cross-links
enhance the differential stretching stiffness of the bundle. For hard
cross-links, the cross-link contribution to the force-extension relation scales
inversely proportional to the force. Its dependence on the cross-link density,
close to the gelation transition, is the same as that of the shear modulus. The
qualitative behavior is captured by a toy model of two chains with a single
cross-link in the middle.Comment: 7 pages, 4 figure
Transverse fluctuations of grafted polymers
We study the statistical mechanics of grafted polymers of arbitrary stiffness
in a two-dimensional embedding space with Monte Carlo simulations. The
probability distribution function of the free end is found to be highly
anisotropic and non-Gaussian for typical semiflexible polymers. The reduced
distribution in the transverse direction, a Gaussian in the stiff and flexible
limits, shows a double peak structure at intermediate stiffnesses. We also
explore the response to a transverse force applied at the polymer free end. We
identify F-Actin as an ideal benchmark for the effects discussed.Comment: 10 pages, 4 figures, submitted to Physical Review
Magellan: Preliminary description of Venus surface geologic units
Observations from approximately one-half of the Magellan nominal eight-month mission to map Venus are summarized. Preliminary compilation of initial geologic observations of the planet reveals a surface dominated by plains that are characterized by extensive and intensive volcanism and tectonic deformation. Four broad categories of units have been identified: plains units, linear belts, surficial units, and terrain units
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