658 research outputs found
Accurate <i>ab initio</i> ro-vibronic spectroscopy of the X<sup>2</sup>∏ CCN radical using explicitly correlated methods
Explicitly correlated CCSD(T)-F12b calculations have been carried out with systematic sequences of correlation consistent basis sets to determine accurate near-equilibrium potential energy surfaces for the X<sup>2</sup>∏ and a<sup>4</sup>Σ<sup>−</sup> electronic states of the CCN radical. After including contributions due to core correlation, scalar relativity, and higher order electron correlation effects, the latter utilizing large-scale multireference configuration interaction calculations, the resulting surfaces were employed in variational calculations of the ro-vibronic spectra. These calculations also included the use of accurate spin-orbit and dipole moment matrix elements. The resulting ro-vibronic transition energies, including the Renner-Teller sub-bands involving the bending mode, agree with the available experimental data to within 3 cm<sup>−1</sup> in all cases. Full sets of spectroscopic constants are reported using the usual second-order perturbation theory expressions. Integrated absorption intensities are given for a number of selected vibronic band origins. A computational procedure similar to that used in the determination of the potential energy functions was also utilized to predict the formation enthalpy of CCN, ΔH<sub>f</sub>(0K) = 161.7 ± 0.5 kcal/mol
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Adding the reliability on tree based topology construction algorithms for wireless sensor networks
Topology control is a technique used in wireless sensor networks to maximize energy efficiency and network lifetime. In previous literature, many tree based techniques have been proposed to save energy and increase the network lifetime. In tree based algorithms, the most promising solution is the formation of a network backbone, which serves on behalf of rest of the nodes in the network and therefore leading towards Connected Dominating Set (CDS) formulation. However, one imminent problem with all tree based solution is a compromise on network reliability. Therefore, to address reliability issues in tree based solutions, in this paper, we propose Poly3 which maintains cliques of size three in order to achieve network reliability on top of the CDS algorithm. This makes the network more robust to link removal. Our empirical and mathematical analysis reveals that Poly3 provides better reliability than algorithms of the same kind
Supplemental chromium-loaded chitosan nanoparticles affect growth, serum metabolites and intestinal histology in broilers
The goal of the present research was to evaluate the effects of chromium-loaded chitosan nanoparticles (Cr-CNPs) on production performance, viscera development, serum metabolites and intestinal histology in broilers. Two hundred (200) day-old broilers were randomly divided into five groups with five replicates (n = 8). Birds in the first group served as control and were fed a corn soybean-based diet, while the remaining four supplemented groups were offered 200, 400, 800, and 1200 μg Cr-CNPs/kg of feed, respectively, for 35 days. Weight gain, feed intake and feed conversion ratio (FCR) remained unaffected with Cr-CNP supplementation. No changes were observed in the relative weights of viscera. The relative length of the small intestine was decreased in birds supplemented with 200 and 800 μg Cr-CNPs/kg compared with the 1200 μg Cr-CNP-supplemented group and control. Serum metabolites remained unaffected with Cr-CNP supplementation except for serum HDL, which was increased. Cr-CNPs decreased the retention of chromium in the bone at higher concentrations. Jejunal villus height, villus surface area, and villus height to crypt depth ratio were increased in the 800 μg Cr-CNP-supplemented group. In conclusion, Cr-CNPs did not affect growth performance, viscera development, and most of the serum metabolites, but enhanced jejunal morphological attributes at 800 μg Cr-CNPs/kg of feed.
Keywords: blood biochemistry, health, nano-biotechnology, prebiotics, poultry, trace minera
Enteric cyst in the left posterior mediastinum mimicking a hydatid cyst on chest computed tomography scan
Abstract
Mediastinal enteric cysts are a rare occurrence among adults and are usually asymptomatic. In most cases they are an incidental finding in the right hemi-mediastinum and are associated with vertebral anomalies. We report the unusual case of a 23 year old male who had a mediastinal mass on chest X-ray as an incidental finding. Chest Computed Tomography (CT) scan revealed no vertebral anomalies and a cystic mass in the left posterior mediastinum with features similar to those of a hydatid cyst.Posterolateral thoracotomy was done and the cyst was excised. Histopathology report revealed it to be an enteric cyst
Influence of β-galacto-oligosaccharide on growth performance and components of intestinal barrier in broilers during heat stress
This study aimed to investigate the influence of β-galacto-oligosaccharides (β-GOS) on growth performance, organ development and intestinal microarchitecture of broilers during heat stress. Day-old chicks (n = 125) were divided into five groups. The control or thermoneutral zone group (TNZ) was raised under standard management until the 35th day. Four groups were exposed to cyclic heat stress (35 °C 8 h/d) from the 22nd to the 35th day. The TNZ and heat stress control (HSCT) groups were fed a corn-based diet and HS + 0.1% β-GOS; HS + 0.2% β-GOS; and HS + 0.5% β-GOS were fed a corn-based diet supplemented with β-GOS (0.1%, 0.2%, and 0.5%), respectively. Exposure to heat stress reduced feed consumption, feed efficiency and the relative weight of the liver, bursa of Fabricius, and small intestine, compared with the TNZ group. Morphometric evaluation of the small intestine revealed reduced villus surface area, villus height to crypt depth ratio (VH : CD) and intraepithelial lymphocytes (IELs) in all segments, and reduced acidic goblet cells (AGCs) in the ileum of the HSCT group compared with the TNZ group. Compared with the HSCT group, dietary β-GOS (0.2% and 0.5%) improved the feed efficiency and relative weight of the small intestine. Furthermore, dietary β-GOS (0.1%) increased villus surface area in the duodenum and IEL count in the small intestine compared with the HSCT group. Dietary β-GOS 0.5% increased villi surface area (VSA) in the jejunum and ileum, whereas the IEL count in the small intestine and acidic goblet cells (AGCs) in the jejunum and ileum were reduced compared with the HSCT group. In conclusion, dietary supplementation of β-GOS (0.2% and 0.5%) improved the growth performance and intestinal microarchitecture of broilers during heat exposure, along with partial immune stimulation. Keywords: Feed efficiency, goblet cell, intraepithelial lymphocytes, mucosal architecture, prebiotics, poultry, villus morphometr
COMPARATIVE EFFICACY OF HYPERTONIC SALINE AND NORMAL SALINE SOLUTIONS IN EXPERIMENTALLY INDUCED ENDOTOXIC SHOCK IN DOGS
This study was contemplated to determine the comparative beneficial effects of hypertonic saline solution and sterile saline solution in induced endotoxic shock in dogs. For this purpose, 12 healthy Mongrel dogs were randomly divided into two equal groups (A and B). All the animals were induced endotoxaemia by slow intravenous administration of Escherichia coli endotoxins 0111:B4. Group A was treated with normal saline solution @ 90 ml/kg BW, while group B was given hypertonic saline solution @ 4 ml/kg BW, followed by normal saline solution @ 10 ml/kg BW. Different parameters were observed for evaluation of these fluids including clinical and haematological parameters, serum electrolytes, mean arterial pressure, and blood gases at different time intervals up to 24 hours post treatments. After infusion of respective fluids, all parameters returned to baseline values in both the groups but group B showed better results than group A except bicarbonates, which better recovered in group A. Thus, it was concluded that a small-volume of hypertonic saline solution could be effectively used in reversing the endotoxaemia. Moreover, it provides a rapid and inexpensive resuscitation from endotoxic shock
Effect of maternal yeast feeding on dam performance and serum health biomarkers of Beetal goat kids
Supplementation with dietary yeast has improved digestibility and productive performance in ruminants. In this research the primary objective was to appraise the effects of dietary yeast supplementation of female goats during the transition period on milk composition and yield and on production and serum health biomarkers of their kids. Twenty-four Beetal goats (4 ± 1.2 years) were randomly assigned to three groups, which received 0, 5, and 10 grams/animal/day of live dried yeast Saccharomyces cerevisiae for 60 days (30 days pre- and post-partum). All goats were fed 500 grams of concentrate with water and green fodder ad libitum. Milk samples were collected at 7, 14, 21, and 28 days post kidding. Kids were weighed on days 0, 7, 15, 22, and 30, and blood samples were collected on days 15 and 30 for serum metabolites (glucose, urea, cholesterol, non-esterified fatty acids (NEFA), serum total proteins, albumin, globulin, albumin to globulin ratio, serum oxidant and antioxidant activity (malondialdehyde) (MDA) and catalase), and liver enzymes aspartate aminotransferase (AST) and alanine transaminase (ALT) assessment. Milk yield was significantly (P =0.02) higher during the post-partum period in yeast-fed goats. Yeast-fed goats also produced milk containing more fat (P <0.001) and protein (P <0.001) compared with control goats. Birth weight, average daily gain, and serum health biomarkers of the kids were not influenced by the treatments. In conclusion, dietary yeast supplementation resulted in increased production performance of the dams without significant impact on their offspring.Keywords: average daily gain, catalase activity, hepatic enzymes, milk production, Saccharomyces cerevisiae, transition perio
The Extraordinary X-ray Light Curve of the Classical Nova V1494 Aquilae (1999 #2) in Outburst: The Discovery of Pulsations and a "Burst"
V1494 Aql (Nova Aql 1999 No. 2) was discovered on 2 December 1999. We
obtained Chandra ACIS-I spectra on 15 April and 7 June 2000 which appear to
show only emission lines. Our third observation, on 6 August, showed that its
spectrum had evolved to that characteristic of a Super Soft X-ray Source. We
then obtained Chandra LETG+HRC-S spectra on 28 September (8 ksec) and 1 October
(17 ksec). We analyzed the X-ray light curve of our grating observations and
found both a short time scale ``burst'' and oscillations. Neither of these
phenomena have previously been seen in the light curve of a nova in outburst.
The ``burst'' was a factor of 10 rise in X-ray counts near the middle of the
second observation, and which lasted about 1000 sec; it exhibited at least two
peaks, in addition to other structure. Our time series analysis of the combined
25 ksec observation shows a peak at 2500 s which is present in independent
analyses of both the zeroth order image and the dispersed spectrum and is not
present in similar analyses of grating data for HZ 43 and Sirius B. Further
analyses of the V1494 Aql data find other periods present which implies that we
are observing non-radial g+ modes from the pulsating, rekindled white dwarf.Comment: ApJ accepte
A rapid synthesis of low-nanomolar divalent LecA inhibitors in four linear steps from d-galactose pentaacetate
Chronic infections with Pseudomonas aeruginosa are associated with
the formation of bacterial biofilms. The tetrameric P. aeruginosa lectin
LecA is a virulence factor and an anti-biofilm drug target. Increasing the
overall binding affinity by multivalent presentation of binding epitopes
can enhance the weak carbohydrate–ligand interactions. Lownanomolar divalent LecA ligands/inhibitors with up to 260-fold
valency-normalized potency boost and excellent selectivity over
human galectin-1 were synthesized from D-galactose pentaacetate
and benzaldehyde-based linkers in four linear steps
A fast ILP-based Heuristic for the robust design of Body Wireless Sensor Networks
We consider the problem of optimally designing a body wireless sensor
network, while taking into account the uncertainty of data generation of
biosensors. Since the related min-max robustness Integer Linear Programming
(ILP) problem can be difficult to solve even for state-of-the-art commercial
optimization solvers, we propose an original heuristic for its solution. The
heuristic combines deterministic and probabilistic variable fixing strategies,
guided by the information coming from strengthened linear relaxations of the
ILP robust model, and includes a very large neighborhood search for reparation
and improvement of generated solutions, formulated as an ILP problem solved
exactly. Computational tests on realistic instances show that our heuristic
finds solutions of much higher quality than a state-of-the-art solver and than
an effective benchmark heuristic.Comment: This is the authors' final version of the paper published in G.
Squillero and K. Sim (Eds.): EvoApplications 2017, Part I, LNCS 10199, pp.
1-17, 2017. DOI: 10.1007/978-3-319-55849-3\_16. The final publication is
available at Springer via http://dx.doi.org/10.1007/978-3-319-55849-3_1
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