Effectiveness of incentives offered by mobile phone app to encourage cycling: A long‐term study

Reduction of car use is one of the most effective ways to tackle congestion-related problems. Using positive incentives to stimulate bicycle use is one possibility to reduce car use. Cycling is a sustainable transport mode that uses little space and is healthy. There is evidence that positive incentives may be more effective than punishing travellers for undesirable behaviour, and the emergence of mobile applications for delivering interventions has opened up new opportunities for influencing travellers. So far, few studies have focused on exploring the effectiveness of positive incentives on long-term behavioural change. We used the SMART app to deliver positive incentives to more than 6000 travellers in the Dutch region of Twente. The app automatically tracks users and provides incentives such as challenges with rewards, feedback, and messages. This study covers the period from March 2017 to June 2018, in which more than 1000 SMART users participated in monthly challenges. We evaluated the effects of the challenges and rewards and found that the challenges did encourage cycling and reduced car use in the short term. There is also some evidence for behavioural change over a longer time period

Pore confinement effects and stabilization of carbon nitride oligomers in macroporous silica for photocatalytic hydrogen production

An ordered macroporous host (mac-SiO2) has been used to prevent aggregation of layered photocatalysts based on carbon nitride. Using typical carbon nitride synthesis conditions, cyanamide was condensed at 550 °C in the presence and absence of mac-SiO2. Condensation in the absence of mac-SiO2 results in materials with structural characteristics consistent with the carbon nitride, melon, accompanied by ca. 2 wt% carbonization. For mac-SiO2 supported materials, condensation occurs with greater carbonization (ca. 6 wt%). On addition of 3 wt% Pt cocatalyst photocatalytic hydrogen production under visible light is found to be up to 10 times greater for the supported composites. Time-resolved photoluminescence spectroscopy shows that excited state relaxation is more rapid for the mac-SiO2 supported materials suggesting faster electron-hole recombination and that supported carbon nitride does not exhibit improved charge separation. CO2 temperature programmed desorption indicates that enhanced photoactivity of supported carbon nitride is attributable to an increased surface area compared to bulk carbon nitride and an increase in the concentration of weakly basic catalytic sites, consistent with carbon nitride oligomers