Spatio-temporal tracer variability in the glacier melt end-member - How does it affect hydrograph separation results?

Geochemical and isotopic tracers were often used in mixing models to estimate glacier melt contributions to streamflow, whereas the spatio‐temporal variability in the glacier melt tracer signature and its influence on tracer‐based hydrograph separation results received less attention. We present novel tracer data from a high‐elevation catchment (17 km2, glacierized area: 34%) in the Oetztal Alps (Austria) and investigated the spatial, as well as the subdaily to monthly tracer variability of supraglacial meltwater and the temporal tracer variability of winter baseflow to infer groundwater dynamics. The streamflow tracer variability during winter baseflow conditions was small, and the glacier melt tracer variation was higher, especially at the end of the ablation period. We applied a three‐component mixing model with electrical conductivity and oxygen‐18. Hydrograph separation (groundwater, glacier melt, and rain) was performed for 6 single glacier melt‐induced days (i.e., 6 events) during the ablation period 2016 (July to September). Median fractions (±uncertainty) of groundwater, glacier melt, and rain for the events were estimated at 49±2%, 35±11%, and 16±11%, respectively. Minimum and maximum glacier melt fractions at the subdaily scale ranged between 2±5% and 76±11%, respectively. A sensitivity analysis showed that the intraseasonal glacier melt tracer variability had a marked effect on the estimated glacier melt contribution during events with large glacier melt fractions of streamflow. Intra‐daily and spatial variation of the glacier melt tracer signature played a negligible role in applying the mixing model. The results of this study (a) show the necessity to apply a multiple sampling approach in order to characterize the glacier melt end‐member and (b) reveal the importance of groundwater and rainfall–runoff dynamics in catchments with a glacial flow regime

The importance of snowmelt spatiotemporal variability for isotope-based hydrograph separation in a high-elevation catchment

Seasonal snow cover is an important temporary water storage in high-elevation regions. Especially in remote areas, the available data are often insufficient to accurately quantify snowmelt contributions to streamflow. The limited knowledge about the spatiotemporal variability of the snowmelt isotopic composition, as well as pronounced spatial variation in snowmelt rates, leads to high uncertainties in applying the isotope-based hydrograph separation method. The stable isotopic signatures of snowmelt water samples collected during two spring 2014 snowmelt events at a north- and a south-facing slope were volume weighted with snowmelt rates derived from a distributed physicsbased snow model in order to transfer the measured plotscale isotopic composition of snowmelt to the catchment scale. The observed δ$^{18}$O values and modeled snowmelt rates showed distinct inter- and intra-event variations, as well as marked differences between north- and south-facing slopes. Accounting for these differences, two-component isotopic hydrograph separation revealed snowmelt contributions to streamflow of 35±3 and 75±14% for the early and peak melt season, respectively. These values differed from those determined by formerly used weighting methods (e.g., using observed plot-scale melt rates) or considering either the north- or south-facing slope by up to 5 and 15 %, respectively

Revisiting Forest Effects on Winter Air Temperature and Wind Spee : New Open Data and Transfer Functions

The diurnal cycle of both air temperature and wind speed is characterized by considerable differences, when comparing open site conditions to forests. In the course of this article, a new two-hourly, open-source dataset, covering a high spatial and temporal variability, is presented and analyzed. It contains air temperature measurements (128 station pairs (open/forest); six winter seasons; six study sites), wind speed measurements (64 station pairs; three winter seasons, four study sites) and related metadata in central Europe. Daily cycles of air temperature and wind speed, as well as further dependencies of the effective Leaf Area Index (effective LAI), the exposure in the context of forest effects, and the distance to the forest edge, are illustrated in this paper. The forest effects on air temperature can be seen particularly with increasing canopy density, in southern exposures, and in the late winter season, while wind speed depends on multiple factors such as effective LAI or the distance to the forest edge. New transfer functions, developed using linear and non-linear regression analysis, in a leave-one-out cross-validation, improve certain efficiency criteria (NSME; r2; RMSE; MAE) compared to existing transfer functions. The dataset enables multiple purposes and capabilities due to its diversity and sample size

Modelling forest snow processes with a new version of WaSiM

We present a new model extension for the Water balance Simulation Model, WaSiM, which features (i) snow interception and (ii) modified meteorological conditions under coniferous forest canopies, complementing recently developed model extensions for particular mountain hydrological processes. Two study areas in Austria and Germany are considered in this study. To supplement and constrain the modelling experiments with on-site observations, a network of terrestrial time-lapse cameras was set up in one of these catchments. The spatiotemporal patterns of snow depth inside the forest and at the adjacent open field sites were recorded along with snow interception dynamics. Comparison of observed and modelled snow cover and canopy interception indicates that the new version of WaSiM reliably reconstructs the variability of snow accumulation for both the forest and the open field. The Nash-Sutcliffe efficiency computed for selected runoff events in spring increases from −0.68 to 0.71 and 0.21 to 0.87, respectively

Risk of groundwater contamination widely underestimated because of fast flow into aquifers

International audienceGroundwater pollution threatens human and ecosystem health in many regions around the globe. Fast flow to the groundwater through focused recharge is known to transmit short-lived pollutants into carbonate aquifers, endangering the quality of groundwaters where one quarter of the world’s population lives. However, the large-scale impact of such focused recharge on groundwater quality remains poorly understood. Here, we apply a continental-scale model to quantify the risk of groundwater contamination by degradable pollutants through focused recharge in the carbonate rock regions of Europe, North Africa, and the Middle East. We show that focused recharge is the primary reason for widespread rapid transport of contaminants to the groundwater. Where it occurs, the concentration of pollutants in groundwater recharge that have not yet degraded increases from <1% to around 20 to 50% of their concentrations during infiltration. Assuming realistic application rates, our simulations show that degradable pollutants like glyphosate can exceed their permissible concentrations by 3 to 19 times when reaching the groundwater. Our results are supported by independent estimates of young water fractions at 78 carbonate rock springs over Europe and a dataset of observed glyphosate concentrations in the groundwater. They imply that in times of continuing and increasing industrial and agricultural productivity, focused recharge may result in an underestimated and widespread risk to usable groundwater volumes