Development of Heterogeneous Photosensitized Transition Metal Oxide Water-Splitting Catalysts on Silica Support

The research presented in this manuscript describes the development of photosensitized inexpensive catalysts based on readily available materials. The investigation covers synthesis and characterization of photosensitizers based on porphyrins, mechanical and thermal coating of solid support with semiconducting transition metal oxides, photosensitization of the semiconducting layer, and characterization of the photoelectrochemical properties displayed by the new materials. The process of water oxidation is of primary interest here, with little emphasis put on reduction of protons to gaseous hydrogen. Photoelectrochemically produced protons serve as a probe of effectiveness of the catalysts. Several systems are described, and two catalysts are identified as the most efficient

The Effects of the Covid-19 Pandemic on Students in the School Setting: The Adaptations Needed for Tiered Supports

This study aims to evaluate the impact of the Covid-19 pandemic on students in the school setting and identify necessary adaptations needed, particularly through a tiered system of support. The research aims for two primary objectives by employing a constructivist framework utilizing mixed methods for data collection. Firstly, it aims to provide districts with a foundation for understanding the social-emotional and academic consequences of the pandemic on students. Secondly, its purpose is to empower districts to leverage this comprehensive evaluation as a proactive approach to cater to the diverse needs of all students. This includes responding to the challenges posed by the pandemic and preparing for potential future uncertainties, such as another pandemic or natural disaster. The Covid-19 pandemic disrupted the amount of content students were exposed to and ripped them from access to mental health resources. As a result, mental health needs have been amplified, particularly in marginalized communities, which further widened the academic gap. The results of this study found a significant disconnect in staff understanding of the Multi-Tiered System of Support (MTSS) processes, coupled with a rise in social-emotional and behavioral challenges arising from the pandemic. These results underscore the necessity for a comprehensive and consistent MTSS framework accompanied by embedded professional learning, particularly through MTSS Directors and a Professional Learning Community (PLC) model. Through the implementation of an MTSS framework, districts can proactively implement screening tools and establish systematic and ongoing processes to address students\u27 academic and social-emotional needs

Native American Weight Loss Movement: Pilot Test of a Culturally Tailored Weight Loss Program for American Indians

American Indians (AIs) have higher rates of obesity than other racial/ethnic groups, placing them at heightened risk for cardiovascular diseases, diabetes, and certain cancers. Culturally appropriate weight loss interventions may be the key to reducing risk. The most successful program used in AI communities has been the Diabetes Prevention Program (DPP), which limits enrollment to individuals with a clinical diagnosis of pre-diabetes. The purpose of this pilot project was to modify and culturally tailor a weight loss intervention to AI communities in Kansas to improve weight loss related behaviors among those who do not qualify for the DPP. The Native American Weight Loss Movement (NAWLM) was developed from 2012-2014 using an iterative process with 4 sequential modifications to the program. Group 1 received a slightly modified version of the DPP that was originally tailored to African Americans. Each group received an improved program based on modifications from the previous group. Our analysis shows 36.1% (95% CI: 25.7, 47.5) of all participants (n=72) lost weight; a majority (63.9%, 95% CI: 52.8-75.0) maintained weight, gained weight, or dropped out. Among individuals who completed the program (n=34), 76.5% lost weight (95% CI: 61.4, 91.5). These individuals lost an average of 2.98% body weight (95% CI: 1.58, 4.37), with 6 participants losing \u3e7% body weight. While most participants who completed the program lost weight, more research is needed to determine factors that discourage drop-out and promote behavioral changes. NAWLM shows promise as a weight loss program for AIs who do not qualify for the DPP

Late Holocene Pollen Stratigraphy in Four Northeastern United States Lakes

Four pollen diagrams from Maine, New York, and Pennsylvania provide fine resolution (40 or 80 years) records of vegetation change in northeastern United States during the past 2000 years. A long term increase in pollen accumulation rates (PAR) of Picea occurred at the three sites in Maine and New York. Around 1100 years ago, Tsuga and Fagus decreased and Quercus and Castanea increased at Ely Lake in northeastern Pennsylvania. Around 500 years ago, Tsuga and Fagus greatly decreased in Maine and northern New York, while in northeastern Pennsylvania there was an increase in Tsuga and Fagus and a decrease in Quercus and Castanea pollen. Non-arboreal PAR were negligible prior to the European settlement of the area, after which there was an abrupt increase in non-arboreal pollen types.Quatre diagrammes polliniques des états du Maine, de New York et de Pennsylvanie illustrent de manière détaillée (40 ou 80 ans) les changements survenus dans la végétation du nord-est des États-Unis sur une période de 2000 ans. Les trois diagrammes des états du Maine et de New York enregistrent un accroissement continu de l'influx pollinique (PAR) de Picea. Il y a environ 1100 ans, Tsuga et Fagus ont subi une diminution, tandis que Quercus et Castanea ont augmenté à Ely Lake, dans le nord-est de la Pennsylvanie. Il y a 500 ans, Tsuga et Fagus ont considérablement diminué dans les états du Maine et de New York, alors que leur représentation pollinique augmentait dans le nord-est de la Pennsylvanie et que Quercus et Castanea diminuaient. Les influx polliniques des herbacés étaient minimes avant l'arrivée des Européens dans la région, après quoi ces taxons ont connu une augmentation subite.Vier Pollen-Diagramme von Maine, New York und Pennsylvania geben detaillierte Auflôsungs-Nachweise der Vegetationswechsel im Nordosten der Vereinigten Staaten wàhrend der letzten 2000 Jahre. Ein langfristiges Anwachsen der Pollen-Akkumulationsraten (PAR) von Picea trat an den drei Fundstellen in Maine und im Staat New York auf. Vor ungefàhr 11000 Jahren, nahmen am Ely-See in Nordost-Pennsylvania Tsuga and Fagus ab und Quercus und Castanea zu. Vor ungefàhr 500 Jahren nahmen in Maine und im Norden des staats New York Tsuga und Fagus stark ab, wàhrend in Nordost-Pennsylvania Tsuga und Fagus zunahmen und Quercus und Casfanea-Pollen abnahmen. Die nicht von Bàumen stammenden PAR waren gering, bevor das Gebiet von Europàern besiedelt wurde, wàhrend danach die nicht von Bàumen stammenden Pollenarten plôtzlich anwuchsen

Composition and dynamics of high power impulse magnetron discharge at W-Mo-C target in argon atmosphere

Metal-doped diamond-like carbon (Me-DLC) is a typical industrial solution for wear resistant coating due to their tribological properties. DLC doping with metal is used to reduce internal stress of the DLC coating, improve its thermal stability, hardness, coating-substrate adhesion, and wear resistance. Furthermore, application of the High Power Impulse Magnetron Sputtering (HiPIMS) for Me-DLC deposition allows improvement of coating adhesion and densification of the coating. To improve the properties of the DLC coatings doping with tungsten and molybdenum from a mixed W-Mo-C target can be used. This study concerns the plasma chemistry and composition for a W-Mo-C target operated with HIPIMS in argon atmosphere. For a HIPIMS discharge with a fixed pulse length of 150 μs a linear dependence of the average power and current are observed. The optical emission spectroscopy experiments reveal a temporal dependence of the plasma composition as the current pulse develops. First plasma is dominated by argon neutrals and ions followed by molybdenum and tungsten. Significant separation between the two metal species is observed in terms of the times of onset and peak of the emission. As a consequence of the change of the neutral gas to metal ratio the estimated effective electron temperature, Te, changes from ~2 eV as estimated from Ar I emission to ~0.3-0.6 eV as indicated by W I emission. A change of Te is also observed with the change of HIPIMS frequency: the Te estimated from metal excitations increases most probably as a result of the processes taking place in the afterglow phase between HIPIMS pulses. The transition from argon plasma at the beginning of the pulse to metal-rich plasma in the second phase of the pulse is discussed in comparison with the ion current measurements performed with a planar probe

Longtime behavior of nonlocal Cahn-Hilliard equations

Here we consider the nonlocal Cahn-Hilliard equation with constant mobility in a bounded domain. We prove that the associated dynamical system has an exponential attractor, provided that the potential is regular. In order to do that a crucial step is showing the eventual boundedness of the order parameter uniformly with respect to the initial datum. This is obtained through an Alikakos-Moser type argument. We establish a similar result for the viscous nonlocal Cahn-Hilliard equation with singular (e.g., logarithmic) potential. In this case the validity of the so-called separation property is crucial. We also discuss the convergence of a solution to a single stationary state. The separation property in the nonviscous case is known to hold when the mobility degenerates at the pure phases in a proper way and the potential is of logarithmic type. Thus, the existence of an exponential attractor can be proven in this case as well

Reliability, Responsiveness, and Validity of the Visual Analog Fatigue Scale to Measure Exertion Fatigue in People with Chronic Stroke: A Preliminary Study

Background and Purpose. Post-Stroke Fatigue (PSF) is a prevalent yet commonly neglected issue that impacts daily functions and quality of life in people post-stroke. To date no studies have attempted to validate a clinically-feasible and reliable instrument to quantify PSF. We developed the Visual Analog Fatigue Scale (VAFS) to eliminate difficulties and poor data validity in testing people post-stroke. The purpose of this study was to evaluate the reliability, responsiveness, and validity of the VAFS. Methods. Twenty-one people post-stroke (12 males, age  = 59.5 ± 10.3 years; time post-stroke  = 4.1 ± 3.5 years) participated. Subjects underwent a standardized fatigue-inducing exercise; fatigue level was assessed at rest, immediately after exercise, and after recovery. The same protocol was repeated after 14 days. Results. ICC values for the VAFS at rest was 0.851 (CI = 95%, 0.673 ∼ 0.936, P < .001), immediately after exercise was 0.846 (CI = 95%, 0.663 ∼ 0.934, P < .001), and 15 minutes after exercise was 0.888 (CI = 95%, 0.749 ∼ 0.953, P < .001). The ES values for at-rest to post-exercise and for post-exercise to post-recovery were 14.512 and 0.685, respectively. Using paired t-test, significant difference was found between VAFS scores at-rest and post-exercise (P < .001), and between post-exercise and post-recovery (P < .001). Conclusion. Our data suggests good reliability, responsiveness, and validity of the VAFS to assess exertion fatigue in people post-stroke

A Statistical Calibration Method of Propagation Prediction Model Based on Measurement Results

Radio environment maps (REMs) are beginning to be an integral part of modern mobile radiocommunication systems and networks, especially for ad-hoc, cognitive, and dynamic spectrum access networks. The REMs will use emerging military systems of tactical communications. The REM is a kind of database used at the stage of planning and management of the radio resources and networks, which considers the geographical features of an area, environmental propagation properties, as well as the parameters of radio network elements and available services. At the REM, for spatial management of network nodes, various methods of propagation modeling for determining the attenuation and capacity of wireless links and radio ranges are used. One method of propagation prediction is based on a numerical solution of the wave equation in a parabolic form, which allows considering, i.a., atmospheric refraction, terrain shape, and soil electrical parameters. However, the determination of a current altitudinal profile of atmospheric refraction may be a problem. If the propagation-prediction model uses a fixed refraction profile, then the calibration of this model based on empirical measurements is required. We propose a methodology for calibrating the analyzed model based on an example empirical research scenario. The paper presents descriptions of the propagation model, test-bed and scenario used in measurements, and obtained signal attenuation results, which are used for the initial calibration of the model