Possible climate change impacts on water resources availability in a large semi-arid catchment in Northeast Brazil.

The semiarid region of Northeast Brazil is characterized by water scarcity, vulnerability of natural resources, and pronounced climatic variability. An integrated model has been developed to simulate this complex situation with an emphasis on a large-scale representation of hydrological processes and on the sensitivity to climate change. Regional climate change scenarios were obtained by empirical downscaling with large-scale climate information from different GCMs which differ strongly in their projections for future precipitation. The results show that due to these differences, it is still impossible to give quantitative values of the water availability in a forecast sense, i.e. to assign probabilities to the simulated results. However, it becomes clear that efficient and ecologically sound water management is a key question for further development. The results show that, independent of the climate change, agriculture is more vulnerable to drought impacts in the case of rainfed compared to irrigated farming. However, the capacity of irrigation and water infrastructure to enhance resilience with respect to climatic fluctuations is significantly constrained in the case of a negative precipitation trend

Structure-Function Relationship of Highly Reactive CuOx Clusters on Co3O4 for Selective Formaldehyde Sensing at Low Temperatures

Designing reactive surface clusters at the nanoscale on metal-oxide supports enables selective molecular interactions in low-temperature catalysis and chemical sensing. Yet, finding effective material combinations and identifying the reactive site remains challenging and an obstacle for rational catalyst/sensor design. Here, the low-temperature oxidation of formaldehyde with CuOx clusters on Co3 O4 nanoparticles is demonstrated yielding an excellent sensor for this critical air pollutant. When fabricated by flame-aerosol technology, such CuOx clusters are finely dispersed, while some Cu ions are incorporated into the Co3 O4 lattice enhancing thermal stability. Importantly, infrared spectroscopy of adsorbed CO, near edge X-ray absorption fine structure spectroscopy and temperature-programmed reduction in H2 identified Cu+ and Cu2+ species in these clusters as active sites. Remarkably, the Cu+ surface concentration correlated with the apparent activation energy of formaldehyde oxidation (Spearman's coefficient ρ = 0.89) and sensor response (0.96), rendering it a performance descriptor. At optimal composition, such sensors detected even the lowest formaldehyde levels of 3 parts-per-billion (ppb) at 75°C, superior to state-of-the-art sensors. Also, selectivity to other aldehydes, ketones, alcohols, and inorganic compounds, robustness to humidity and stable performance over 4 weeks are achieved, rendering such sensors promising as gas detectors in health monitoring, air and food quality control

Handheld Device for Selective Benzene Sensing over Toluene and Xylene

More than 1 million workers are exposed routinely to carcinogenic benzene, contained in various consumer products (e.g., gasoline, rubbers, and dyes) and released from combustion of organics (e.g., tobacco). Despite strict limits (e.g., 50 parts per billion (ppb) in the European Union), routine monitoring of benzene is rarely done since low-cost sensors lack accuracy. This work presents a compact, battery-driven device that detects benzene in gas mixtures with unprecedented selectivity (>200) over inorganics, ketones, aldehydes, alcohols, and even challenging toluene and xylene. This can be attributed to strong Lewis acid sites on a packed bed of catalytic WO3 nanoparticles that prescreen a chemoresistive Pd/SnO2 sensor. That way, benzene is detected down to 13 ppb with superior robustness to relative humidity (RH, 10–80%), fulfilling the strictest legal limits. As proof of concept, benzene is quantified in indoor air in good agreement (R2 ≥ 0.94) with mass spectrometry. This device is readily applicable for personal exposure assessment and can assist the implementation of low-emission zones for sustainable environments

Modeling the influence of climate on groundwater flow and heat regime in Brandenburg (Germany)

This study investigates the decades-long evolution of groundwater dynamics and thermal field in the North German Basin beneath Brandenburg (NE Germany) by coupling a distributed hydrologic model with a 3D groundwater model. We found that hydraulic gradients, acting as the main driver of the groundwater flow in the studied basin, are not exclusively influenced by present-day topographic gradients. Instead, structural dip and stratification of rock units and the presence of permeability contrasts and anisotropy are important co-players affecting the flow in deep seated saline aquifers at depths >500 m. In contrast, recharge variability and anthropogenic activities contribute to groundwater dynamics in the shallow (<500 m) freshwater Quaternary aquifers. Recharge fluxes, as derived from the hydrologic model and assigned to the parametrized regional groundwater model, reproduce magnitudes of recorded seasonal groundwater level changes. Nonetheless, observed instances of inter-annual fluctuations and a gradual decline of groundwater levels highlight the need to consider damping of the recharge signal and additional sinks, like pumping, in the model, in order to reconcile long-term groundwater level trends. Seasonal changes in near-surface groundwater temperature and the continuous warming due to conductive heat exchange with the atmosphere are locally enhanced by forced advection, especially in areas of high hydraulic gradients. The main factors controlling the depth of temperature disturbance include the magnitude of surface temperature variations, the subsurface permeability field, and the rate of recharge. Our results demonstrate the maximum depth extent and the response times of the groundwater system subjected to non-linear interactions between local geological variability and climate conditions

Interannual variations of the terrestrial water storage in the Lower Ob' Basin from a multisatellite approach

International audienceTemporal variations of surface water volume over inundated areas of the Lower Ob' Basin in Siberia, one of the largest contributor of freshwater to the Arctic Ocean, are estimated using combined observations from a multisatellite inundation dataset and water levels over rivers and floodplains derived from the TOPEX/POSEIDON (T/P) radar altimetry. We computed time-series of monthly maps of surface water volume over the common period of available T/P and multisatellite data (1993–2004). The results exhibit interannual variabilities similar to precipitation estimates and river discharge observations. This study also presents monthly estimates of groundwater and permafrost mass anomalies during 2003–2004 based on a synergistic analysis of multisatellite observations and hydrological models. Water stored in the soil is isolated from the total water storage measured by GRACE when removing the contributions of both the surface reservoir, derived from satellite imagery and radar altimetry, and the snow estimated by inversion of GRACE measurements. The time variations of groundwater and permafrost are then obtained when removing the water content of the root zone reservoir simulated by hydrological models

Estimación del coeficiente de almacenamiento del acuífero Pampeano a partir de datos de un gravímetro superconductor

El rendimiento específico o porosidad drenable se define como la cantidad media de agua por unidad de volumen de suelo que se drena por unidad de descenso del nivel freático en un perfil que se extiende desde el nivel freático hasta la superficie. Desde un punto de vista hidrogeológico este parámetro resulta de importancia en problemas tales como la estimación de la recarga y el diseño de planes eficientes para la explotación sustentable de aguas subterráneas. El valor de este parámetro se suele estimar mediante ensayos de bombeo y su valor resulta siempre menor al de la porosidad de la formación. En el presente trabajo se propone una técnica para la determinación del rendimiento específico que correlaciona mediciones de gravedad in situ del gravímetro superconductor GWR R038 con variaciones del nivel freático muestreadas en el predio del Observatorio Argentino Alemán de Geodesia (AGGO). Para emplear esta técnica es necesario contar con datos observados durante un periodo de tiempo sin precipitaciones para garantizar un descenso continuo del nivel freático por flujo regional. Bajo estas hipótesis y asumiendo que el problema es unidimensional se obtiene una relación lineal entre las variaciones de gravedad y los niveles freáticos que depende del rendimiento específico. Para la aplicación práctica de esta técnica se seleccionó un período de tiempo de 19 días (9 al 28 de mayo del 2016) donde se observó un perfil de humedad estable y un descenso continuo de los niveles. Los datos gravimétricos fueron corregidos por efectos de marea, carga oceánica, presión atmosférica y movimiento del polo. El valor del rendimiento específico determinado para el acuífero Pampeano es aproximadamente 0.18. Este valor se encuentra dentro del rango de valores admisibles para la textura de este acuífero. La técnica empleada es sumamente novedosa en nuestra región ya que el gravímetro superconductor de AGGO es el único instrumental de su tipo funcionando en América Latina.Eje: Ciencias Hidrológicas y Criósfera.Facultad de Ciencias Astronómicas y Geofísicas (FCAG

First implementation of a new cross-disciplinary observation strategy for heavy precipitation events from formation to flooding

Heavy Precipitation Events (HPE) are the result of enormous quantities of water vapor being transported to a limited area. HPE rainfall rates and volumes cannot be fully stored on and below the land surface, often leading to floods with short forecast lead times that may cause damage to humans, properties, and infrastructure. Toward an improved scientific understanding of the entire process chain from HPE formation to flooding at the catchment scale, we propose an elaborated event-triggered observation concept. It combines flexible mobile observing systems out of the fields of meteorology, hydrology and geophysics with stationary networks to capture atmospheric transport processes, heterogeneous precipitation patterns, land surface and subsurface storage processes, and runoff dynamics. As part of the Helmholtz Research Infrastructure MOSES (Modular Observation Solutions for Earth Systems), the effectiveness of our observation strategy is illustrated by its initial implementation in the Mueglitz river basin (210 km$^2$), a headwater catchment of the Elbe in the Eastern Ore Mountains with historical and recent extreme flood events. Punctual radiosonde observations combined with continuous microwave radiometer measurements and back trajectory calculations deliver information about the moisture sources, and initiation and development of HPE. X-band radar observations calibrated by ground-based disdrometers and rain gauges deliver precipitation information with high spatial resolution. Runoff measurements in small sub-catchments complement the discharge time series of the operational network of gauging stations. Closing the catchment water balance at the HPE scale, however, is still challenging. While evapotranspiration is of less importance when studying short-term convective HPE, information on the spatial distribution and on temporal variations of soil moisture and total water storage by stationary and roving cosmic ray measurements and by hybrid terrestrial gravimetry offer prospects for improved quantification of the storage term of the water balance equation. Overall, the cross-disciplinary observation strategy presented here opens up new ways toward an integrative and scale-bridging understanding of event dynamics

Monitoring of selected skin- and breath-borne volatile organic compounds emitted from the human body using gas chromatography ion mobility spectrometry (GC-IMS)

ISSN:1873-376XISSN:1570-0232ISSN:1572-6495ISSN:1387-227