1,236 research outputs found
Dynamically Slow Processes in Supercooled Water Confined Between Hydrophobic Plates
We study the dynamics of water confined between hydrophobic flat surfaces at
low temperature. At different pressures, we observe different behaviors that we
understand in terms of the hydrogen bonds dynamics. At high pressure, the
formation of the open structure of the hydrogen bond network is inhibited and
the surfaces can be rapidly dehydrated by decreasing the temperature. At lower
pressure the rapid ordering of the hydrogen bonds generates heterogeneities
that are responsible for strong non-exponential behavior of the correlation
function, but with no strong increase of the correlation time. At very low
pressures, the gradual formation of the hydrogen bond network is responsible
for the large increase of the correlation time and, eventually, the dynamical
arrest of the system and of the dehydration process.Comment: 14 pages, 3 figure
Hydrogen-Bonded Liquids: Effects of Correlations of Orientational Degrees of Freedom
We improve a lattice model of water introduced by Sastry, Debenedetti,
Sciortino, and Stanley to give insight on experimental thermodynamic anomalies
in supercooled phase, taking into account the correlations between
intra-molecular orientational degrees of freedom. The original Sastry et al.
model including energetic, entropic and volumic effect of the
orientation-dependent hydrogen bonds (HBs), captures qualitatively the
experimental water behavior, but it ignores the geometrical correlation between
HBs. Our mean-field calculation shows that adding these correlations gives a
more water-like phase diagram than previously shown, with the appearance of a
solid phase and first-order liquid-solid and gas-solid phase transitions.
Further investigation is necessary to be able to use this model to characterize
the thermodynamic properties of the supercooled region.Comment: 7 pages latex, 3 figures EP
Effect of hydrogen bond cooperativity on the behavior of water
Four scenarios have been proposed for the low--temperature phase behavior of
liquid water, each predicting different thermodynamics. The physical mechanism
which leads to each is debated. Moreover, it is still unclear which of the
scenarios best describes water, as there is no definitive experimental test.
Here we address both open issues within the framework of a microscopic cell
model by performing a study combining mean field calculations and Monte Carlo
simulations. We show that a common physical mechanism underlies each of the
four scenarios, and that two key physical quantities determine which of the
four scenarios describes water: (i) the strength of the directional component
of the hydrogen bond and (ii) the strength of the cooperative component of the
hydrogen bond. The four scenarios may be mapped in the space of these two
quantities. We argue that our conclusions are model-independent. Using
estimates from experimental data for H bond properties the model predicts that
the low-temperature phase diagram of water exhibits a liquid--liquid critical
point at positive pressure.Comment: 18 pages, 3 figure
Softness dependence of the Anomalies for the Continuous Shouldered Well potential
By molecular dynamic simulations we study a system of particles interacting
through a continuous isotropic pairwise core-softened potential consisting of a
repulsive shoulder and an attractive well. The model displays a phase diagram
with three fluid phases, a gas-liquid critical point, a liquid-liquid critical
point, and anomalies in density, diffusion and structure. The hierarchy of the
anomalies is the same as for water. We study the effect on the anomalies of
varying the softness of the potential. We find that, making the soft-core
steeper, the regions of density and diffusion anomalies contract in the T -
{\rho} plane, while the region of structural anomaly is weakly affected.
Therefore, a liquid can have anomalous structural behavior without density or
diffusion anomalies. We show that, by considering as effective distances those
corresponding to the maxima of the first two peaks of the radial distribution
function g(r) in the high-density liquid, we can generalize to continuous
two-scales potentials a criterion for the occurrence of the anomalies of
density and diffusion, originally proposed for discontinuous potentials. We
observe that the knowledge of the structural behavior within the first two
coordination shells of the liquid is not enough to establish the occurrence of
the anomalies. By introducing the density derivative of the the cumulative
order integral of the excess entropy we show that the anomalous behavior is
regulated by the structural order at distances as large as the fourth
coordination shell. By comparing the results for different softness of the
potential, we conclude that the disappearing of the density and diffusion
anomalies for the steeper potentials is due to a more structured short-range
order. All these results increase our understanding on how, knowing the
interaction potential, we can evaluate the possible presence of anomalies for a
liquid
Structural behavior and dynamics of an anomalous fluid between attractive and repulsive walls: Templating, molding, and superdiffusion
Confinement can modify the dynamics, the thermodynamics, and the structural properties of liquid water, the prototypical anomalous liquid. By considering a generic model for anomalous liquids, suitable for describing solutions of globular proteins, colloids, or liquid metals, we study by molecu- lar dynamics simulations the effect that an attractive wall with structure and a repulsive wall without structure have on the phases, the crystal nucleation, and the dynamics of the fluid. We find that at low temperatures the large density of the attractive wall induces a high-density, high-energy structure in the first layer ('templating' effect). In turn, the first layer induces a 'molding' effect on the second layer determining a structure with reduced energy and density, closer to the average density of the system. This low-density, low-energy structure propagates further through the layers by templating effect and can involve all the existing layers at the lowest temperatures investigated. Therefore, al- though the high-density, high-energy structure does not self-reproduce further than the first layer, the structured wall can have a long-range influence thanks to a sequence of templating, molding, and templating effects through the layers. We find that the walls also have an influence on the dynamics of the liquid, with a stronger effect near the attractive wall. In particular, we observe that the dy- namics is largely heterogeneous (i) among the layers, as a consequence of the sequence of structures caused by the walls presence, and (ii) within the same layer, due to superdiffusive liquid veins within a frozen matrix of particles near the walls at low temperature and high density. Hence, the partial freezing of the first layer does not correspond necessarily to an effective reduction of the channel's section in terms of transport properties, as suggested by other authors
A discrete model of water with two distinct glassy phases
We investigate a minimal model for non-crystalline water, defined on a Husimi
lattice. The peculiar random-regular nature of the lattice is meant to account
for the formation of a random 4-coordinated hydrogen-bond network. The model
turns out to be consistent with most thermodynamic anomalies observed in liquid
and supercooled-liquid water. Furthermore, the model exhibits two glassy phases
with different densities, which can coexist at a first-order transition. The
onset of a complex free-energy landscape, characterized by an exponentially
large number of metastable minima, is pointed out by the cavity method, at the
level of 1-step replica symmetry breaking.Comment: expanded version: 6 pages, 7 figure
More than one dynamic crossover in protein hydration water
Studies of liquid water in its supercooled region have led to many insights
into the structure and behavior of water. While bulk water freezes at its
homogeneous nucleation temperature of approximately 235 K, for protein
hydration water, the binding of water molecules to the protein avoids
crystallization. Here we study the dynamics of the hydrogen bond (HB) network
of a percolating layer of water molecules, comparing measurements of a hydrated
globular protein with the results of a coarse-grained model that has been shown
to successfully reproduce the properties of hydration water. With dielectric
spectroscopy we measure the temperature dependence of the relaxation time of
protons charge fluctuations. These fluctuations are associated to the dynamics
of the HB network of water molecules adsorbed on the protein surface. With
Monte Carlo (MC) simulations and mean--field (MF) calculations we study the
dynamics and thermodynamics of the model. In both experimental and model
analyses we find two dynamic crossovers: (i) one at about 252 K, and (ii) one
at about 181 K. The agreement of the experiments with the model allows us to
relate the two crossovers to the presence of two specific heat maxima at
ambient pressure. The first is due to fluctuations in the HB formation, and the
second, at lower temperature, is due to the cooperative reordering of the HB
network
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