A study of the applicability of nucleation theory to quasi-thermodynamic transitions of second and higher Ehrenfest-order, supplement 3

The work includes an investigation of the applicability of the nucleation theory to second and higher order thermodynamic transitions in the Ehrenfest sense, and a number of significant conclusions relevant to first order transitions, as well. The underlying theoretical method consisted of expanding the Gibbs' free energy in a Maclarin or Taylor series and then using fundamental thermodynamic determinable quantities, and interpreting the results. Work was performed on the existence and interpretation of an interfacial energy between phases in a second order transition in addition to an investigation of the solid-liquid interfacial energy for various polymers. Extensive considerations were devoted to various aspects of a particular polymer, polyvinylidene fluoride (PVDF or PVF2), including an experimetal investigation of the effects of an applied electric field on the morphology of melt crystallization and on the nucleation and growth of polarized domains

A study of the applicability of nucleation theory to quasi-thermodynamic transformations of second and higher Ehrenfest-order

Transient and steady-state phenomena in temperature, stress, and electric, field intensity in ferroelectric polymers were investigated. The application and extension of the theory in the primary stage to the polarization domain nucleation and growth in ferroelectric polymers were developed. The kinetics of this growth were investigated. Expressions describing nucleation under the influence of an electric field were found through the expansion of the Gibbs' free energy in a Maclaurin series. The series was expanded in the electric field strength rather than the degree of undercooling. The resulting expressions were manipulated and applied to the case of nucleation of polarized domains in ferroelectric polymers. The kinetics of the nucleation and growth of polarized domains are also investigated. This was accomplished through the modification of the Johnson-Mehl-Avrami treatment of crystallization kinetics to be applicable to the growth of polarization domains in ferroelectric materials

Oedipus of many pains: Strategies of contest in Homeric poetry

In this paper we analyse Oedipus’ appearance during Odysseus’ tale in book 11 of Homer’s Odyssey in order to outline and test a methodology for appreciating the poetic and thematic implications of moments when ‘extraneous’ narratives or traditions appear in the Homeric poems. Our analysis, which draws on oral-formulaic theory, is offered partly as a re-evaluation of standard scholarly approaches that tend to over-rely on the assumed pre-eminence of Homeric narratives over other traditions in their original contexts or approaches that reduce such moments to instances of allusions to or parallels with fixed texts. In conjunction with perspectives grounded in orality, we emphasise the agonistic character of Greek poetry to explore the ways in which Odysseus’ articulation of his Oedipus narrative exemplifies an attempt to appropriate and manipulate a rival tradition in the service of a particular narrative’s ends. We focus specifically on the resonance of the phrases algea polla and mega ergon used by Odysseus as a narrator to draw a web of interconnections throughout Homeric and Archaic Greek poetry. Such an approach, in turn, suggests to what extent the Homeric Oedipus passage speaks to the themes and concerns of Homeric poetry rather than some lost Oedipal epic tradition and illustrates the importance of recognizing the deeply competitive nature of Homeric narratives vis-à-vis other narrative traditions

Late biological effects of heavy charged particles: Cataracts, vascular injury and life shortening in mice

Risks associated with extended habitation in a space environment, particularly hazards to space workers that might result from exposure to high energy heavy ion particles (HZE), were studied. Biological effects of HZE were investigated in mice to assess their potential adverse health hazards. The potential effects of HZE particles on the crystalline lens of the eye and the carcinogenic effects and blood vessel (vascular) damage from radiation were evaluated by a risk assessment. Animal experiments to evaluate dose response relationships for tumor induction/promotion and for vascular injury were introduced. Cataract productions and preliminary results on cacinogenic and vascular effects are presented for perspective

Hydrographic charting from LANDSAT Satellite: A comparison with aircraft imagery

The relative capabilities of two remote-sensing systems in measuring depth and, consequently, bottom contours in sandy-bottomed and sediment-laden coastal waters were determined quantitatively. The multispectral scanner (MSS), orbited on the LANDSAT-2 Satellite, and the ocean color scanner (OCS), flown on U-2 aircraft, were used. Analysis of imagery taken simultaneously indicates a potential for hydrographic charting of marine coastal and shallow shelf areas, even when water turbidity is a factor. Several of the eight optical channels examined on the OCS were found to be sensitive to depth or depth-related information. The greatest sensitivity was in OCS-4(0.544 + or - 0.012 microns) from which contours corresponding to depths up to 12m were determined. The sharpness of these contours and their spatial stability through time suggests that upwelling radiance is a measure of bottom reflectance and not of water turbidity. The two visible channels on LANDSAT's MSS were less sensitive in the discrimination of contours, with depths up to 8m in the high-gain mode (3x) determined in MSS-4(0.5 to 0.6 microns)

An Alternative Parameterization of R-matrix Theory

An alternative parameterization of R-matrix theory is presented which is mathematically equivalent to the standard approach, but possesses features which simplify the fitting of experimental data. In particular there are no level shifts and no boundary-condition constants which allows the positions and partial widths of an arbitrary number levels to be easily fixed in an analysis. These alternative parameters can be converted to standard R-matrix parameters by a straightforward matrix diagonalization procedure. In addition it is possible to express the collision matrix directly in terms of the alternative parameters.Comment: 8 pages; accepted for publication in Phys. Rev. C; expanded Sec. IV, added Sec. VI, added Appendix, corrected typo

A two-stage stochastic programming with recourse model for determining robust planting plans in horticulture

A two-stage stochastic programming with recourse model for the problem of determining optimal planting plans for a vegetable crop is presented in this paper. Uncertainty caused by factors such as weather on yields is a major influence on many systems arising in horticulture. Traditional linear programming models are generally unsatisfactory in dealing with the uncertainty and produce solutions that are considered to involve an unacceptable level of risk. The first stage of the model relates to finding a planting plan which is common to all scenarios and the second stage is concerned with deriving a harvesting schedule for each scenario. Solutions are obtained for a range of risk aversion factors that not only result in greater expected profit compared to the corresponding deterministic model, but also are more robust

A study of the applicability of nucleation theory to quasi-thermodynamic transitions of second and higher Ehrenfest-order

The applicability of classical nucleation theory to second (and higher) order thermodynamic transitions in the Ehrenfest sense has been investigated and expressions have been derived upon which the qualitative and quantitative success of the basic approach must ultimately depend. The expressions describe the effect of temperature undercooling, hydrostatic pressure, and tensile stress upon the critical parameters, the critical nucleus size, and critical free energy barrier, for nucleation in a thermodynamic transition of any general order. These expressions are then specialized for the case of first and second order transitions. The expressions for the case of undercooling are then used in conjunction with literature data to estimate values for the critical quantities in a system undergoing a pseudo-second order transition (the glass transition in polystyrene). Methods of estimating the interfacial energy gamma in systems undergoing a first and second order transition are also discussed

Prospects for adopting system of rice intensification in Sri Lanka: a socioeconomic assessment

Models / Rice / Paddy fields / Irrigated farming / Rain-fed farming / Poverty / Farmers / Sri Lanka / Ratnapura / Kurunegala / Kalthota Irrigation System